• Journal of the Korean Ceramic Society
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• v.49 no.1
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• pp.1-10
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• 2012

Super-plastic deformation that originates from transformation plasticity has favorable aspects for steels with improved strength and ductility. However, it also causes undesirable deformation of products or specimens, leading to their degradation. This article reviews recent investigations of transformation plasticity. A combination of newly suggested models, numerical analyses, and novel experiments has attempted to reveal the mechanism. Since the nature of the transformation plasticity is still unclear, there are significant challenges still to be solved. Fundamental understanding of transformation plasticity will be essential for the development of advanced steels.

• Journal of the Korean Ceramic Society
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• v.26 no.4
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• pp.493-498
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• 1989

High purity, submicron BaTiO3 powder was prepared by a hydrothermal technique using Ba(OH)2.8H2O, TiCl4 and NH4OH as starting raw materials. The submicron BaTiO3 powder was synthesized at 130~23$0^{\circ}C$ for 2.5h to yield highly crystalline particles with a narrow particle distribution. The mole ratio of Ba(OH)2.8H2O/TiO(OH)2 was 1.5. It is possible to obtain BaTiO3 with Ba : Ti=1.00$\pm$0/01. The samples densified well at 13$25^{\circ}C$, showing a uniform and fine grain structure. The grain size ranged between 0.3 and 0.5${\mu}{\textrm}{m}$. The products obtained by hydrothermal treatment at various temperatures from 130 to 23$0^{\circ}C$ were characterized by XRD, DTA, BET and SEM etc.

• Journal of the Korean Ceramic Society
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• v.33 no.2
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• pp.235-241
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• 1996

Self-Propagating high temperature synthesis(SHS) technique was used to synthesize the spinel phase of MgAl2O from MgO and Al powder. Processing factors such as mixing time preheating temperature and ignition catalyst were varied to determine the optimum condition to form MgAl2O4 phase. The reaction products were heat treated at the temperature range of 120$0^{\circ}C$ and 150$0^{\circ}C$. to observe phase transformation of unreacted materials. Processing factors such as 48 hrs-mixing 80$0^{\circ}C$-preheating and 20wt% KNO3-ignition catalyst were effective of the formation of MgAl2O spinel. An activation energy 49.7kcal/mol. was calculated to form a MaAl2O4 spinel from unreacted materials.

• The Korean Journal of Ceramics
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• v.3 no.3
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• pp.195-198
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• 1997

Post-firing process of electronic ceramic, such as electroding and encapsultion with resin, often causes damage by thermal shock. The thermal shock behavior of $BaTiO_3$ ceramics was investigated by the down-quench test, where the relative strength retained is determined after the sample is quenched from an elevated temperature into a fixed temperature bath. The critical temperature drop, $\DeltaTc$, was evaluated for three kinds of sintered $BaTiO_3$ ceramics, which were formed by extrustioin, uniaxial pressing using granules, and uniaxial pressing using powders. A drastic loss in strength caused by microcracking was observed for the specimens quenched with $\DeltaT\geq150^{\circ}C$. This concentp can be adopted as a method of the quality control by monitoring the sudden drop of the strength of capacitor products after each exposure to heat.

• Journal of the Korean Ceramic Society
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• v.32 no.11
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• pp.1301-1307
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• 1995

Pitting corrosion of TiN film deposited on Inconel 600 by plasma assisted chemical vapor deposition (PACVD) was investigated. Cyclic potentiodynamic polarization (CPP) tests were conducted in order to determine the pit nucleation potentials, Enp, of the TiN-deposited sample and the bare Inconel 600 in deaerated NaCl solution at 25, 135 and 20$0^{\circ}C$. The effects of the TiN film thickness, the solution temperature and the Cl- concentration on Enp were studied. Enp of the TiN-deposited sample which had the film thickness above 1${\mu}{\textrm}{m}$ were higher than those of the bare Inconel 600 by 300~600mV at all the solution temperatures, implying the pitting resistance improvement of the TiN film. The morphologies of the pits generated after immersion test were examined with a scaning electron microscopy. The higher was the solution temperature, the more corrosion products, mainly composed of Cr and Ni oxides, were formed.

