• 제목/요약/키워드: Chain Structure

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A study on the O2O Commerce Business Process with Business Model Canvas

  • PARK, Hyun-Sung
    • Journal of Distribution Science
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    • v.18 no.5
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    • pp.89-98
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    • 2020
  • Purpose: The growth of online commerce is now becoming a major threat and a new opportunity for retailers. Existing offline retailers struggle to cope with new online retailers' threats by utilizing offline infrastructure. Besides, online retailers expand their online strengths to offline sales by opening their offline stores. Many retailers are paying close attention to the O2O business and the resulting changes. Thus, this research focuses on the O2O business model and process that retailers can adopt. Research design, data and methodology: Considering the features of products that retailers sell, this paper divides O2O business process with the following criteria: delivery lead-time and delivery area. And This research uses the business model canvas to define the features of O2O commerce business process. This paper also uses nine key elements in the business model canvas for analyzing the structure of O2O commerce business. Results: This paper suggests the delivery model of retailers respond to offline customer orders and summarizes the following results. (1) Considering characteristics such as logistics process, delivery area, and product type, we define the features of O2O business models: wide-area (warehouse) based O2O business model, regional area (store) based O2O business model and time-separated O2O business model. (2) This study checks the availability of the business model through the business cases of O2O business models. (3) This study also analyzes the O2O business model of domestic retail companies by the factors defined in the business model canvas. Conclusions: Retailers can adopt the O2O business process to fit their business requirements and strategy. The online retailers who deal with normal consumer products mainly have the wide-area based O2O business model. The wide-area based O2O business model can be suitable for retailers who manage inventory centrally. The time-separated O2O business model can be a good solution for fresh food retailers to operate the logistics process efficiently. And to shorten the delivery lead-time of fresh foods, the regional area based O2O business model can be fit to the retailer that utilizes its offline logistics or sales infrastructure. It may be much more important for retailers to share the inventory information with other branches and to change the role of offline stores.

Solvent-Polymer Interactions for Stable Non-Aqueous Graphene Dispersions in the Presence of PVK-b-PVP Block Copolymer (PVK-b-PVP 블록 공중합체의 존재 하에서 안정한 비 수계 그래핀 분산액을 위한 용매-고분자 상호작용에 관한 연구)

  • Park, Kyung Tae;Perumal, Suguna;Lee, Hyang Moo;Kim, Young Hyun;Cheong, In Woo
    • Journal of Adhesion and Interface
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    • v.18 no.3
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    • pp.109-117
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    • 2017
  • Poly(N-vinyl carbazole) (PVK) homopolymer, poly(4-vinylpyridine) (PVP) homopolymer, and PVK-b-PVP block copolymer were synthesized by reversible addition-fragmentation chain transfer (RAFT) polymerization and the polymers were used to prepare non-aqueous graphene dispersions with four different solvents, ethanol, N-methyl-2-pyrrolidone (NMP), dichloromethane (DCM), and tetrahydrofuran (THF). $^1H-$ and $^{13}C-NMR$ spectroscopy, size exclusion chromatography (SEC), and differential scanning calorimetry (DSC) were carried out to confirm the chemical structure of the polymers. Stability of graphene dispersions was measured by on-line turbidity measurement. Time-dependent Turbiscan Stability Index (TSI) values were interpreted in terms of surface tension (${\sigma}$) and solubility parameter (${\delta}$) among solvents, polymers, and graphene. It was confirmed that the solubilities of polymer and surface tension between solvent and graphene affected the dispersion stability of graphene. PVK-b-PVP block copolymer could effectively maintain the low TSI values of graphene dispersions in ethanol and THF, which have been known as poor solvents for graphene dispersions. It can also be noted that DCM shows good dispersion stability comparable to NMP, which has been known as the best solvent for graphene dispersion.

