• Title/Summary/Keyword: Chain initiation

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MAP/G/1/K QUEUE WITH MULTIPLE THRESHOLDS ON BUFFER

  • Choi, Doo-Il
    • Communications of the Korean Mathematical Society
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    • v.14 no.3
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    • pp.611-625
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    • 1999
  • We consider ΜΑΡ/G/ 1 finite capacity queue with mul-tiple thresholds on buffer. The arrival of customers follows a Markov-ian arrival process(MAP). The service time of a customer depends on the queue length at service initiation of the customer. By using the embeded Markov chain method and the supplementary variable method, we obtain the queue length distribution ar departure epochs and at arbitrary epochs. This gives the loss probability and the mean waiting time by Little's law. We also give a simple numerical examples to apply the overload control in packetized networks.

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OXIDANT-INDUCED NEUROTOXICITY WAS BLOCKED BY ANTIOXIDANTS AND METAL CHELATORS IN MOUSE CEREBRAL NEURON CULTURES

  • Park, S.T.;H.Y. Yoon
    • Proceedings of the Korean Society of Toxicology Conference
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    • 2002.05a
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    • pp.89-89
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    • 2002
  • It is well known that oxygen radicals induce neuronal cell damage by initiation of lipid peroxidation chain reaction. Recent work has been also demonstrated that enzymatically generated free radicals cause the release of glutamate and aspartate from cultured rat hippocampal slices.(omitted)

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POLYMERIZATION OF HEMA IN THE PRESENCE OF PHENYLSILANES (PHENYLSILANE의 존재하에서 HEMA(2-Hydroxyethylmethacrylate)의 중합)

  • Sung, A-Young
    • Journal of Korean Ophthalmic Optics Society
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    • v.6 no.2
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    • pp.145-148
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    • 2001
  • The bulk photopolymerization of 2-hydrxyethylmethacrylate(HDMA) with phenylsilane was perforemed to produce poly(HEMA)s containing phenylsilyl moiety presumably as an end group. This result, are the same as that of thermal polymerization. It was found that while the polymerization yields and intrinsic viscosities decreased, the TGA residue yields and the relative intensities of SiH IR stretching bands increased with increasing molar ratio of phenylsilane over HEMA. The phenylsilane seemed to significantly influence on the photopolymerization as both chain initiation and chain transfer agents.

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Preferred Conformations of Cyclic Ac-Cys-Pro-Xaa-Cys-NHMe Peptides: a Model for Chain Reversal and Active Site of Disulfide Oxidoreductase

  • Park, Hae-Sook;Kim, Choonmi;Kang, Young-Kee
    • Proceedings of the Korean Biophysical Society Conference
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    • 2001.06a
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    • pp.35-35
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    • 2001
  • The conformational study on cyclic Ac-Cys-Pro-Xaa-Cys-NHMe (Ac-CPXC-NHMe; X = Ala, Val, Leu, Aib, Gly, His, Phe, Tyr, Asn, and Ser) peptides has been carried out using the ECEPP/3 force field and the hydration shell model in the unhydrated and hydrated states. This work has been undertaken to investigate structural implications of the CPXC sequence as the chain reversal for the initiation of protein folding and as the motif for active site of disulfide oxidoreductases.(omitted)

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Photopolymerization of Methyl Methacrylate with Disilanes

  • U, Hui Gwon;Hong, Ran Yeong;Park, Jin Yeong;Jeong, Yeong Tae;Park, Hyeong Ryun;Ham, Hui Seok
    • Bulletin of the Korean Chemical Society
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    • v.17 no.1
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    • pp.16-19
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    • 1996
  • The bulk photopolymerization of methyl methacrylate (MMA) with disilanes such as 1,2-diphenyldisilane and 2-phenyl-1,3-disilapropane was carried out to yield poly(MMA)s containing the corresponding disilyl moiety presumably as an end group. It was found that while the polymerization yields and the polymer molecular weights decreased as the relative disilane concentration increased, the TGA residue yields and the relative intensities of SiH IR stretching bands increased with increment of molar ratio of disilane over MMA. The photopolymerization of MMA with 2-phenyl-1,3-disilapropane produced higher-molecular-weight polymer with lower TGA residue yield when compared to the photopolymerization of MMA with 1,2-diphenyldisilane. The disilanes seemed to significantly influence on the photopolymerization as both chain initiation and chain transfer agents.

