• 제목/요약/키워드: Cell temperature

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고온형 연료전지의 실용화를 위한 재료 기술 (Material technique for practical use of high temperature fuel cell)

  • 김귀열;윤문수
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1991년도 추계학술대회 논문집
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    • pp.52-55
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    • 1991
  • A fuel cell is a device that directly converts the chemical energy of reatants into low voltage d$.$c electricity. The high temperature fuel cell (MCFC, SOFC)is an excellent electric generator with regard to preservation of the environment and the energy-savings. The purpose of this research is to investigate technical issue and research need for practical use of high temperature fuel cell.

고분자연료전지의 냉각수 운전 조건에 관한 실험적 연구 (An Experimental Study of Coolant Operating Conditions in a Polymer Electrolyte Membrane Fuel Cell)

  • 정성일;김태완;이창건;김두현;안영철;이재근;황유진
    • 설비공학논문집
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    • 제20권8호
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    • pp.541-546
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    • 2008
  • A coolant operating condition in al fuel cell stack was an important factor to determine the temperature distribution which affected the fuel cell performance and relative humidity. In this study, the fuel cell performance was evaluated as a function of the coolant flow rate with the range of $0.1{\sim}0.8$ liter/min cell and the coolant inlet temperature of $20{\sim}82^{\circ}C$. The cell temperature increased with increasing the coolant inlet temperature and with decreasing the coolant flow rate. The coolant inlet temperature and flow rate to maintain the better performance of the fuel cell were in the range of $45{\sim}60^{\circ}C$ and $0.2{\sim}0.4$ liter/min cell, respectively. The experimental results showed that the optimal heat removal rate from the stack by coolant was $0.4{\sim}0.6W/cm^2$ cell.

셀 입구 예열방법에 따른 고체산화물 연료전지/가스터빈 하이브리드 시스템의 성능해석 (Performance Analysis of Solid Oxide Fuel Cell/Gas Turbine Hybrid Systems for Different Cell Inlet Preheating Methods)

  • 양원준;김동섭;김재환
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2004년도 추계학술대회
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    • pp.1664-1669
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    • 2004
  • Design analysis of the solid oxide fuel cell and gas turbine combined power system is performed considering different methods for preheating cell inlet air. The purpose of air preheating is to keep the temperature difference between cell inlet and outlet within a practical design range. Three different methods are considered such as a burner in front of the cell, a preheater in front of the cell and recirculation of the cathode exit gas. Analyses are carried out for two maximum cell temperature differences. The greater temperature difference ensures higher efficiency. The cathode exit gas recirculation exhibits better performance than other methods.

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계란의 저장·보관 조건에 따른 위생적 품질 변화 (Effects of Storage Time and Temperature on the Hygienic Quality of Shell Eggs)

  • 김종규;박정영;김중순
    • 한국환경보건학회지
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    • 제41권6호
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    • pp.438-448
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    • 2015
  • Objectives: This study was performed to examine the effects of storage time and temperature and their interaction on the hygienic quality parameters of shell eggs. Methods: Eggs from 40-week-old Hy-Line Brown hens were sampled immediately after being laid and subjected to storage periods of four weeks at a refrigerated temperature ($4-5^{\circ}C$) or room temperature ($13.0-19.7^{\circ}C$). Interior/exterior qualities were examined every one week. Results: Weight loss was 2.4-3.1%. The initial specific gravity of the eggs was maintained until one week at both temperatures. Air cell size exceeded 4 mm when stored for one week at room temperature, and two weeks at refrigerated temperature. Albumen index and Haugh unit were significantly decreased at both temperatures after one week (p<0.001). Rapidly increased pH of the albumen with one week of storage was observed, regardless of temperature (p<0.001). Extension of the storage for up to four weeks at room temperature resulted in remarkable deterioration of eggshell quality and instrumental color as redness (a). Air cell size, albumen and yolk indices, Haugh unit, pH of albumen and yolk were found to be influenced by storage time and temperature (p<0.001). Interaction effects between storage time and temperature were also significant for air cell size, pH of albumen and yolk (p<0.001). Conclusion: The results suggest that air cell size and pH of albumen and yolk were important parameters influenced by storage time and temperature in shell eggs. Storage time was more influential for air cell size, and temperature for the pH of yolk. Both variables almost equally influenced the pH of albumen.

