• Korean Chemical Engineering Research
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• 제46권5호
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• pp.983-987
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• 2008

IGCC 파일럿 플랜트의 집진시스템을 최적 설계하기 위하여 수치해석을 수행하였다. 서로 다른 가스 유입 방식이 집진용기 내부의 유체 유동장과 입자 거동에 미치는 영향을 분석하였다. 필터 표면에 전달되는 입자의 부하율은 분진입자가 혼합된 가스가 내부에 차단관이 설치된 집진용기의 외벽에 접하게 설치된 접선 유입구를 따라 집진용기 내로 유입되는 경우 아주 낮았으며, 입자크기가 클수록 입자부하율은 급격히 감소하였다. 이에 반하여, 가스 유동이 집진용기의 필터지지판 중앙에 수직하게 설치된 수직 유입구를 통하여 집진용기 내로 유입되는 경우, 필터 표면으로의 입자 부하율이 아주 높았으며, 입자크기 증가에 따른 입자부하율의 감소는 접선 유입 방식에 비하여 크지 않았다.

• Journal of Ceramic Processing Research
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• 제20권6호
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• pp.589-596
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• 2019

Pigments with minute particle sizes, such as carbon black (CB) and pigment red 48:2 (P.R.48:2), are the most important types of pigment and have been widely used in many industrial applications. However, minute particles have large surface areas, high oil absorption and low surface energy. They therefore tend to be repellent to the vehicle and lose stability, resulting in significant increases in viscosity or reaggregation in the vehicle. Therefore, finding the best way to improve the dispersion properties of minute particle size pigments presents a major technical challenge. In this study, minute particle types of CB and P.R.48:2 were treated with nitrogen gas plasma generated via radio frequency-plasma enhanced chemical vapor deposition (RF-PECVD) to increase the dispersion properties of minute particles in deionized (DI) water. The morphologies and particle sizes of untreated and plasma treated particles were evaluated using scanning electron microscopy (SEM) and atomic force microscopy (AFM). The average distributions of particle size were measured using a laser particle sizer. Fourier transform infrared spectroscopy was carried out on the samples to identify changes in molecular interactions during plasma processing. The results of our analysis indicate that N2 plasma treatment is an effective method for improving the dispersibility of minute particles of pigment in DI water.

• 한국군사과학기술학회지
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• 제5권2호
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• pp.207-216
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• 2002

In this paper, the study on the behavior of the deformation of brittle material, such as concrete, ceramic, was peformed by comparison of Lagrangian technique and Smoothed Particle Hydrodynamics using commercial nonlinear hydrodynamic numerical program, Autodyn_2D. The effect of SPH technique was proved by investigating the behavior of material deformation, velocity profile and pressure profile.

• 대한기계학회논문집A
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• 제35권9호
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• pp.1035-1040
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• 2011

본 논문은 세라믹과 금속파우더를 이용한 복합소재를 플라즈마 용사 방식으로 개발한 결과를 수록하였다. 사용된 세라믹 파우더는 $Al_2O_3+40TiO_2$ 이고 입자 크기는 $20{\mu}m$, $Al_2O_398+$파우더의 입자 크기는 $45{\mu}m$를 사용하였다. $20{\mu}m$, $30{\mu}m$ 및 $50{\mu}m$ 금속필터 입자는 SIKA-R 20IS, 30IS 및 50IS(소결금속필터)을 사용 했으며, $75{\mu}m$ 금속필터 입자는 5 겹 소결메쉬 필터를 사용��다. 용사 공정으로 가공된 복합 필터는 세라믹 파우더의 종류, 크기 및 코팅 두께에 따라 성능의 차이를 보였으나, 전반적으로 필터링 가능 능력은 향상되었다.

• 마이크로전자및패키징학회지
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• 제6권1호
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• pp.11-21
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• 1999

