• Title/Summary/Keyword: Cellulose Paper

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A Study on The Spontaneous Ignition of a Hydroxy Propyl Methyl Cellulose Dust Cloud (Hydroxy Propyl Methyl Cellulose 분진의 운상자연발화에 관한 연구)

  • Lim, Woo-Sub;Mok, Yun-Soo
    • Journal of the Korean Society of Safety
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    • v.19 no.1
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    • pp.137-140
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    • 2004
  • The minimum ignition temperature at which the dust cloud can spontaneously ignite is considered to be very important in industries to prevent explosion occurring in hot surfaces. This paper has dealt with the experimental study of the determination of minimum ignition temperature of Hydroxy Propyl Methyl Cellulose (HPMC) dust cloud. We have used the Godbert-Greenwald Furnace Apparatus to determine the ignition temperature and limiting oxyten concentration for dust could. The experimental determinations on the minimum ignition temperature were carried out with various particle size with nominal diameters 45, 75 and 106${\mu}m$. The limiting oxygen concentration of dust cloud was determinated for the smaller size(45${\mu}m$) HPMC. Minimum ignition temperature of dust cloud was at 364$^{\circ}C$ for the concentration of 2.5g/L in the air and became higher with the increasing of nitrogen concentration. It was also found that the ignition didn't occur when the oxygen concentration was below 10%, and limiting oxygen concentration is at 11%.

Study on Accelerated Aging Characteristics of Paper-Records by Air Pollutants (종이 기록물의 대기 중 유해물질에 의한 가속 열화 특성 연구)

  • Park, Mi-Seon;Jeong, So-Yoon;Hwang, Ji-Hyun;Kim, Hyoung-Jin;Kim, Shin-Do
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.46 no.4
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    • pp.76-84
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    • 2014
  • Preventive conservation is one of most important issues in the field of conservation for paper-records. Many researchers have been studied environmental factors such as effects of humidity, temperature, biological attack and air pollutants. Air pollutants strongly associated with oxidative and hydrolytic degradation of cellulose. It is important to control air pollutants in storage environment to improve stabilities of conservation environment. Four paper samples have been analyzed for their accelerated aging characteristics by air pollutants, sulfur dioxide, nitrogen dioxide, ozone, carbon monoxide. Physical and optical properties and weight molar masses(Mw) showed that interactions between air pollutants and paper sample. Nitrogen dioxide, ozone caused severe damage to cellulose in paper by hydrolytic and oxidative decompositions during aging.

Copy Paper as a Platform for Low-cost Sensitive Glucose Sensing

  • Ye Lin Kim;Young-Mog Kim;Junghwan Oh;Joong Ho Shin
    • Journal of Sensor Science and Technology
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    • v.32 no.1
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    • pp.16-21
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    • 2023
  • This study reports the potential of using commercial copy papers as substrates for simple sensitive glucose detection. Typical paper-based devices use filter papers as porous substrates that can contain reagents; however, this is the first study to report the use of copy papers for the purpose of enhancing enzymatic colorimetric detection. Glucose detection using glucose oxidase, horseradish peroxidase and potassium iodide was performed on a copy paper, cellulose-based filter paper, and polyethylene film. The results indicated that the copy paper exhibited a stronger coloration than the other substrates. Reagents required for detection were dried on the copy paper, and a 3D-printed holder was designed to provide an environment for consistent imaging, making it a convenient cost-effective option for point-of-care testing using a mobile phone camera. The simple paper-based glucose sensor exhibited a linear range of 0.1-20 mM, limit of quantification of 0.477 mM, and limit of detection of 0.143 mM.

Characteristics of Cellulose Aerogel Prepared by Using Aqueous Sodium Hydroxide-urea (Sodium Hydroxide-urea 수용액을 이용하여 제조한 셀룰로오스계 에어로겔의 특성)

  • Kim, Eun-Ji;Kwon, Gu-Joong;Kim, Dae-Young
    • Journal of the Korean Wood Science and Technology
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    • v.41 no.4
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    • pp.302-309
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    • 2013
  • The highly porous cellulosic aerogels were prepared by freeze-drying method using sodium hydroxide-urea aqueous solution in the process of dissolution, gelation, regeneration and organic solvent substitution. The structural characteristics of porous aerogel were analyzed using scanning electron microscopy and nitrogen adsorption apparatus. As a result, the dissolving pulp was completely dissolved, but filter papers and holocellulose were divided into two layers (dissolved and undissolved parts) in the process of centrifugation. The structure of aerogel from dissolved pulp showed porous pores in the surface and net-shaped network in the inner part. Aerogels from filter paper and holocellulose had the condensed porous network surface and the open-pore nano-fibril network inner structure. Undissolved form of fibers was observed in the aqueous solution of aerogel from holocellulose. The BET value ($S_{BET}$) of aerogel from dissolved pulp was ranged in 260~326 $m^2/g$, and it was decreased with the increase of concentration. Whereas, the $S_{BET}$ value of aerogel from filter paper (198~418 $m^2/g$) was increased with the increase of concentration. The $S_{BET}$ value of aerogel from holocellulose were 137 $m^2/g$ at 2% (w/w) of cellulose, and it was increased to maximum 401 $m^2/g$ at 4% (w/w) of cellulose. Then, it was decreased at 5% (w/w) of cellulose.

