• Title/Summary/Keyword: Ceramic

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Phase Formation and Thermo-physical Properties of GdO1.5-ZrO2 System for Thermal Barrier Coating Application (열차폐코팅용 GdO1.5-ZrO2계 희토류 지르코네이트 세라믹스의 상형성과 열물리 특성)

  • Kim, Sun-Joo;Lee, Won-Jun;Kwon, Chang-Sup;Lee, Sung-Min;Oh, Yoon-Suk;Kim, Hyung-Tae;Im, Dae-Soon;Kim, Seongwon
    • Journal of the Korean Ceramic Society
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    • v.51 no.6
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    • pp.554-559
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    • 2014
  • Gadolinium zirconate, $Gd_2Zr_2O_7$, is one of the most promising candidates for replacing yttira-stabilized zirconia (YSZ) in thermal barrier coating (TBC) applications due to its low thermal conductivity and chemical stability at high temperature. In this study, rare-earth zirconate ceramics in the $GdO_{1.5}-ZrO_2$ system with reduced gadolinia contents were fabricated via solid-state reaction as well as hot-pressing at $1800^{\circ}C$. The phase formation, microstructure, and thermo-physical properties of these oxides were examined. The potential application of $GdO_{1.5}-ZrO_2$ ceramics for TBC was also discussed.

Thermal Property of 2D-Disordered Tungsten Chalcogenides (2차원적으로 무질서화된 텅스텐 칼코겐화물의 열적특성에 관한 연구)

  • Kim, Jong-Young;Jang, Kyoung-Ju;Pee, Jae-Hwan;Cho, Kwang-Yeon;Choi, Soon-Mok;Seo, Won-Sun;Kim, Kyung-Ja
    • Journal of the Korean Ceramic Society
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    • v.47 no.2
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    • pp.132-135
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    • 2010
  • Thermal properties of layered metal chalcogenides such as $WT_2$ (T=S,Se) with two-dimensionally disordered structure were evaluated. Thermal conductivity shows a marked decrease after exfoliation and subsequent restacking because of random stacking of two-dimensional crystalline sheet, which circumvents thermal conduction pathways along longitudinal direction in anisotropic materials.

Recent Trend of Esthetic All-Ceramic Materials and Guidelines for Correct Cementation (올세라믹 심미 수복재료의 최신 동향과 적합한 시멘트 선택 및 사용)

  • Park, Yeong-Joon
    • The Journal of the Korean dental association
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    • v.58 no.7
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    • pp.413-434
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    • 2020
  • Recently, there are much improvement in optical and mechanical properties of dental ceramic materials coupled with improved fabrication techniques, which have caused a considerable shift in the preference of the dentists to ceramic restorations. Because the chemical composition and microstructure of all-ceramic materials are different by the type, correct choice of cement type and surface treatment procedure, and cementation strategy is essential for the success of ceramic restorations with adequate retention and decreased incidence of complications. This manuscript reviews on the most often prescribed and some newly developed ceramic materials, and the selection criteria and usage guidelines of cement materials that are used in conjunction with various ceramic materials. This manuscript emphasizes that continuous updating the information of newly developed ceramic and cement materials and application techniques by the dentists and dental staffs are demanding in response to the constantly improving ceramic and cement materials and corresponding application protocol changes.

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A Making of Aesthetic Dental restorations with Nano Hybrid Ceramic material by CAD/CAM System (치과 CAD/CAM용 Nano Hybrid Ceranic 소재를 이용한 심미 치과보철물의 제작)

  • Choi, Beom-jin
    • Journal of the Korean Academy of Esthetic Dentistry
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    • v.25 no.2
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    • pp.98-108
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    • 2016
  • In recent days, perhaps the biggest driver in new material development is the desire to improve restorations esthetics compared to the traditional metal substructure based ceramics or all-ceramic restorations. Each material type performs differently regarding strength, toughness, effectiveness of machining and the final preparation of the material prior to placement. For example, glass ceramics are typically weaker materials which limits its use to single-unit restorations. On the other hand, zirconia has a high fracture toughness which enables multi-unit restorations. This material requires a long time sintering procedure which excludes its use for fast chair side production. Hybrid ceramic material developed for CAD/CAM system is contained improved nano ceramic elements. This new material, called a Resin Nano Hybrid Ceramic is unique in durability of function and aesthetic base compositions. The new nano-hybrid ceramic material is not a composite resin. It is also not a pure ceramic. The material is a mixture of both and consists of nano-ceramic fillers. Like a composite, the material is not brittle and is fracture resistant. Like a glass ceramic, the material has excellent polish retention for lasting esthetics. The material is easily machined by chair side or in a dental lab side, could be an useful restorative option.

