• Korean Membrane Journal
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• v.9 no.1
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• pp.43-51
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• 2007

This paper describes the preparation and characterization of two kinds of fluorinated polybenzimidazole (PBI)s which can be potentially used for phosphoric acid-doped, high-temperature polymer electrolyte membrane fuel cells. Two kinds of perfluorocyclobutane (PFCB)-containing monomers were prepared via following synthetic steps; after fluoroalkylation of methyl 3-(hydroxy) benzoate and methyl 4-(hydroxy) benzoate with 1,2-dibromotetrafluoroethane and subsequent Zn-mediated dehalogenation, these compounds were cyclodimerized at $200^{\circ}C$ affording the ester-terminated monomers containing PFCB ether groups. The synthesized intermediates and monomers were characterized using FT-IR, $^1H-NMR,\;^{19}F-NMR$, and mass spectroscopy. The fluorinated PBIs were then successfully prepared through the solution polycondensation of the monomers and 3,3'-diaminobenzidine in polyphosphoric acid. Compared with traditional PBI, the glass transition temperatures of the fluorinated PBIs were obtained at $262^{\circ}C\;and\;269^{\circ}C$ which are lower than that of PBI and their initial degradation temperatures were still high over $400^{\circ}C$ under nitrogen. The fluorinated PBIs showed higher d-spacing values and improved solubility in several organic solvents as well as phosphoric acid, which confirmed they could be good candidates for the high temperature fuel cell membranes.

• Journal of the Mineralogical Society of Korea
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• v.26 no.1
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• pp.35-44
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• 2013

Synthetic carbon-coated olivine-like structured lithium iron phosphate ($Li^+Fe^{2+}(PO_4)^{3-}/C$) powder composites were compressed up to 35.0 GPa in the symmetrical diamond anvil cell at room temperature. Bulk modulus of $LiFePO_4/C$ was determined to be $130.1{\pm}10.3$ GPa. New peak appears at the d-spacing of 3.386 ${\AA}$ above 18 GPa, and another new one at 2.854 ${\AA}$ around 35 GPa. The crystallographic symmetry of the sample (i.e. orthorhombic) is apparently retained up to 35 GPa as no clear evidence for the phase transition into spinel structure has been observed. The pressure-induced volume change in the M1 site ($Li^+O_6$) is more significant than those in M2($Fe^{2+}O_6$) and $PO_4$ tetrahedral sites.

• Korean Journal of Materials Research
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• v.9 no.9
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• pp.890-895
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• 1999

The recent important issue in solar cell fabrication is to adopt thin film silicon solar cells on cheap substrates. However, thin cells demand new grid design concept that all the contacts(to the emitter and base) be located on the front surface. Hence, the aim of the investigation presented in this paper was to determine the potential and the basic limitation of the design. With this concept, an interdigitated front grid structure was realized and cells were fabricated through a set of photolithography processes. Confirmed efficiencies of up to 11.5% were achieved on bonded SOI wafers with a cell thickness of 50$\mu\textrm{m}$ in the case of finger spacing more than $\mu\textrm{m}$ and a base width of 35$\mu\textrm{m}$. It was also shown from the results that the design rules for optimizing the base fraction and reducing the shadowing fraction are noted as an important technique to realize high-efficiency thin silicon solar cells.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.33 no.5
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• pp.331-338
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• 2020

In this study, the characteristic of a 3-D micro-woven material, which is one of the newly developed periodic open-cell structure, is analyzed through various computational simulations. To increase the accuracy of the numerical simulations, the distance between each directional wire is parameterized using six design variables, and its model geometry is precisely discretized using tetrahedron elements. Using the improved computational model, the material properties of the mechanical, thermal, and fluidic behavior are investigated using commercial software and compared with the previous experimental results. By changing the space between the x- and y-directional wires, a parametric test is performed to determine the tendency of the change in the material properties. In addition, the correlation between two different material properties is investigated using the Ashby chart. The result can further be used in determining the optimal pattern and wire spacing in 3-D micro-woven materials.

• Korean Chemical Engineering Research
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• v.54 no.2
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• pp.268-273
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• 2016

To improve mechanical strength of carbon foams, the carbon black (CB) added carbon foams were fabricated by impregnating different contents of carbon black (CB) and mesophase pitch using polyvinyl alcohol (PVA) solution into polyurethane foam and being followed by heat treatment. The cell wall-thicknesses of carbon foams were controlled by adding amounts of CB, and it was confirmed that the compressive strength of carbon foams was increased as increasing cell wall-thickness. The compressive strength had the highest value of $0.22{\pm}0.05MPa$ with the highest bulk density of $0.44g/cm^3$ when adding 5 wt% CB in carbon foam. However, the thermal conductivity was decreased by adding CB in carbon foam. The results indicated that the thermal conductivities of carbon foams were reduced by increased interlayer spacing ($d_{002}$) with the addition of CB in carbon foams.