Thermal Property and Fire Resistance of Cellulose Insulation (섬유질 단열재의 열적 특성 및 내화성능)

  • Kwon, Young-Cheol;Seo, Seong Yeon;Kim, Sung Young
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.9 no.3
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    • pp.203-212
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    • 2005
  • Cellulose insulation is primarily manufactured from recycled newsprint and treated with fire retardants for the fire resistance. Thanks to the fire retardants, it is not combustible and flammable. In addition to that, Its thermal resistance is much better than that of fiberglass or rock wool. It is made from waste paper and easily decayed when it is demolished, and it has small embodied energy. So it is very environment-friendly building material. For broader use of cellulose insulation in buildings in Korea, it is necessary to test its physical performance to compare the results with the requirements on the Korean Building Code. To this end, apparent thermal conductivity (ka) measurements of Korean-made loose-fill cellulose insulations were recently completed using equipment that was built and operated in accordance with ASTM C 518 and the fire resistance was tested in accordance with ASTM C 1485. Korean loose-fill cellulose has thermal conductivity about 5% greater than the corresponding U.S. product at the same density. This is likely due to differences in the recycled material being used. Both spray-applied and loose-fill cellulose insulation lose about 1.5% of their thermal resistivity for $5.5^{\circ}C$ increase in temperature. The fire resistance of cellulose insulation is increased in linear proportion to the increase of the rate of fire retardant. Thanks to the high fire resistance, cellulose insulation can be used as a substitution of Styrofoam or Urethane foam which is combustible. The thermal conductivity of cellulose insulation was $0.037-0.043W/m{\cdot}K$ at the mean specimen temperature from $4-43^{\circ}C$. It corresponds to the thermal resistance of "Na Grade" according to the Korean Building Code. The effect of chemical content on thermal conductivity was negligible for all but the chemical-free specimen which had the highest value for the thermal conductivity over the temperature range tested. The thermal resistance of cellulose insulation is better than that of fiberglass or rock wool, and its fire resistance is higher than that of Styrofoam or Urethane foam. Therefore it can be substituted for those above considering its physical performance. Cellulose insulation is no more expensive than Styrofoam or rock wool, so it is recommended to use it more widely in Korea.

Mechanism of AKD Sizing Development (AKD의 사이즈 효과 발현기구)

  • Jo, Byoung-Muk;Lee, Don-Sub
    • Journal of Forest and Environmental Science
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    • v.12 no.1
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    • pp.45-56
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    • 1996
  • Generally, it has been know that AKD develops sizing efficiency by forming the chemical bond with cellulose in neutral paper making. However, there have been many expriments in opposition to this theory. This study was carried out to find whether there is chemical bond between AKD and cellulose or not. Also, it was investigated that how much the reacted AKD forming chemical bond and the unreacted AKD contribute to sizing degree respectively if chemical bond presents, and what caused AKD sized paper to migrate under high temperature. Besides, this work experimented several factors having influences on AKD sizing in paper amking.

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Effect on the Crack Resistance of Fiber Reinforced Concrete using Incinerated Paper Mill Sludge Ash (제지(製紙) 슬러지 소각재(燒却滓)를 활용(活用)한 섬유보강(纖維補强)콘크리트의 균열(龜裂) 억제(抑制) 효과(效果))

  • Kim, Nam-Wook
    • Resources Recycling
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    • v.17 no.4
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    • pp.10-20
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    • 2008
  • This study was intended to use an incinerated paper mill sludge ash as cement alternatives in order to derive a method of utilizing the incinerated paper mill sludge ash of low utilization rate in large quantities. Also, the utilization possibility of incinerated paper mill sludge ash as the cement alternative was examined by mixing a polypropylene fiber and cellulose fiber and by considering its control effect for shrinkage cracks caused by an increase of absorption rate and hydration heat, as a weakness shown at the alternation of incinerated paper mill sludge ash.

Strengthening Performance of Aged Papers with Chemical Strengthening Treatments (화학적 보강 방법에 따른 열화 종이의 보강 특성)

  • Lee, Hyeyoon;Lee, Jegon;Kim, Minsu;Sim, Kyujeong;Youn, Hye Jung
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.46 no.5
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    • pp.35-42
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    • 2014
  • Many historical archives have been deteriorated by aging with time. Various kinds of defects such as worm-hole, yellowing, brittleness are observed and their severity was dependent on raw material type, storage condition, and so on. For a long-term use and storage, a proper preservation treatment is required. Many studies on preservation and conservation have been carried out on hanji which was made from mulberry fiber, but there are few concerns on foreign paper. Therefore, aging and chemical strengthening treatment was done on paper made of bamboo and wood fibers depending on aging condition, the type and pickup weight of chemicals and treatment method. When methyl cellulose was treated with impregnation or brushing, the aged paper was strengthened effectively. The strengthening effect by chemicals was dependent on the aged condition of the paper.

