• Title/Summary/Keyword: Cement solidification

검색결과 114건 처리시간 0.024초

Study on Water Resistance of Environmentally Friendly Magnesium Oxychloride Cement for Waste Wood Solidification

  • Zhang, Feng-Jun;Sun, Xian-Yang;Li, Xuan;Zhang, Dan;Xie, Wen- Jie;Liu, Jin;Oh, Won-Chun
    • 한국세라믹학회지
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    • 제55권5호
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    • pp.446-451
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    • 2018
  • In this study, different formulations of magnesium oxide and various modifiers (phosphoric acid, ferrous sulfate, pure acrylic emulsion, silicone acrylic emulsion, glass fiber, and polypropylene fiber) were used to prepare magnesium oxychloride cement composites. The compressive strength of the magnesium oxychloride cement was tested, and the softening coefficients of the composites after soaking in water were also calculated. The results showed that a magnesium oxychloride cement sample could not be coagulated when the MgO activity was 24.3%, but the coagulation effect of the magnesium oxide cement sample was excellent when the MgO activity was 69.5%. While pure acrylic emulsion, silicon-acrylic emulsion, and glass fiber showed insignificant modification effects on the magnesium oxychloride cement, ferrous sulfate heptahydrate, phosphoric acid, and polypropylene fiber could effectively improve its water resistance and compressive strength. When the phosphoric acid, ferrous sulfate heptahydrate, and polypropylene fiber contents were 0.47%, 0.73%, and 0.25%, respectively, the softening coefficient of a composite soaked in water reached 0.93 after 7 days, and the compressive strength reached 64.3 MPa.

순환자원을 활용한 지반고화용 무기결합재의 강도 특성 (Strength Characteristics of Solidified Soil with Binder made of Industrial By-products)

  • 안양진;형원길;문경주;윤성진
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2012년도 추계 학술논문 발표대회
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    • pp.213-214
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    • 2012
  • This study is about the assessment of utilization possibility as a material for cementation of ground which is necessary for the reinforcement of soft ground by making environment-friendly inorganic composite utilizing inorganic recycled resources, and it was verified that it showed higher uniaxial compressive strength than the existing cementitious ground solidifier when it was applied as a combination material for soft ground such as dredge reclaimed land, and since an inorganic composite utilizing recycled resources such as high calcium fly ash and blast furnace slag etc. does never use cement, it is considered that it would be safe in the issue of a hexavalent chromium that was recognized as a problem of a cementitious solidifier.

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Recycling of In-site waste soil material to fill a hollow between PHC pile and Earthen wall

  • Jang, Myung-Houn;Choi, Hee-Bok
    • 한국건축시공학회지
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    • 제12권5호
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    • pp.510-517
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    • 2012
  • This study evaluated the recycling potential of in-site waste soil as pile back filling material (PBFM). We performed experiments to check workability, segregation resistance, bond strength, direct shear stress test, and dynamic load test using in-site waste soil in coastal areas. We found that PBFM showed better performance than general cement paste in terms of workability, segregation resistance, and bond strength. On the other hand, the structural performance of PBFM was slightly lower than that of general cement paste due to the skin friction force of pile by Pile Driving Analyzer and direct shear stress. However, because this type of performance degradation in terms of structure can be improved through the use of piles with larger diameter or by changing the type of pile, considering the economics and environment, we considered that recycling of PBFM has sufficient value.

Safety Assessment for the Landfill Disposal of Decommissioning Waste Solidified by Magnesium Potassium Phosphate Cement

  • Jeong, Jongtae;Baik, Min-Hoon;Lee, Jae-Kwang;Pyo, Jae-Young;Um, Wooyong;Heo, Jong
    • 방사성폐기물학회지
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    • 제20권1호
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    • pp.13-22
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    • 2022
  • The decommissioning of a nuclear power plant generates large amounts of radioactive waste, which is of several types. Radioactive concrete powder is classified as low-level waste, which can be disposed of in a landfill. However, its safe disposal in a landfill requires that it be immobilized by solidification using cement. Herein, a safety assessment on the disposal of solidified radioactive concrete powder waste in a conceptual landfill site is performed using RESRAD. Furthermore, sensitivity analyses of certain selected input parameters are conducted to investigate their impact on exposure doses. The exposure doses are estimated, and the relative impact of each pathway on them during the disposal of this waste is assessed. The results of this study can be used to obtain information for designing a landfill site for the safe disposal of low-level radioactive waste generated from the decommissioning of a nuclear power plant.