• Advances in aircraft and spacecraft science
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• v.5 no.4
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• pp.411-430
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• 2018

This computational study examines the augmentation of classic 2-D Rayleigh-$B{\acute{e}}nard$ convection by the addition of periodically-spaced transverse fins. The fins are attached to the heated base of the cavity and serve to partition the cavity into 'units' with different aspect ratios. The respective impacts upon heat transfer of the fin configuration parameters - including spacing, height, thickness and thermal conductivity - are systematically examined through numerical simulations for a range of laminar Rayleigh numbers (0 < Ra < $2{\times}10^5$) and reported in terms of an average Nusselt number. The selection of the low Rayleigh number regime is linked to likely scenarios within aerospace applications (e.g. avionics cooling) where the cavity length scale and/or gravitational acceleration is small. The net heat transfer augmentation is found to result from a combination of competing fin effects, most of which are hydrodynamic in nature. Heat transfer enhancement of up to $1.2{\times}$ that for a Rayleigh-$B{\acute{e}}nard$ cavity without fins was found to occur under favorable fin configurations. Such configurations are generally characterized by short, thin fins with half-spacings somewhat less than the convection cell diameter from classic Rayleigh-$B{\acute{e}}nard$ theory. In contrast, for unfavorable configurations, it is found that the introduction of fins can result in a significant reduction in the heat transfer performance.

• ALGAE
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• v.19 no.1
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• pp.23-30
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• 2004

The purpose of this study is to assess the effects that hydraulic-gun-aerators have on cyanobactedial bloom in Sayeon Dam Reservoir in Ulsan City, Korea. A total of nine hydraulic-gun-aerators are in operation at the reservoir withe 100 m spacing between each aerator to control severe cyanobacterial bloom in the dam reservoir. The field studies were performed an total four times at two sampling stations in the reservoir from July to August in 2001. The standing crops of phytoplankton did not changed significantly by the operation. The cell concentration of the cyanobacteria at the surface layer were reduced about 10%, which is a poor result for the dispersing cyandobacteria deeper into the water. The average surface temperature during the study was reduced by 2.0$^{\circ}C$ by the hydraulic-gun-aerators. The effect of the operation on the vertical distribution of DO concentration was clear. However, the hydraulic-gun-aerators were not expected to have an effect in the lowest layer of the hypolimnion. In the study, it was proposed that installation distance between each hydraulic-gun-aerator would be proper when they are apart about 120 m based on DO depth profiles.

• Current Photovoltaic Research
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• v.4 no.3
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• pp.114-118
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• 2016

$Cu_{1.8}Zn_{1.2}(Sn_{1-x}Ge_x)S_4$ (CZTGeS) nanocrystals were mechanochemically synthesized from elemental precursor powders without using any organic solvents and any additives. The composition of CZTGeS nanocrystals were systematically varied with different Ge mole fraction (x) from 0.1 to 0.9. The XRD, Raman spectroscopy, high-resolution TEM, and diffuse reflectance studies show that the as-synthesized CZTGeS nanocrystals exhibited consistent changes in various structural and optical properties as a function of x, such as lattice parameters, wave numbers for $A_1$ Raman vibration mode, interplanar distances (d-spacing), and optical bandgap energies. The bandgap energy of the synthesized CZTGeS nanocrystals gradually increases from 1.40 to 1.61 eV with increasing x from 0.1 to 0.9, demonstrating that Ge-doping is useful means to tune the bandgap of mechanochemically synthesized nanocrystals-based kesterite thin-film solar cells. The preliminary solar cell performance is presented with an efficiency of 3.66%.

• Journal of Korea Foundry Society
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• v.22 no.4
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• pp.174-183
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• 2002

Twin-roll process is a relatively new continuous casting process which can produce high-quality strip products directly, and solidification rate can reach $10^3$ to $10^4$ K/s, leading to fine and uniform microstructures with enhanced mechanical properties. The strip casting condition for producing fine Al-Sn alloy strip was obtained experimentally, and defects appearing on the strip was examined. Crack formation and surface quality of the strip was found to depend mainly on process parameters such as melt temperature, roller gap and rolling speed. Sn structure of network type was observed in Al-20Sn and Al-40Sn alloy strips, and cell spacing of Al-40Sn alloy was smaller than that of Al-20Sn. Banding strength of the heat treated specimens increased with increasing of soaking time and temperature, and bonding strength of Al-20Sn alloy was more superior than that of Al-40Sn alloy. However wear resistance of Al-40Sn alloy contained large amount of soft Sn which possess good anti-friction characteristics was superior than that of Al-20Sn alloy.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.29 no.4
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• pp.231-236
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• 2016

A three-electrode type reflective display (electronic paper) is designed to apply an independent electric field to each three electrodes of the cell including two electric-type of particles and electrically neutral color fluid, so single color realization is possible. In particular, the movement of particles and optical properties are decided by the electric field between two electrodes on the lower substrate. So, the effect of electric field by the distance between two electrodes on the lower substrate is studied with electrode spacing with $10{\mu}m$, $15{\mu}m$, $20{\mu}m$, and $25{\mu}m$. By our experimentation, the driving voltage induces more reliable movement of charged particles and the optical properties as compared with the threshold voltage. We ascertain the single color realization and non-inverted particle separation is possible. So the more desirable optical properties are observed in case of the short electrode like $10{\mu}m$.