• Journal of the Korean Ceramic Society
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• v.32 no.9
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• pp.1085-1091
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• 1995

Molybdenum disilicide (MoSi2) was synthesized from Mo, MoO3, Si and Al powders by self-propagating high temperature synthesis (SHS). The effect of processing parameters such as Mo/MoO3 molar ratio, Ar gas pressure in the reactor and pressing pressure of compacts in synthesis of MoSi2 were investigated. h-MoSi2 was transformed into t-MoSi2 with increasing the Mo/MoO3 mole ratio, and only t-MoSi2 phase was identified above 3.5 : 1 (molar ratio). The synthesized phases did not change with the variation of Ar gas pressure and pressing pressure of compacts. It was found that the combustion temperature was above 2,50$0^{\circ}C$. The products were separated into MoSi2 (s) and $\alpha$-Al2O3 by the difference of their specific grativities. Bending strength, hardness and density of sintered specimen exhibited 82 MPa, 5.368 GPa and 5.43 g/㎤, respectively.

• Journal of the Korean Ceramic Society
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• v.23 no.4
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• pp.35-40
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• 1986

The production process of a fine size fraction of Korean kaolin by ball milling is studied in this paper by analyzing the size distribution the size distribution of products with the Rosin-rammle formular and the rate process of cumulative size fractions with Alyavdin-Chujyo's formular. The size distribution is found to be divided in three regions a coarser part influenced by feed size an intermediate part where the size distribution shows a clear straight line relationship on Rosin-Rammler chart and the finest part with the ultimate limit of fineness by ball milling. Alyavdin-Chujyo's relationship is found to be valid over a very wide range of milling conditions. For different feed sizes the Alyavdin-Chujyo's relationship gives a group of straight lines with a common intersection point which can be defined as the limiting point of the persistent component region.

• Journal of the Korean Ceramic Society
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• v.28 no.1
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• pp.74-78
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• 1991

Willemite powders which have been prepared by solid state reaction were easy to intermixed impurities, and particle surfaces were demaged in the progress of crushing. The above defacts were easy to accompany non-crystallization for mechanochemical effects and luminescence efficiency was deteriorated. The goal of this study improve each of defacts, and synthesize high purity and fine Mn doped willemite powders by wet and hydrothermal methods without crushing progress. It has been experimentally verified that the single phase Zn1.98Mn0.02SiO4 willemite powders which prepared by hydrothermal synthes is at 220$^{\circ}C$ for 10 hours in 2N KOH solution. The products are like needle and composition is the same with starting composition.

• Journal of the Korean Ceramic Society
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• v.35 no.11
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• pp.1227-1232
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• 1998

In order to prohibit the delay of early stage hydration activator Na2SO4 was added to Fly Ash blended ce-ment and its effects were investigated. Various measurements such as Compressive strength Heat of hy-dration Pore size distribution Hydration products Microstructure were evaluated and the results show that specimens of Fly Ash(50wt%) with 5% Na2SO4 dramatically improved the compressive strength because pozzolanic reaction of Fly Ash and the formation of ettringite make th microstructure denser than OPC and flyash cement paste.

• Journal of the Korean Ceramic Society
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• v.36 no.8
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• pp.820-828
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• 1999

This study suggests the accurate method to calculate dominant wavelength and excitation purity which are used for analyzing color of glass product. Instead of ruler and magnified chromatricity diagram by using the slope of lines by tristimulus measured and achromatic timulus and by monochromatiic stimulus and achromatic stimulus calculating method of dominant wavelength and excitation purity was acquired with the relation between them. When it was applied to products the obtained results were more accurate than those from existing methods.