Polymerization of Methyl Methacrylate with Phenylsilane

  • 유희권;박선희;박진영;양수연;함희숙;김환기
    • Bulletin of the Korean Chemical Society
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    • v.17 no.4
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    • pp.373-376
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    • 1996
  • The bulk thermal and photopolymerization of methyl methacrylate(MMA) with phenylsilane were performed to produce poly(MMA)s containing phenylsilyl moiety presumably as an end group. It was found for both thermal and photopolymerization that while the polymerization yields and polymer molecular weights decreased as the relative phenylsilane concentration increases, the TGA residue yields and the relative intensities of SiH IR stretching bands increased with increasing molar ratio of phenylsilane over MMA. The polymerization yield, molecular weight, and TGA residue yield for the thermal polymerization were higher than those for the photopolymerization. Thus, the phenylsilane seemed to significantly influence on the polymerization as both chain initiation and chain transfer agents. However, an appreciable silane effect was not observed on the thermal and photopolymerization of 4-vinylpyridine, acrylonitrile, styrene, and vinyltrimethoxysilane.

Photopolymerization of Methyl Methacrylate with Primarty Aryl- and Alkylsilanes

  • 우희권;홍란영;양수연;박선희;송선정;함희석
    • Bulletin of the Korean Chemical Society
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    • v.16 no.11
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    • pp.1056-1059
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    • 1995
  • The bulk photopolymerization of methyl methacrylate (MMA) with primary arylsilane (e.g., phenylsilane) and various primary alkylsilanes (e.g., benzylsilane, 3-phenoxyphenyl-1-silabutane, 3-naphthyl-1-silabutane, and 3-chlorophenyl-1-silabutane) was performed to produce poly(MMA)s containing the corresponding silyl moiety as an end group. It was found for the phenylsilane that while the polymerization yields increased and then decreased with a turning point at the molar ratio of MMA:silane=10:1 as the relative silane concentration increases, the polymer molecular weights decreased, and the TGA residue yields and the relative intensities of SiH IR stretching bands increased with increment of molar ratio of silane over MMA. The photopolymerization yield of MMA with the arylsilane was found to be higher than those with the alkylsilanes and without the silanes. Thus, the silanes seemed to significantly influence on the photopolymerization as both chain initiation and chain transfer agents.

Photopolymerization of Methyl Methacrylate with p-X-$C_{6}H_{4}SiH_{3}$ (X = F, $CH_3$, $OCH_3$)

  • U, Hui Gwon;Kim, Bo Hye;Jo, Myeong Sik;Kim, Dae Yeong;Choe, Yeong Seop;Gwak, Yeong Chae;Ham, Hui Seok;Kim, Dong Pyo;Hwang, Taek Seong
    • Bulletin of the Korean Chemical Society
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    • v.22 no.12
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    • pp.1337-1340
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    • 2001
  • The bulk photopolymerization of methyl methacrylate (MMA) with para-substituted phenylsilanes such as F-C6H4SiH3 (1), H3C-C6H4SiH3 (2), and H3CO-C6H4SiH3 (3) was performed to produce poly(MMA)s containing the respective silyl moiety as an end group. For all the hydrosilanes, the polymerization yields and the polymer molecular weights decreased, whereas the TGA residue yields and the relative intensities of Si-H IR stretching bands increased as the relative silane concentration over MMA increased. The polymerization yields and polymer molecular weights of MMA with 1-3 increased in the order of 3 < 1 < 2. These hydrosilanes influence significantly upon the photopolymerization of MMA as both chain-initiation and chain-transfer agents.

Photopolymerization of Methacrylic Acid with Secondary Silanes

  • 우희권;박선희;홍란영;강행구;함희숙
    • Bulletin of the Korean Chemical Society
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    • v.17 no.6
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    • pp.532-535
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    • 1996
  • The bulk photopolymerization of methacrylic acid (MA) with secondary silanes such as PhMeSiH2 and Ph2SiH2 gave poly(MA)s possessing the secondary silyl moiety presumably as an end group. It was found that while the polymerization yields and intrinsic viscosities decreased, the TGA residue yields and the relative intensities of SiH IR stretching bands increased with increasing mole ratio of the secondary silane over MA. The sterically less bulky silane PhMeSiH2 produced poly(MA)s with somewhat higher molecular weights and with similar TGA residue yields compared with the sterically bulkier silane Ph2SiH2. The secondary silanes seem to significantly influence on the photopolymerization of MA as both chain initiation and chain transfer agents.

Theoretical Analysis for the HF Chemical Laser System with a Selected Fluoride Molecule

  • You, Myung-A;Cho, Ung-In;Kim, Sung-Ho
    • Korean Journal of Optics and Photonics
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    • v.2 no.4
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    • pp.227-232
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    • 1991
  • The possibility for the high intensity and energy possessing a short pulse in the HF chemical laser system which contained fluoride molecules (RF) was demonstrated theoretically through the numerical model simulation. The calculation was accomplished by assuming that the thermal branched chain mechanism of RF was occurred in the initiation step of $H_2+F_2$ chain reaction. Variations of the major chemicals and the temperature in the system were calculated as a function of time. An analysis was also performed to evaluate output pulse profile through parametric studies.

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