A Research on Powder Dispersion Ability Using Several Content, Variety of Powder and Additive in Aqueous System (파우더, 첨가제의 종류와 함량에 따른 수상 내에서의 파우더 분산에 관한 연구)

  • Kim, Sun-Young;Kim, Il-Gu;Choi, Seung-Man;Lee, Sang-Min
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.38 no.4
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    • pp.271-276
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    • 2012
  • In this study, the dispersion ability of powder in low viscosity solubilization system that depends on variety and amount of additives and powders was investigated. A PMMA powder shows outstanding dispersion ability because of its repulsive force of partially charged chain and low density of porous structure. A sample, which contains salts, showed better dispersion tendency than a sample without any additives. The dispersion ability was quantity of salts dependent. Furthermore, a sample with divalent ion salts, like $MgSO_4$, showed better dispersion tendency than that of monovalent ion salts, like NaCl or KCl. The reason for the better dispersion tendency was due to the existence of ionized salts around the powders which significantly improves repulsive force between powders and consequently reduces powder aggregation. The sample with chelating agent, like EDTA as an additive, had improved dispersion ability. EDTA chelates and blocks metal cation therefore anion's character is maximized and repulsive force between powders is improved. As a result, salts and EDTA help to improve the powder dispersion ability and the stability of product.

Properties of a Thermosetting Epoxy Composite : Effect of Isothermal Physical Aging (에폭시 열경화 복차재료의 성질 : 등온물리시효의 효과)

  • 이종근;윤성호
    • Polymer(Korea)
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    • v.25 no.3
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    • pp.359-366
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    • 2001
  • Isothermal physical aging of a glass fiber/epoxy composite was examined at different aging temperatures ($T_a$) and degrees of conversion (monitored by the glass transition temperature, $T_g$) by means of the TBA torsion pendulum technique. The range of aging temperature was from 10 to $130^{\circ}C$ : the conversion was systematically changed from $T_g$=$76^{\circ}C$ to $T_g$=$177^{\circ}C$ (fully crosslinked). The effect of isothermal physical aging was manifested as perturbations of the modulus and mechanical loss vs. temperature in the vicinity of $T_a$ for all conversions. The rate of isothermal physical aging determined from the change of modulus with aging time at fixed aging temperature decreased and then increased with increasing conversion below T$_{a}$=9$0^{\circ}C$. There exists a superposition in aging rate vs. ($T_g$ -$T_a$) by shifting horizontally and vertically. This implies that the physical aging process is independent of the change of chemical structure as conversion proceeds. It has been found that water absorbed at the aging temperature below $70^{\circ}C$ during isothermal physical aging lowers the apparent aging rate. It is due to the absorbed water molecules forming strong polar interactions with hydroxyl group on network chain and reducing the segmental mobility during the physical aging.g.

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Hydrogen Bond Effect on Chain Behavior at the Semidilute Regime of Poly(vinyl alcohol) Aqueous Solution (폴리(비닐 알코올) 수용액의 준희박농도 영역에서 사슬 거동에 대한 수소결합의 효과)

  • Park Il-Hyun;Yu Young-Chol;Park Ki-Sang;Lee Dong-Il;Lyoo Won-Seok
    • Polymer(Korea)
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    • v.30 no.3
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    • pp.271-278
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    • 2006
  • In order to investigate the structure and dynamics of atatic poly (vinyl alcohol) (PVA)/water system, laser light scattering experiment has been done in the semi-dilute concentration regime at $25^{\circ}C$. The scattering intensity I(q) can be analyzed with the fractal equation of $I(q){\sim}q^{-m}$ instead of Onstein-Zernike type equation. The fractal dimensionality m was found to be constant after reaching the plateau value of $m=2.6{\pm}0.3$ above C=3wt%. The time correlation function of dynamic light scattering has always two different modes such as fast mode and slow one. The cooperative diffusion of fast mode showed concentration independence contrary 4o the reptation theory's concentration dependent exponent of 3/4. The slow mode can be interpreted as the motion of large scale heterogeneities and its strong concentration dependence is apparent with a large negative exponent of -3.0. It is considered that the stereo-regular arrangement with four successive meso units of -OH plays as a key role in forming such heterogeneity.