PVC수치와 온도가 한국재래 산양적혈구 침강에 미치는 영향 (Erythrocyte Sedimentation Rates of Reshuffled Packed Cell Volume in Korean Native Goat)

  • 이수두;김영홍;유창준
    • Current Research on Agriculture and Life Sciences
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    • 제11권
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    • pp.55-59
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    • 1993
  • The packed cell volume(PCV) of Korean native goat, volume percentage of red blood cell in whole blood, was reshuffled of 20%, 40% and 60% using autoplasma, and erythrocyte sedimentation rate was measured in Westergren tubes at room temperature ($27{\pm}1^{\circ}C$) and low temperature ($8{\pm}1^{\circ}C$). The sedimentation rates of red blood cell obtained are summarized as follows. The erythrocyte sedimentation rates of Korean native goat are accelerated more at high temperature than low temperature. The erythrocyte sedimentation rates of reshuffled Korean native goat upon time are almost linear for several hours. The erythrocyte sedimentation rates of Korean native goat are settled faster at low PCV than higher PCV, i. e., there is a reverse relationshif between the erythrocyte sedimentation rate and packed cell volume.

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가온요법을 위한 암조직 세포의 무침습 온도분포 추정에 관한 기초연구 (A Basic Study on the Estimation of Noninvasive Temperature Distribution in Carcinoma Cell for the Hyperthermia)

  • 이면섭;김낙환;홍승홍
    • 대한의용생체공학회:의공학회지
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    • 제7권1호
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    • pp.11-20
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    • 1986
  • In the clincal application of Hyperthermia, tissue temperature measurements are made at only a few selecte4 locations because of patient tolerance and practical clinical limitation. Since it is necessary to know the complete carcinoma cell temperature field in order to treat effectively, The difficulty of making such estimates from only a few point compounded because of the lack of knowledge of the carcinomoma cell blood perfusion characteristics. To solve the temperature on carcinoma cell, A noninvasive method (the finite element method) is used. The simulation results show that the finite element method is promising for estimating the complete corcinoma cell temerature distribution, if some knowledge of the blood perfusion pattern is available.

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Ni-Al-$ZrH_2$ 연료극을 사용한 용융탄산염 연료전지의 온도의 영향 (Effect of operating temperature using Ni-Al-$ZrH_2$ anode in molten carbonate fuel cell)

  • 서동호;장성철;윤성필;남석우;오인환;임태훈;홍성안;한종희
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2010년도 춘계학술대회 초록집
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    • pp.134-134
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    • 2010
  • Fuel cell is a device that directly converts chemical energy in the form of a fuel into electrical energy by way of an electrochemical reaction. In the anode for a high temperature fuel cell, nickel or nickel alloy has been used in consideration of the cost, oxidation catalystic ability of hydrogen which is used as fuel, electron conductivity, and high temperature stability in reducing atmosphere. Most MCFC stacks currently operate at an average temperature of $650^{\circ}C$. There is some gains with decreased temperature in MCFC to diminish the electrolyte loss from evaporation and the material corrosion, which could improve the MCFC life. However, operating temperature has a strong related on a number of electrode reaction rates and ohmic losses. Baker et al. reported the effect of temperature (575 to $650^{\circ}C$). The rates of cell voltage loss were 1.4mV/$^{\circ}C$ for a reduction in temperature from 650 to $600^{\circ}C$, and 2.16mV/$^{\circ}C$ for a decrease from 600 to $575^{\circ}C$. The two major contributors responsible for the change in cell voltage with reducing operation temperature are the ohmic polarization and electrode polarization. It appears that in the temperature range of 550 to $650^{\circ}C$, about 1/3 of the total change in cell voltage with decreasing temperature is due to an increase in ohmic polarization, and the electrode polarization at the anode and cathode. In addition, the oxidation reaction of hydrogen on an ordinary nickel alloy anode in MCFC is generally considered to take place in the three phase zone, but anyway the area contributing to this reaction is limited. Therefore, in order to maintain a high performance of the fuel cell, it is necessary to keep this reaction responsible area as wide as possible, that is, it is needed to keep the porosity and specific surface area of the anode at a high level. In this study effective anodes are prepared for low temperature MCFC capable of enhancing the cell performance by using zirconium hydride at least in part of anode material.

