• Journal of the Korean Ceramic Society
• /
• v.26 no.4
• /
• pp.521-531
• /
• 1989

The dependence of the chemical durability of simulated waste glasses containing the simplified waste similar to the SRP waste on compositions of host glasses, amounts of waste loading, and kinds of leachants has been investigated as a basic study on the waste immobilization through vitrification. The maximum limit of the amount of waste loading for glassforming with the host sodium borosilicate glasses selected in this study was 50wt%. The chemical durability of waste glasses whose host glass belonged to the immiscible composition region was much higher than that of waste glasses whose host glass belonged to the miscible composition region. The former waste glass showed lower chemical durability in deionized and silicate waters than in brine, while the latter glass showed the lowest chemical durability in deionized and silicate waters than in brine, while the latter glass showed the lowest chemical durability in silicate water. It was also observed that the total leaching rates in brine were noticeably small in comparison with those in other solutions. The composition of the host borosilicate glass which was suitable for the treatment of the waste through vitrification was found to be 25 Na2O-5B2O3-70SiO2(wt.%).

• Journal of the Korean Ceramic Society
• /
• v.29 no.10
• /
• pp.765-772
• /
• 1992

As the fundamental research of preparation of fine single crystalline ferroxplana by means of glass-crystallization methods using steel twin-roller the properties of ferroxplana extracted from cyrstallized glass were studied. Most of all the specimens quenched by twin-roller at about 1350$^{\circ}C$ were glass phase, the crystallization of these glass had multi-steps and ferroxplana phase was only stable untill 900$^{\circ}C$, began to be decomposed from about 950$^{\circ}C$ in glass. The morphology of particle could be controlled by the composition and crystallization condition, and Zn2+ was replaced by reduced Fe2+ which is 2∼3% contents of total Fe. Ferroxplana extracted had such magnetic properties as Ms=34 emu/g, mHc=10 Oe and Curie Temperature, Tc=425K.

• Journal of the Korean Ceramic Society
• /
• v.52 no.2
• /
• pp.133-136
• /
• 2015

The outward diffusion of $Na^+$ ions in iron-bearing soda lime silicate glass via oxidation heat treatment before the ion exchange process is artificially induced in order to increase the amount of ions exchanged during the ion exchange process. The effect of the addition process is analyzed through measuring the bending strength, the weight change, and the inter-diffusion coefficient after the ion exchange process. The glass strength is increased when the outward diffusion of $Na^+$ ions via oxidation heat treatment before the ion exchange process is added. For the glass subjected to the additional process, the weight change and diffusion depth increase compared with the glass not subjected to the process. The interdiffusion coefficient is also slightly increased as a result of the additional process.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
• /
• v.29 no.8
• /
• pp.489-493
• /
• 2016

In this study, the effect of vanadium oxide ($V_2O_5$) content and pre-sintering atmosphere on sealing property of glass frit that consisted of $V_2O_5-BaO-ZnO-P_2O_5-TeO_2-CuO-Fe_2O_3-SeO_2$ was investigated by XPS (X-ray photoelectron spectroscopy). The content of V2O5 was changed to 15, 30, and 45 mol%, and the pre-sintering was carried out in air and $N_2$ condition, respectively. XPS analysis conducted before and after laser irradiation with identical sample. Before laser treatment, glass frits that were pre-sintered at air condition showed both $V^{4+}$ and $V^{5+}$, but the valence state was changed to $V^{5+}$ after laser irradiation when the glass frits contained 30 and 45 mol% $V_2O_5$; this change led to non-adhesive property. On the other hand, glass frits that were pre-sintered at $N_2$ condition exhibited only $V^{4+}$ and it showed fine adhesion irrespective of the $V_2O_5$ content. As a result, the existence of $V^{4+}$ seems to be a major factor for controlling the adhesive property of glass frit for laser sealing.