For microelectronic packaging application, the crystallizable glass powder in CaO-$A1_2O_3-SiO_2-B_2O_3$system was mixed with various amounts of alumina inclusions (\approx 4 $\mu \textrm{m}$), and its sintering behavior, crystallization behavior, and dielectric constant were examined in terms of vol% of alumina and the reaction between the alumina and the glass. Sintering of the CASB glass powder alone at $900^{\circ}C$ resulted in full densification (99.5%). Sintering of alumina-filled composite at $900^{\circ}C$ also resulted in a substantial denslfication higher than 97% of theoretical density, In this case, the maximum volume percent of alumina should be less than 40%. XRD analysis revealed that there was a partial dissolution of alumina into the glass. This alumina dissolution, however, did not show the particle growth and shape accommodation. Therefore, the sintering of both the pure glans and the alumina-filled composite was mainly achieved by the viscous flow and the redistribution of the glass. Alumina dissolution accelerated the crystallization initiation time at $1000^{\circ}C$ and hindered the densification of the glass. Dielectric constants of both the alumina-filled glass and the glass-ceramic composites were increased with increasing alumina content and followed rule of mixture. In case of the glass-ceramic matrix composites showed relatively lower dielectric constant than the glass matrix composite. Furthermore, as alumina content increased, crystallization behavior of the glass was changed due to the reaction between the glass and the alumina. As alumina reacted with the glass matrix, the major crystallized phase was shifted from wollastonite to gehlenite. In this system, alumina dissolution strongly depended on the particle size: When the particle size of alumina was increased to 15 $\mu\textrm{m}$, no sign of dissolution was observed and the major crystallized phase was wollastonite.

• 한국세라믹학회지
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• 제55권3호
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• pp.275-284
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• 2018

In the ball milling process of ceramic powders, according to economic considerations for industrial applications, it is very important to quickly determine the optimum process condition with the maximum grinding efficiency. However, it is still difficult to determine the optimum condition for a ball mill with respect to the various process parameters, such as the rotational speed and the milling time. Ball milling was carried out at the same starting conditions with given amounts of alumina powders, balls and water, and was conducted slower or faster or a critical rotational speed was just determined by observing the angular position of the slurry in a semi-translucent polyethylene laboratory container. With respect to the different rotational speeds, which were slower or faster than the critical rotational speed, the particle size distribution of the grained powders and the acoustic intensity caused by cascading of the balls led to various behaviors. From the results of the particle size distribution and the acoustic signal analysis in the ball milling, there was one rotational speed that made the finest milled powder with maximum acoustic intensity. As a result, there was a correlation between the ground particle size and the acoustic intensity, which yields the interpretation that it can be possible in-situ to determine the optimum condition of ball milling by acoustic signal without repeated measurement efforts.

• 한국세라믹학회:학술대회논문집
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• 한국세라믹학회 2004년도 추계총회 및 연구발표회 초록집
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• pp.96.4-96.4
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• 2004

• 한국세라믹학회지
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• 제46권1호
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• pp.69-73
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• 2009

We report the preparation of nanocrystalline cobalt ferrite, $CoFe_2O_4$ particles and their surface coating with silica layers using micro emulsion method. The cobalt ferrite nanoparticles with the size 7nm are firstly prepared by thermal decomposition method. Hydrophobic nanoparticles were coated with silica using micro-emulsion method with surfactant, $NH_4OH$, and tetraethylorthosilicate (TEOS). Monodispersed and spherical silica coated cobalt ferrite nanoparticles have average particle diameter of 38 nm and narrow sized distribution.

• 한국세라믹학회지
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• 제24권4호
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• pp.349-356
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• 1987

${\beta}$-Sialon powder was synthesized by the simultaneous reduction and nitridation of Hadong kaolin at 1350$^{\circ}C$ in N2-H2 atmosphere, using graphite as a reducing agent. The synthesized ${\beta}$-Sialon powder was pressurelessly sintered over 1450-1850$^{\circ}C$ in nitrogen atmosphere. The average particle size of ${\beta}$-Sialon powder was about 4.5$\mu\textrm{m}$. The relative density, M.O.R., fracture toughness and micro-hardness of ${\beta}$-Sialon ceramics sintered at 1800$^{\circ}C$ for 1 hour were 92%, 36 kpsi, 2.8MN/㎥/2 and 13.3 GN/㎡, respectively. The critical temperature difference (ΔT) in water quench thermal shock behavior showed about 375$^{\circ}C$ for the synthesized ${\beta}$-Sialon ceramics.

• 한국세라믹학회지
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• 제47권6호
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• pp.633-637
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• 2010

In this study, lithium manganese oxide spinel ($LiMn_{1.9}Fe_{0.1}Nb_{0.0005}O_4$) as a cathode material of lithium ion secondary batteries is synthesized with spray drying, and in order to increase its crystallinity and electrochemical properties, the granulated $LiMn_{1.9}Fe_{0.1}Nb_{0.0005}O_4$ particle surface is coated with lithium titanium oxide spinel ($Li_4Ti_5O_{12}$) through a sol-gel method. The granulated particles present a higher tap density and lower specific surface area. The crystallinity and discharge capacity of the $Li_4Ti_5O_{12}$ coated material is relatively higher than uncoated material. With the coating layer, the discharge capacity and cycling stability are increased and the capacity fading is suppressed successfully.