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Synthesis of Pd and Pt Based Low Cost Bimetallic Anode Electrocatalyst for Glycerol Electrooxidation in Membraneless Air Breathing Microfluidic Fuel Cell

  • Panjiara, Deoashish;Pramanik, Hiralal
    • Journal of Electrochemical Science and Technology
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    • 제12권1호
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    • pp.38-57
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    • 2021
  • The different weight ratios of Pd to Pt, i.e., 16:4, 10:10, 4:16 in Pd-Pt/C and Pd (20 wt. %) /C electrocatalysts with low metal loading were synthesized for glycerol electrooxidation in an air breathing microfluidic fuel cell (MFC). The cell performance on Pd-Pt (16:4)/C anode electrocatalyst was found best among all the electrocatalysts tested. The single cell when tested at a temperature of 35℃ using Pd-Pt (16:4)/C, showed maximum open circuit voltage (OCV) of 0.70 V and maximum power density of 2.77 mW/㎠ at a current density of 7.71 mA/㎠. The power density increased 1.45 times when cell temperature was raised from 35℃ to 75℃. The maximum OCV of 0.78 V and the maximum power density of 4.03 mW/㎠ at a current density of 10.47 mA/㎠ were observed at the temperature of 75℃. The results of CV substantiate the single cell performance for various operating parameters.

선박 배기가스 활용에 따른 SOFC 시스템 공급가스의 온도특성에 관한 연구 (A study on temperature characteristic of the gases supplied to SOFC system by utilizing the ship exhaust gas)

  • 박상균
    • Journal of Advanced Marine Engineering and Technology
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    • 제37권8호
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    • pp.822-828
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    • 2013
  • 고체산화물형 연료전지는 운전온도가 고온이기 때문에 연료전지 시스템으로 공급되는 가스의 열관리 문제가 중요하다. 본 연구에서는 선박 배기가스의 폐열을 선박 전원용 500kW급 SOFC 시스템으로 공급되는 연료, 가스 및 물을 가열하는 열원으로 활용한 경우에 연료전지 애노드 및 캐소드로 공급되는 가스의 온도특성에 관하여 검토하였다. 본 연구에서 제안한 연료전지 시스템에서는 선박의 배기가스를 활용하지 않고 연료전지에서 배출되는 배기가스만으로 연료전지 시스템으로 공급되는 가스의 가열원으로 활용한 경우의 애노드 및 캐소드로 공급되는 가스의 온도가 963K로 가장 높음을 알 수 있었다. 또한 엔진의 출력(배기가스의 유량)은 연료전지 스택으로 공급되는 가스의 온도에 큰 영향을 미치지 않음을 알 수 있었다.

고온열을 이용한 고온수증기전기분해장치(HTSE)에 의한 수소생산 특성에 관한 전산유체해석적 연구 (A CFD Analysis Study on the Characteristics of Hydrogen Production by High Temperature Steam Electrolysis(HTSE) Using High Temperature Heat)

  • 한원희;최정식;윤석훈;윤두호;최재혁
    • 해양환경안전학회지
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    • 제17권4호
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    • pp.419-427
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    • 2011
  • 고온수증기전기분해(HTSE) 장치의 수소생산 및 열 화학적 특성을 파악하고자 COMSOL $^Multiphysics^{(R)}$를 사용해 2차원 정상상태 수치해석을 실시하였다. 계산을 위한 주요 파라메터로는 작동전압, ASR(Area-specific Resistance) 및 유입가스의 온도와 압력 등이다. 해석결과 1.2454 V에서 Thermal-neutral Voltage가 나타나고, 작동 전압이 증가함에 따라 Cell의 내부 온도가 단조 증가하는 것이 아니라 Thermal-neutral Voltage를 기준으로 낮은 전압에서는 Cell의 온도가 감소하고, 높은 전압에서는 Cell의 온도가 증가하였다. 또한, ASR 값이 증가함에 따라 Cell 내부의 온도는 하강하고, 수소생산율도 낮아지는 경향을 보였다.