• Journal of the Korean Ceramic Society
• /
• v.47 no.5
• /
• pp.467-473
• /
• 2010

The objective of this study is to prepare lead-free thick film resistor (TFR) paste compatible with AlN substrate for hybrid microelectronics. For this purpose, CaO-ZnO-$B_2O_3-Al_2O_3-SiO_2$ glass system was chosen as a sintering aid of $RuO_2$. The effects of the weight ratio of CaO to ZnO in glass composition, the glass content and the sintering temperature on the electrical properties of TFR were investigated. $RuO_2$ as a conductive and glass powder were dispersed in an organic binder to obtain printable paste and then thick-film was formed by screen printing, followed by sintering at the range between $750^{\circ}C$ and $900^{\circ}C$ for 10 min with a heating rate of $50^{\circ}C$/min in an ambient atmosphere. The addition of ZnO to glass composition and sintering at higher temperature resulted in increasing sheet resistance and decreasing temperature coefficient of resistance. Using $RuO_2$-based resistor paste containing 40 wt%glass of CaO-20.5%ZnO-25%$B_2O_3$-7%$Al_2O_3$-15%$SiO_2$ composition, it is possible to produce thick film resistor on AlN substrate with sheet resistance of $10.6\Omega/\spuare$ and the temperature coefficient of resistance of 702ppm/$^{\circ}C$ after sintering at $850^{\circ}C$.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
• /
• v.20 no.1
• /
• pp.19-24
• /
• 2007

The effects of $B_2O_3-SiO_2-R(R;CaO,\;BaO,\;ZnO,\;Bi_2O_3)$ borosilicate glass system on the sintering behavior and microwave dielectric properties of ceramic/glass composites were investigated as functions of modifier, glass addition ($30{\sim}50\;vol%$) and sintering temperature ($500{\sim}900^{\circ}C$ for 2 hrs). The addition of 50 and 45 vol% glass ensured successful sintering below $900^{\circ}C$. Sintering characteristics of the composites were well described in terms of modifier. Borosilicate glass enhanced the reaction with $Al_{2}O_{3}$ to form pores, second phases and liquid phases, which was responsible to component of modifier. Dielectric constant (${\varepsilon}_{r},\;Q{\times}f_{o}$) and temperature coefficient of resonant frequency (${\tau}_{f}$) of the composite with 50 and 45 vol% glass contents($B_{2}O_{3}:SiO_{2}:R=25:10:65$) demonstrated A-CaBS(7.8, 2,560 GHz, -81ppm/$^{\circ}C$), A-BaBs(5.8, 3.130 GHz, -64 ppm/$^{\circ}C$), A-ZnBS(5.7, 17,800 GHz, -21 ppm/$^{\circ}C$), A-BiBs(45 vol% glass in total)(8.3, 2,700 GHz, -45 ppm/$^{\circ}C$) which is applicable to substrate requiring an low dielectric properties.

• Journal of the Korean Crystal Growth and Crystal Technology
• /
• v.20 no.1
• /
• pp.43-52
• /
• 2010

Glass was fabricated by using refused coal ore obtained from Dogye coal mine in Samchuk. We additionally used soda ash and calcium carbonate as raw materials to make a glass with the chemical composition of soda-lime glass. And the properties of glass were measured when limestone was used as natural raw materials instead of calcium carbonate as chemical raw materials. Transparent glass was fabricated by melting raw materials at $1550^{\circ}C$ for 1 hr in an electrical furnace. The various kinds of glass samples were fabricated according to the kinds of refused coal ore and glass cullet. The optical properties of transmittance and color chromaticity were measured by UV/VIS/NIR spectrometer and the thermal properties of thermal expansion coefficient and softening point were measured. Transparent glass with the transmittance of over 70% in visible range was fabricated by using normal refused coal ore and black colored glass with the transmittance of 0~35% was fabricated by using shel1 type refused coal ore. Therefore, it is concluded that refused coal ore can be used for raw materials to manufacture secondary glass products such as a glass tile and foamed glass panel for construction material.

• Journal of the Korean Ceramic Society
• /
• v.44 no.2 s.297
• /
• pp.110-115
• /
• 2007

The effects of $TiO_2$ in the glasses on the shrinkage and dielectric properties of BNT-glass composites have been investigated. Without $TiO_2$ addition, BNT-glass composite showed two humps in the shrinkage curve, which are related with crystallization of $BaTi(BO_3)_2\;and\;Bi_4Ti_3O_{12}$. However, the increase of $TiO_2$ addition resulted in the decrease of 2nd hump in the shrinkage. The increased dielectric constant with $TiO_2$ addition might be due to the reduced crystallization of $Bi_4Ti_3O_{12}$. A dielectric constant of 52, a quality factor of 5088 GHz, and a temperature coefficient of resonant frequency of $-0.16ppm/^{\circ}C$ were obtained for a specimen containing $TiO_2$-added glasses, without sacrificing the benefits of high ${\varepsilon}_r$ and low TCF of BNT ceramics.

