• Proceedings of the Korean Fiber Society Conference
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• 2001.04b
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• pp.55-58
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• 2001

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.43 no.2
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• pp.40-48
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• 2011

To build up the conservativeness of aged paper heritages, the strength reinforcement treatment using various cellulose derivative solutions was considered. Hand-made Hanji prepared by traditional papermaking technique was firstly simulated in order to modify the overall of paper properties like aged paper heritages by accelerated ageing treatment at $150^{\circ}C$ for 24 hours, and then the ageing stability of Hanji was verified through the secondary accelerated ageing at $150^{\circ}C$ for 12 hours. The physical properties of aged Hanji were improved by applying with cellulose derivative solutions. The ageing stability for physical, optical (L, brightness, opacity, yellowness) and chemical (oxidation index, degree of polymerization) properties of aged Hanji treated with all kinds of cellulose derivative solutions was also good compared to those of untreated samples, especially using MC solution. Therefore, it was that a kind of MC solution would be well-suited for the strength reinforcement treatment of aged paper heritages.

• Proceedings of the Korean Fiber Society Conference
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• 2001.10a
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• pp.215-218
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• 2001

이산화탄소($CO_2$)를 사용한 셀룰로오스 카보네이트 유도체의 제조 및 재생 셀룰로오스 섬유 제조와 관련한 기초 연구성과를 이미 발표한 바 있다[1~3]. 이번 연구에서는 일정한 조건에서 제조된 셀룰로오스 카보네이트 유도체의 용해온도, 셀룰로오스 카보네이트 함량, 10% 수산화나트륨 수용액내의 산화아연의 함량 변화에 따른 용해성을 평가하여 상그림표를 작성하였다. (중략)

• Journal of the Korean Society of Clothing and Textiles
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• v.24 no.7
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• pp.1081-1087
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• 2000

Gromwell colorants were extracted with methanol and dried. Four fractions were obtained by silica gel adsorption column chromatography using step-wise elution method. Relative ratio of four fraction is 1.00:0.07:0.22:0.30(Fl:F2:F3:F4) and gromwell colorants mainly consist of Fl, F3 and F4. IR analysis shows that each fraction has similar structure. Main component of gromwell extracts is acetyl derivative of naphthoquinone, and the rest are isobutyl derivative and isovaleryl derivative etc., in order. Gromwell colorants exhibit relatively good affinity to protein and polyamide fibers, but low affinity to cellulose and regenerated cellulose fibers.

• Elastomers and Composites
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• v.31 no.2
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• pp.122-129
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• 1996

The Thermal decomposition of the ${\alpha}-Cellulose$ and NaCl was studied using a thermal analysis technique in the steam of nitrogen gas with 30ml/min at various heating ranges from 4 to $20^{\circ}C/min$. The Derivative and Integral method used to be obtained values of activation energy of decomposition reaction. 1. The values of activation energy evaluated by Derivative and Intergral method were consistent with each other very well. 2. The maximum value of heat of decomposition evalated by DSC method was ${\alpha}-Cellulose/NaCl= 90/10$. 3. The thermogravimetric trace curve agreed with the theoretical equation.

• Bulletin of the Korean Chemical Society
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• v.28 no.6
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• pp.999-1004
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• 2007

Spherical porous silica supports modified with titanium or zirconium alkoxides were prepared, and allyl groups were chemically attached to the titanized or zirconized silica supports, and the product was cross-polymerized with a double bond containing cellulose derivative to yield new CSPs (chiral stationary phases). Magic angle spinning 13C solid state NMR and elemental analysis were used to characterize the CSPs. The performances of the chiral stationary phases were examined in comparison with a conventional chiral stationary phase. Spherical porous silica particles modified with 3,5-dimethylphenylcarbamate of cellulose were prepared and used as the conventional chiral stationary phase. Chromatographic data were collected for a few pairs of enantionmers in heptane/2-propanol mixed solvents of various compositions with the three chiral columns and the results were comparatively studied. The separation performance of the chrial phase made of the titanized silica was better than the others, and the separation performance of the chiral phase of the zirconized silica was comparable to that of the conventional chiral phase. The superiority of titanized silica over bare or zirconized silica in chiral separation seemed to be owing to the better yield of crosslinking (monitored by increase of carbon load) for titanized silica than for the others.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2005.11a
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• pp.9-12
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• 2005