창덕궁 소장 지류 및 섬유질유물의 가해생물 분포조사

  • Min, Gyeong-Hui;An, Hui-Gyun;Han, Seong-Hui;Jeong, Hui-Jin
    • 보존과학연구
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    • s.5
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    • pp.148-166
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    • 1984
  • The Investigation of organisms damaged to papers and cellulose materials of Cultural Property in the Ch'ang Dok Palace The investigation of the airborne fungi, the attached fungi to the papers and cellulose materials of Cultural Properties in addition to the insects inhabiting at the Ku Sonwon Jon, Shin Sonwon Jon and Yonwa ch'anggo in the Ch'ang Dok Palace carried out from Jul. 10 to Jul. 21,1984.The results are summarized as follows ;1. Isolation and identification of the airborne fungi from the three storages were Cladosporium sp., Alternaria alternata, As pergillus cervinus, A. flavus, A. nidulance, A. oryzae, A. terreus, A. versicolor, A. wentii, Penicillium adametzii, P.albicans, P.canescens, P. citreo-viride, P. citrinums, P. decumbens, P. frequentans, P. funiculosum, P.herquei, P.implicatum, P.multicolor, P.nigricans, P.nonatum,P.purpurogenum, P.roqueforti, P.viridicatum, Trichodema viride, Geotrichumcandidum, Curvvlaria lunata, Torula hebarum, T.thermophila, Itersoniliasalmonicolor, Drechsclera avenue, Candida sp., Acremonium sp., and Botrytis sp., It was found that thirty five species in thirteen genera was isolated. Among them, the dominant species was Cladosporium sp., and the order was Penicillium, Aspergillus, Alternaria and so on.2. The attached fungi directly isolated from the papers and cellulose materials of Cultural Properties were twenty-nine species in fourteen genera, namely, Acremonium sp., Albertiniella sp., Alternaria alternata, Aspergillus clavatus,A.niger, A.ornatus, A.versicolor, Botrytis sp., Bysochlamys sp., Carpenteles sp.,Chaetomium globosum, Cladosporium sp., Eurotium sp., Mucor sp., Penicilliumcanescens, P.chermesium, P.citrinum, P.frequentans, P.funiculosum, P.herqueiP .implicatum, P.javanicum, P.luteum, P.purpurogenum, P.thomii, P.viridicatum, Torula thermophila, Trichoderma koningi and T.viride. Among them, the mostfungi distributed on the surface of the papers and cellulose materials was Penicillium and the order was Aspergillus, Alternaria, Cladosporium, Trichodermaand so on.3. The insects collected the three storages were ten genera and ten species including 916 specimens. By classifying the insects collected, the most species of the insects was Stenoscelodes hayashii of 857 specimens occupied about 93% of the total insect. And the other insects were collected as Microgamme costipennisAnobium pertinax, Xenomimetes alni, Anthrenus verbasci, Holoparmecus signatus,Thermobia domestica, Halyomorpha brevis, Drosophila coracine and Brattaorientalis. As described above, it could be known that the most airborne fungi was Cladosporium and the order was Penicillium, Aspergillus, Alternaria in the three storages. And the most attached fungi distributed on the surface of papers and cellulose materials was Penicillium and the other fungi were Aspergillus, Alternaria Cladosporium, Trichoderma and so on. Accordingly, from the results, itwas assumed that the major part of airborne fungi were attached to the papers and cellulose materials of Cultural Properties. The paper and cellulose materials of Cultural Properties in Ch'ang Dok Palace were chiefly damaged by S.hayashii in Coleoptera.

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Hydrophilizing Effect of Support on PRO Membrane Performance through Cellulose Solution Treatment (셀룰로오스에 의한 지지체 친수화가 압력지연삼투막 성능에 미치는 영향)

  • Choi, Myungho;Koo, Kee-Kahb;Lim, Jung Ae;Kim, BeomSik
    • Membrane Journal
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    • v.23 no.6
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    • pp.425-431
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    • 2013
  • This paper has studied the hydrophilizing effect of support on the performance of pressure retarded osmosis (PRO). The hydrophilicity of polyester support has been controlled with cellulose solutions. In order to investigate the effect of hydrophilizing of support, the performance test has been conducted with membrane which compose of active layer and support in absence of support layer. The active layer has been made by casting of cellulose tri-acetate (CTA) 1,4-dioxane solution (13 wt%) and combined with the hydrophilized support. The results show that water fluxes of PRO membranes with hydrophobic or hydrophilized support were measured $0.8L/m^2hr$ and $1.2L/m^2hr$ under $5kgf/cm^2$ pressure, respectively. However, water flux increase did not accord with hydrophilicity of supports treated by cellulose solutions. It is because the porosity and pore size of supports decrease as the cellulose concentration increases. This result confirms that both the hydrophilization of support and the maintenance of membrane porosity are important to enhance the performance of PRO membrane.