• 한국신재생에너지학회:학술대회논문집
• /
• 2011.11a
• /
• pp.88.1-88.1
• /
• 2011

SOFC는 사용되는 셀의 디자인에 따라 튜브형, 평판형으로 구분되어진다. 평판형의 경우에는 전해질 지지형(ESC), Anode 지지형(ASC) 및 금속 지지형(MSC)로 크게 나눌 수 있다. SOFC 스택은 이와 같은 셀과 밀봉재, 집전체, 분리판의 구성요소를 여러 장으로 적층하여 이루어진다. SOFC 발전시스템은 SOFC 스택과 EBOP, MBOP로 구성되는데, SOFC 발전시스템의 상용화를 위해 선행되어야 할 것은 스택의 안정적 출력 및 신뢰성 확보이다. 즉, 셀, 밀봉재, 분리판 및 집전체로 대변되는 구성요소들이 스택에 장착되었을 때 그 기능을 최대한 발휘하면서도 점진적 또는 급격한 품질저하가 발생되지 말아야 한다. 특히, 밀봉재의 경우 SOFC에 사용되는 연료와 공기의 혼합(Cross-over)을 방지하는 중요한 기능을 담당하고 있으며 여러 장 적층된 분리판의 전기적 단락을 방지해야 한다. 또한 SOFC의 특성상 $700^{\circ}C$ 이상의 고온에서 다른 구성요소와 화학적 반응이 없어야하고 열싸이클(Thermal cycle)을 견딜 수 있도록 충분한 기계적 강도가 보장되어야 하는 등 요구되는 품질기준이 엄격하다. SOFC의 밀봉재는 접합형(Brazing), 압착형(Compressive), 용융-고정형(Glass-ceramic)이 대표적으로 적용되고 있다. 이 중에서 Brazing 물질과 방법은 현재 활발히 연구가 수행 중에 있지만 범용적으로 사용되고 있지는 않은 상태이고 Compressive 밀봉재와 Glass-ceramic 밀봉재가 대면적 SOFC 스택에 사용되어 적용 가능성을 평가받고 있다. 본 연구에서는 SOFC 구성요소의 국산화를 추진하는 지경부과제의 결과물 중 (주)써모텍에서 개발한 Glass-ceramic 밀봉재(RC1) 단품에 대한 특성평가와 실제 단전지 평가를 통해 SOFC 스택 적용 가능성을 평가하였다. 밀봉재 단품에 대한 특성평가는 용융특성, 상분석, 열팽창계수 등의 물리적, 화학적 평가 외에 가스 누설 정도를 평가하는 기밀도 평가와 SOFC의 작동 온도인 $700^{\circ}C$와 상온 분위기를 주기적으로 인가하는 Thermal cycle 특성을 평가하였다. 셀을 한 장 사용하는 단전지(Unit cell) 평가는 RIST에서 자체 제작한 $100{\times}100mm^2$ 평판형 ASC 셀을 사용하여 수행하였으며, 밀봉재는 Dispensing 공정을 통해 구성되었다.

• Journal of Technologic Dentistry
• /
• v.40 no.1
• /
• pp.9-15
• /
• 2018

Purpose: The purpose of this study is to investigate the effect of lithium disilicate glass ceramic polishing on the strength of the final prosthesis. Methods: Fourteen lithium disilicate glass ceramic specimens were prepared. These were randomly divided into two groups of seven(LPG: low polishing group, HPG: high polishing group). In LPG, SiC paper was sequentially polished using 300, 600, 800, 1000 grit, and the specifications of the test piece were adjusted. HPG was sequentially polished using 300, 600, 800, 1000, 1200, 1500, and 2000 grit. Two groups of specimens are executed 3- point bending test. Using the statistical program SPSS 22.0, the average values of the strengths of the two groups were compared in the Mann-Whiteney test. The significance level was set at 0.05. Results: The mean strength value of HPG was measured at $307.14{\pm}23.28MPa$ significantly higher than LPG(p<0.001). Conclusion : The final polishing of the prosthesis is aesthetically important but has proven to play an important role in the flexural strength, early fracture, and prolongation of the prosthesis.