Molecular characteristics and rheological properties of cellulose acetate butyrate (CAB), cellulose acetate propionate (CAP) and nitrocellulose (GC-519) which are being widely used as propellants were investigated. Their weight-average molecular weight (Mw) and number-average molecular weight (Mn) were estimated via Gel Permeartion Chromatograpy (GPC). Cellulose derivatices were mixed with di-n-propyl adipate (DNPA) which acted as plasticizer in acetone, and then rheological properties of the mixture of cellulose derivatives and this plasticizer in acetone were investigated at $0^{\circ}C$ by rheometer.

• Proceedings of the Korean Fiber Society Conference
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• 2003.04a
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• pp.299-300
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• 2003

본 연구자들은 이산화탄소($CO_2$)에 의한 셀룰로오스 카보네이트의 제조 및 재생 셀룰로오스 섬유 제조에 대한 몇몇 기초 연구성과를 발표한 바 있다[1, 2]. 이번 연구에서는 이산화탄소와의 반응을 통해 제조된 셀룰로오스 카보네이트 유도체의 치환도 변화에 따른 용해성을 평가하고 상그림표를 작성하였다. (중략)

• Journal of the Korean Society of Clothing and Textiles
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• v.21 no.7
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• pp.1196-1204
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• 1997

Cotton, rayon/cotton, and Tencel twill weave fabrics were used to investigate the effect of fiber types on the cellulase washing finish. And twill. basket, and derivative weave cotton fabrics were used to study the weave effect. Various fabrics were treated with neutral cellulase varying treatment times and with acid cellulase, stone, and stone-neutral cellulase respectively for two hours in a rotary washer. Weight loss decreased in the order of rayon/cotton> cotton> Tencel, and basket and derivative weave fabrics lost more weight than twill weave fabric. Color difference decreased in the order of cotton> Tencel> rayon/cotton, and twill weave fabric had larger color difference than derivative and basket weave fabrics. Back staining decreased in the order of cotton> rayon/cotton> Tencel, and twill weave fabric had larger back staining than derivative and basket weave fabrics. Tear strength retention decreased in the order of rayon/cotton> cotton> Tencet and twill weave fabric had larger tear strength retention than derivative and basket weave fabrics. Flex stiffness retention decreased in the order of cotton> Tencel> rayon/cotton, and in the order of derivative> twill> basket weave. In cotton fibers, damage of primary wall was observed. And the cellulase treatment on Tencel seemed to roughen the fabric surface slightly, and to fibril fibers along the fiber axis.

• Journal of the Korean Wood Science and Technology
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• v.49 no.4
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• pp.287-298
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• 2021

Torch ginger (Etlingera elatior Jack) is a potential source of lignocellulose material for various derivative products. This study aims to determine the chemical components, ratio of syringyl to guaiacyl units (S/G) in lignin, and crystallinity of the biomass of torch ginger. The effects of soda pulping on the chemical characteristics of torch ginger pulp were also studied. Pulping of the chips was conducted with active alkali of 15%, 20%, and 25% and a Liquor-to-Wood (L/W) ratio of 4:1, 5:1, and 6:1. The impregnation and pulping times at maximum temperature (170℃) were 120 and 90 min, respectively. To assess the effect of treatments on the properties of pulping, a two-factorial experimental design was applied. Results showed that the content of α-cellulose and hemicellulose in the torch ginger was 48.48% and 31.50%, respectively, with an S/G ratio of 0.70 in lignin. Soda pulping changed the crystalline structure of the biomass from triclinic to monoclinic. Active alkali, L/W ratio, and interactions considerably influenced the observed responses. The degree of delignification increased with an increase in the loading of active alkali, which lead to a decrease in the kappa number of the pulp. An active alkali content of 25% and an L/W ratio of 6:1 resulted in the highest delignification selectivity with a kappa number of 2.78 and a yield of 24%. Given its cellulose content and ease of pulping, torch ginger can be a potential raw material for derivative products that require delignification as pretreatment. However, the increase in cellulose crystallinity should be considered when converting torch ginger to bioethanol.