시멘트계 주입재 종류별 주입 특성 및 환경적 영향 연구 (The Injection Characteristics and Environmental Effects for Grouting Materials Based on Cement)

  • 천병식;이재영;서덕동
    • 한국지반공학회논문집
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    • 제19권2호
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    • pp.159-170
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    • 2003
  • 본 연구에서는 재료분야에서 최근의 기술동향인 고강도.고침투성.고내구성 및 환경에 대한 안정성이 높은 주입재료의 배합설계를 실시하여 주입목적, 지반조건에 따른 주입효과와 환경적 영향성을 분석.검토함으로써 현장적용시 주입설계의 기초자료로 제안하고자 한다. 주입재의 물리, 역학.화학적 특성 및 입자형상을 파악하고 작업성과 침투범위 조정에 필수적인 겔타임을 조정하였다. 또한 실내모형시험을 통하여 고결성, 침투성 및 내구성 평가를 수행하였다. 환경적 영향평가를 위해 본 연구에서 사용된 재료는 현장에서 일반적으로 사용되는 보통포틀랜드시멘트, 고로슬래그시멘트와 초미립자시멘트를 사용하였다. 시멘트계 그라우트재에서의 6가 크롬의 용출특성을 판단하기 위해 원재료의 6가크롬 함유량 시험과 pH변화에 따른 6가크롬의 용출변화량 시험 그리고 그라우트가 적용되는 주변환경에 따른 특성파악을 위해 호모겔을 제작하여 양생수를 각각 초순수, 침출수로 하여, 양생수에 따른 그라우트 호모겔의 일축압축강도 및 6가크롬 용출량의 변화를 시험하였다.

방사성 폐기물 고화재 활용을 위한 재생시멘트의 수화반응성 평가 (Evaluation of Hydration Reactivity of Recycled Cement for the Utilization of Radioactive Waste Solidifying Materials)

  • 최유진;김지현;정철우
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2022년도 가을 학술논문 발표대회
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    • pp.167-168
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    • 2022
  • Recently, starting with the permanent suspension of Gori 1 in Korea, the importance of the disposal of concrete structures in nuclear power plants has emerged, and environmental and safety are required to be proved accordingly. Safe radioactive waste disposal technology that immobilizes harmful radioactive elements, which are by-products of nuclear power, inside a solid matrix and recycling measures are needed to secure an efficient waste disposal space. This study was conducted to confirm whether recycled cement generated in the process of radioactive concrete treatment can be used as a solidifying material for radioactive waste treatment. In order to simulate the concrete exposed to radiation, aqueous solutions of Di-water, CsCl 1M, and CoCl2 1M were used as blending water at W/B 0.5. Tricalcium phosphate and Prussian blue were substituted with 5 wt.% based on the weight of recycled cement as a binder to improve solidification performance, and their hydration characteristic was analyzed.

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$CaO-Al_{2}O_{3}-SiO_{2}$계 제강슬래그를 이용한 하수슬러지 고화체 물성연구 (Properties for Solidification of Sewage Sludge by Steelmaking Slag with $CaO-Al_{2}O_{3}-SiO_{2}$ system)

  • 이훈하;손진군;이박석;조규용
    • 한국자원리싸이클링학회:학술대회논문집
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    • 한국자원리싸이클링학회 2006년도 춘계임시총회 및 제27회 학술발표대회
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    • pp.150-155
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    • 2006
  • 제강공정에서 발생되는 $CaO-Al_{2}O_{3}-SiO_{2}$계 조성을 갖는 2 차 정련슬래그 (래들 슬래그)를 이용하여 하수슬러지용 고화재개발 및 하수슬러지 고화체의 물성에 관한 연구를 수행하였다. 래들슬래그는 냉각과정에서 분화되는 성질이 있어 냉각후 분말상의 슬래그가 만들어진다. 분말상 슬래그의 주 결정상은 $12CaO{\cdot}7Al_{2}O_{3}$$2CaO{\cdot}SiO_{2}$로 구성되어 있다. $12CaO{\cdot}7Al_{2}O_{3}$ 상은 속경성 시멘트의 특징이 있다. 또한 $CaSO_{4}$와 혼합사용시 ettringite 상을 형성시켜 하수슬러지의 함수율 저감효과 및 강도발현 효과가 우수한 결과를 얻었다. $Cl^{-}$ 이온의 고정화면에서는 고화재중 래들슬래그의 혼합비가 높을수록 고화체 구조내에 $Cl^{-}$ 이온이 고정화되어 용출량은 감소하였다. 고화재로서 제강부산물을 사용하기 때문에 경제성이 있으며, $Cl^{-}$ 이온 함량이 높은 하수슬러지 고화재로서의 재활용이 기대된다.