Assessment of Bacteria Removal Using Silver Ion Absorbed Ceramic Filter

  • Kim, Woo-Hang;Smith, James
    • Journal of Environmental Science International
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    • v.21 no.8
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    • pp.901-907
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    • 2012
  • The objective of this study was to evaluate bacteria removal ability of the metallic silver which was baked silver ion impregnated ceramic filter at heating condition. Silver leaking from baked ceramic filter was tested to sustain bacteria removal for a long time. Silver impregnated ceramic filter could remove E. coli completely at $10^{12}$ MPN/100ml to $10^{13}$ MPN/100ml of influent. However, ceramic filter without silver did not remove E. coli completely under the same condition. After baking, the silver impregnated ceramic filter almost didn't leak out the silver ion from filter. Photo of TEM (Transmission Electron Microscopy) showed that absorbed silver ions remained in ceramic filter after baking process and most of silver were less than 10 nm. According to the increase in the amount of silver in the ceramic filter, removal efficiencies of E. coli were increased but turbidity removal was decreased. It can be accounted that increased removal efficiency of E. coli was from disinfection of silver that is in the ceramic filter. Simulated concentrations of bacteria agree well with the observed experimental effluent concentration data. Moreover, first-order decay coefficients increased to 0.0034/min after silver was added in the ceramic filter. Increase of first-order decay coefficient proves that silver-added ceramic filter can remove bacteria easily.

Silica Coating of Nanosized CoFe2O4 Particles by Micro-emulsion Method (마이크로에멀젼법을 이용한 나노 CoFe2O4 분말의 실리카 코팅)

  • Kim, Yoo-Jin;Yu, Ri;Park, Eun-Young;Pee, Jae-Hwan;Choi, Eui-Seok
    • Journal of the Korean Ceramic Society
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    • v.46 no.1
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    • pp.69-73
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    • 2009
  • We report the preparation of nanocrystalline cobalt ferrite, $CoFe_2O_4$ particles and their surface coating with silica layers using micro emulsion method. The cobalt ferrite nanoparticles with the size 7nm are firstly prepared by thermal decomposition method. Hydrophobic nanoparticles were coated with silica using micro-emulsion method with surfactant, $NH_4OH$, and tetraethylorthosilicate (TEOS). Monodispersed and spherical silica coated cobalt ferrite nanoparticles have average particle diameter of 38 nm and narrow sized distribution.

Optimization of Binder Burnout for Reaction Bonded Si3N4 Substrate Fabrication by Tape Casting Method

  • Park, Ji Sook;Lee, Hwa Jun;Ryu, Sung Soo;Lee, Sung Min;Hwang, Hae Jin;Han, Yoon Soo
    • Journal of the Korean Ceramic Society
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    • v.52 no.6
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    • pp.435-440
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    • 2015
  • It is a challenge from an industrial point of view to fabricate silicon nitride substrates with high thermal conductivity and good mechanical properties for power devices from high-purity Si scrap powder by means of thick film processes such as tape casting. We characterize the residual carbon and oxygen content after the binder burnout followed by nitridation as a function of the temperature in the temperature range of $300^{\circ}C-700^{\circ}C$ and the atmosphere in a green tape sample which consists of high-purity Si powder and polymer binders such as polyvinyl butyral and dioctyl phthalate. The optimum condition of binder burnout is suggested in terms of the binder removal temperature and atmosphere. If considering nitridation, the burnout of the organic binder in air compared to that in a nitrogen atmosphere could offer an advantage when fabricating reaction-bonded $Si_3N_4$ substrates for power devices to enable low carbon and oxygen contents in green tape samples.

Fabrication and Characterization of Silica Coated Fe3O4 Nanoparticles in Reverse Micro Emulsion (마이크로에멀젼법을 이용하여 실리카 코팅된 나노 Fe3O4 분말의 합성과 분석연구)

  • Yu, Ri;Kim, Yoo-Jin;Pee, Jae-Hwan;Hwang, Kwang-Taek;Yang, Hee-Seung;Kim, Kyung-Ja
    • Journal of the Korean Ceramic Society
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    • v.47 no.2
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    • pp.113-116
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    • 2010
  • The silica coated $Fe_3O_4$ nanoparticles have been synthesized using a micro-emulsion method. The $Fe_3O_4$ nanoparticles with the sizes 6 nm in diameter were synthesized by thermal decomposition method. Hydrophobic $Fe_3O_4$ nanoparticles were coated silica using surfactant and tetraethyl orthosilicated (TEOS) as a $SiO_2$ precursor. Shell thickness of silica coated $Fe_3O_4$ can be controlled (11~20 nm) through our synthetic conditions. The $Fe_3O_4$ and silica coated $Fe_3O_4$ nano powders were characterized by transmission electron microscopy (TEM), x-ray diffraction (XRD) and vortex magnetic separation (VMS).