Residual Stress Behavior and Physical Properties of Colorless and Transparent Polyimide Films (무색 투명 폴리이미드 박막의 잔류응력 거동 및 특성분석)

  • Nam, Ki-Ho;Lee, Wansoo;Seo, Kwangwon;Han, Haksoo
    • Polymer(Korea)
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    • v.38 no.4
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    • pp.510-517
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    • 2014
  • A series of polyimide (PI) was prepared by reacting 4,4'-(hexafluoroisopropylidene)-diphthalic anhydride (6FDA) as the anhydride and bis(3-aminophenyl) sulfone (APS), bis[4-(3-aminophenoxy)-phenyl] sulfone (BAPS), 2,2-bis(4-aminophenyl)-hexafluoropropane (6FPD), 2,2-bis[4-(4-aminophenoxy)-phenyl]hexafluoropropane (6FBAPP), 2,2'-bis(trifluoromethyl)benzidine (TFDB), or 1,4-phenylenediamine (PDA) as the diamine. Residual stress behaviors were detected in-situ during thermal imidization of the polyimide precursors using a thin film stress analyzer (TFSA), and interpreted with respect to their morphology. According to the molecular orientation and packing order, the residual stress varied from 23.1 to 12.5 MPa, decreased with increasing chain rigidity. The thermal properties of the PI films were investigated using differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), and thermomechanical analysis (TMA). Their optical properties were measured by ultraviolet-visible spectrophotometer (UV-vis), and spectrophotometry. The properties of PI films were found to be strongly dependent upon the morphological structure. However, trade-offs between residual stress and optical properties were identified.

Examination of Color Difference in Elastic Pavement that uses EPDM Chip using Ultraviolet Ray Accelerated Weathering Test (자외선 촉진 내후성 시험에 의한 EPDM Chip을 사용한 탄성포장의 색차분석)

  • Hong, Chang Woo
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.31 no.1D
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    • pp.91-98
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    • 2011
  • Recently, the usage of elastic paving using EPDM Chip instead of pedestrian sidewalk blocks or permeable concrete used mostly for pedestrian walk, trails and in parks has been increassed as it can absorb impact during walking and produce wide range of colors and designs. However, the properties of EPDM Chip including elasticity and durability are decreased when exposed to ultraviolet ray and scenic paving functions through various colors are lowered due to the yellowing phenomenon. In this study, ultraviolet ray accelerated weathering test has been conducted to analyze the color changes in EPDM Chip and polyurethane resin, which are the main ingredients of elastic paving, when exposed to ultraviolet ray. The color differences are quantitatively analyzed through the color value coordination of the colored space by using the color difference scheme. The experimental results show that the color changes in BL polyurethane resin which is used most frequently at present was larger than that of EPDM Chip. Moreover, the total color difference, ${\Delta}E$, of BC polyurethane resin are 3.162 on the $14^{th}$ day of commencement of acceleration, which is 6 times greater color change resistance against ultraviolet ray than that of BL polyurethane resin with total color difference of 20.639. Therefore, the usage of BC polyurethane resin, which is manufactured to have chain-type molecular structure by using the isocyanate as the HMDI at the time of producing polymer, as binder in elastic paving with EPDM Chip is found to be a highly efficient method of restraining the color changes due to the ultraviolet ray.

Molecular Monitoring of Eukaryotic Plankton Diversity at Mulgeum and Eulsukdo in the Lower Reaches of the Nakdong River (낙동강 하류 물금과 을숙도 수환경의 진핵 플랑크톤 종조성에 대한 분자모니터링)