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농축폐기물 유리화를 위한 전처리 방안 연구 (Study on Pre-treatment Method for Vitrification of Concentrated Wastes)

  • 조현제;김득만;박종길
    • 방사성폐기물학회지
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    • 제8권3호
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    • pp.221-227
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    • 2010
  • 가압경수로 원전 농축폐액건조설비(CWDS)에서 생성된 농축폐액건조물에 대한 고화 방안이 국내외적으로 다양하게 연구되어 왔다. 농축폐액의 고형화는 시멘트, 파라핀 및 폴리머와 같은 고화제를 이용하여 수행되어 왔다. 동시에 농축폐액에 대한 감용비 및 운영상의 효과를 극대화하기 위한 농축폐액건조물 전처리 방안이 연구되었다. 건조된 분말 형태의 폐기물을 유리화 설비에서 직접 처리할 경우 비산에 의한 배기체 계통 및 폐기물 투입구 막힘 현상을 초래할 수 있으며, 취급 중 비산에 의한 방사성피폭을 초래할 가능성이 있다. 본 연구는 분말형태의 폐기물을 유리화설비에서 고화하기 위한 전처리방안을 수립하고 이를 통해 설비운영 및 폐기물 운영관리의 안전성을 확보하는데 목적이 있다.

롤 컴팩션을 이용한 분말 방사성폐기물의 펠렛화 연구 (A Study on the Pelletization of Powdered Radioactive Waste by Roll Compaction)

  • 송종순;임상현;정민영;김기홍
    • 방사성폐기물학회지
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    • 제17권2호
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    • pp.203-212
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    • 2019
  • 처분 부적합 폐기물이란 원전운영이나 해체 시 처리, 고화 및 포장이 요구되는 방사성폐기물 등을 일컬으며, 대표적으로 분산 특성을 갖는 입자성 방사성폐기물을 예로 들 수가 있다. 이들 폐기물에는 원전 운영과정에서 발생되는 농축폐액의 건조분말, 슬러리 및 슬러지, 향후 원전 해체과정에서 발생되는 온갖 분말 상태의 폐기물(콘크리트 파쇄물, 제염 슬러지 등), 그리고 제염이 용이치 못한 미세 크기의 방사능오염 토양 등이 있다. 입자성 폐기물을 기존의 고화방식으로 처리할 경우에는 최종 폐기물의 부피가 증가하는 단점을 갖게 되어 처분 비용의 증가 및 처분장의 수용성을 감소하는 결과를 야기할 수가 있다. 따라서 이들 문제를 해결하고자 본 연구에서는 최종 폐기물 부피의 감용화를 위해 롤 압축 기술을 이용하여 분말의 펠렛화 연구를 수행하였다.

Experimental study on nano silica modified cement base grouting reinforcement materials

  • Zhou, Fei;Sun, Wenbin;Shao, Jianli;Kong, Lingjun;Geng, Xueyu
    • Geomechanics and Engineering
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    • 제20권1호
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    • pp.67-73
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    • 2020
  • With the increasing number of underground projects, the problem of rock-water coupling catastrophe has increasingly become the focus of safety. Grouting reinforcement is gradually applied in subway, tunnel, bridge reinforcement, coal mine floor and other construction projects. At present, cement-based grouting materials are easy to shrink and have low strength after solidification. In order to overcome the special problems of high water pressure and high in-situ stress in deep part and improve the reinforcement effect. In view of the mining conditions of deep surrounding rock, a new type of cement-based reinforcement material was developed. We analyses the principle and main indexes of floor strengthening, and tests and optimizes the indexes and proportions of the two materials through laboratory tests. Then, observes and compares the microstructures of the optimized floor strengthening materials with those of the traditional strengthening materials through scanning electron microscopy. The test results show that 42.5 Portland cement-based grouting reinforcement material has the advantages of slight expansion, anti-dry-shrinkage, high compressive strength and high density when the water-cement ratio is 0.4, the content of bentonite is 4%, and the content of Nano Silica is 2.5%. The reinforcement effect is better than other traditional grouting reinforcement materials.