  • Lee, Jee Eun;Lee, Sang-Rae;Youn, Seok-Hyun;Chung, Sang Ok;Lee, Jin Ae;Chung, Ik Kyo
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.17 no.3
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    • pp.160-180
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    • 2012
  • We have studied the eukaryotic plankton species diversity to compare the community structure of fresh and brackish waters in the lower reaches of the Nakdong River using metagenomic methods. We constructed 18S rDNA clone libraries of total DNAs extracted from environmental water samples collected at Mulgeum (MG100929, fresh) and Eulsukdo bridge (ES, brackish). Through the steps of colony PCR, PCR-RFLP, sequencing and similarity analysis, we discovered the diverse species composition of eukaryotic plankton. Total 338 clones (170 at MG100929 and 168 at ES) were analyzed, and then we found 74 phylotypes (49 for MG100929 and 25 for ES). From the phylogenetic analysis, we confirmed various eukaryotic plankton of broad range of taxonomic groups, including Stramenopiles, Cryptophyta, Viridiplantae, Alveolata, Rhizaria, Metazoa, and Fungi. We also found several unreported species in Korea and candidates of new taxonomic entities at levels higher than genus. Especially, the cryptic species diversity including unreported phylotypes of Pirsonia (Stramenopiles) and Perkinsea (Alveolata) suggests that the molecular monitoring method can produce new informative biological data in monitoring the changes in the Nakdong River Mouth ecosystem.

Inhibitory Effects of β-Cyclodextrin-Helenalin Complexes on H-TERT Gene Expression in the T47D Breast Cancer Cell Line - Results of Real Time Quantitative PCR

  • Ghasemali, Samaneh;Nejati-Koshki, Kazem;Akbarzadeh, Abolfazl;Tafsiri, Elham;Zarghami, Nosratollah;Rahmati-Yamchi, Mohamad;Alizadeh, Effat;Barkhordari, Amin;Tozihi, Majid;Kordi, Shirafkan
    • Asian Pacific Journal of Cancer Prevention
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    • v.14 no.11
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    • pp.6949-6953
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    • 2013
  • Background: Nowadays, the encapsulation of cytotoxic chemotherapeutic agents is attracting interest as a method for drug delivery. We hypothesized that the efficiency of helenalin might be maximized by encapsulation in ${\beta}$-cyclodextrin nanoparticles. Helenalin, with a hydrophobic structure obtained from flowers of Arnica chamissonis and Arnica Montana, has anti-cancer and anti-inflammatory activity but low water solubility and bioavailability. ${\beta}$-Cyclodextrin (${\beta}$-CD) is a cyclic oligosaccharide comprising seven D-glucopyranoside units, linked through 1,4-glycosidic bonds. Materials and Methods: To test our hypothesis, we prepared ${\beta}$-cyclodextrin-helenalin complexes to determine their inhibitory effects on telomerase gene expression by real-time polymerase chain reaction (q-PCR) and cytotoxic effects by colorimetric cell viability (MTT) assay. Results: MTT assay showed that not only ${\beta}$-cyclodextrin has no cytotoxic effect on its own but also it demonstrated that ${\beta}$-cyclodextrin-helenalin complexes inhibited the growth of the T47D breast cancer cell line in a time and dose-dependent manner. Our q-PCR results showed that the expression of telomerase gene was effectively reduced as the concentration of ${\beta}$-cyclodextrin-helenalin complexes increased. Conclusions: ${\beta}$-Cyclodextrin-helenalin complexes exerted cytotoxic effects on T47D cells through down-regulation of telomerase expression and by enhancing Helenalin uptake by cells. Therefore, ${\beta}$-cyclodextrin could be superior carrier for this kind of hydrophobic agent.

Theoretical Considerations on Analytical Framework Design for the Interactions between Participants in Group Argumentation on Socio-Scientific Issues (사회 속 과학 쟁점에 대한 소집단 논변 상호작용 분석을 위한 방법론 고찰)

  • Park, Jee-Young;Kim, Heui-Baik
    • Journal of The Korean Association For Science Education
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    • v.32 no.4
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    • pp.604-624
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    • 2012
  • This study aims to design a framework for analyzing group argumentation in terms of participants' interaction. Regarding the current group argumentation setting as argumentation on socio-scientific issues within participants who have had limited experience on group argumentation, the analytical framework was designed to explain (1) what was each participant's role on group argumentation, (2) how these roles were changed within each time of argumentation, and (3) how the patterns of interaction were changed through seven times of a series of argumentation on socio-scientific issues. Based on the literature review on analytical framework of argumentation in science education including the works on the structure of argumentation, the discourse formation through interaction, and the linguistic approach on participants' interaction, the current research framework was built. Showing the results of applying the designed framework on group argumentation as an example, strength of using the current designed framework was discussed.