• Elastomers and Composites
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• 제36권1호
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• pp.52-60
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• 2001

발포체의 물성은 발포체의 밀도, 사용된 폴리머의 기계적 물성과 열린 셀(open cell) 함량, 셀 크기, 셀 크기 분포, 셀 형태, 격벽의 두께 등을 포함하는 셀 구조에 의존하며 이러한 발포체의 밀도는 사용된 폴리머의 종류와 가교제의 농도, 발포제의 농도 그리고 가공 기술 및가공 조건 같은 다양한 원료물질과 가교조건에 영향을 받는다. Ethylene vinyl acetate coplymer (EVA) 발포체는 가교 발포체로서 가교속도와 발포제의 분해속도에 의해 발포특성에 영향을 받으며 이에 따라 발포체 물성에도 영향을 미친다. 본 연구에서는 가공 온도인 $155^{\circ}C$에서의 시간에 따른 발포제의 분해 속도 차이와 이에 따른 발포특성과 발포체의 물성에 대한 영향을 평가하였다. 발포제 분해 속도가 보다 느린 경우, 발포제 분해속도가 빠른 경우와 비교하여 낮은 밀도를 보여주었으며, 우수한 충격흡수성을 나타내었고 발포체의 셀 크기는 보다 균일하였다.

• Journal of Electrochemical Science and Technology
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• 제12권1호
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• pp.67-73
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• 2021

Nickel-rich lithium nickel-cobalt-manganese oxides (NCM) are viewed as promising cathode materials for lithium-ion batteries (LIBs); however, their poor cycling performance at high temperature is a critical hurdle preventing expansion of their applications. We propose the use of a functional electrolyte additive, triphenyl phosphate (TPPa), which can form an effective cathode-electrolyte interphase (CEI) layer on the surface of Ni-rich NCM cathode material by electrochemical reactions. Linear sweep voltammetry confirms that the TPPa additive is electrochemically oxidized at around 4.83 V (vs. Li/Li+) and it participates in the formation of a CEI layer on the surface of NCM811 cathode material. During high temperature cycling, TPPa greatly improves the cycling performance of NCM811 cathode material, as a cell cycled with TPPa-containing electrolyte exhibits a retention (133.7 mA h g-1) of 63.5%, while a cell cycled with standard electrolyte shows poor cycling retention (51.3%, 108.3 mA h g-1). Further systematic analyses on recovered NCM811 cathodes demonstrate the effectiveness of the TPPa-based CEI layer in the cell, as electrolyte decomposition is suppressed in the cell cycled with TPPa-containing electrolyte. This confirms that TPPa is effective at increasing the surface stability of NCM811 cathode material because the TPPa-initiated POx-based CEI layer prevents electrolyte decomposition in the cell even at high temperatures.

• 대한기계학회논문집A
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• 제37권10호
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• pp.1305-1313
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• 2013

본 논문에서는 경계표현 모델에 특징형상기반 단순화를 적용하는 방법을 제안한다. 특징형상기반 단순화를 위해, 경계표현 모델로부터 볼륨분해 트리가 생성된다. 볼륨분해 트리는 가산적 볼륨, 감산적 볼륨 및 필렛/라운드/모따기 볼륨들의 정규화된 불리언 연산으로 표현되며, 필렛/라운드/모따기 분해, 랩어라운드 분해, 볼륨분할 분해 및 셀 기반 분해로 구성된 단계적 볼륨분해를 이용해 생성된다. 볼륨분해 트리는 중위연산 형태로 변환되고, 볼륨들의 순서를 변경하여 CAD 모델을 단순화시킨다. 제안한 방법의 검증을 위해, 프로토타입 시스템을 구현했고, 테스트 케이스에 대한 CAD 모델 단순화 실험을 수행하였다. 실험을 통해 제안한 방법이 경계표현 기반 CAD 모델의 단순화에 유용함을 확인하였다.

• Journal of Electrochemical Science and Technology
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• 제13권1호
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• pp.63-70
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• 2022

Compared with hydrogen, ammonia has the advantages of high gravimetric hydrogen densities (17.8 wt.%), ease of storage and transportation as a chemical hydrogen storage medium, while its application in small-scale on-site hydrogen production scenarios is limited by the need for complex separation equipment during high purity hydrogen production. Therefore, the study of PEMFC, which can directly utilize ammonia decomposition gas, can greatly expand the application of fuel cells. In this paper, the output characteristics, fuel efficiency and the variation trend of hydrogen concentration and local current density in the anode channel of fuel cell with the output voltage of PEMFC fueled by ammonia decomposition gas were studied by experiment and simulation. The results indicate that the maximum output power of the hybrid fuel decreases by 9.6% compared with that of the pure hydrogen fuel at the same inlet hydrogen equivalent. When the molar concentration of hydrogen in the anode channel is less than 0.12, the output characteristics of PEMFC will be seriously affected. Employing ammonia decomposition gas as fuel, the efficiency corresponding to the maximum output power of PEMFC is approximately 47%, which is 10% lower than the maximum efficiency of pure hydrogen.

• Nuclear Engineering and Technology
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• 제54권12호
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• pp.4441-4448
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• 2022

The electrochemical oxidation process has been widely studied in the field of wastewater treatment for the decomposition of organic materials through oxidation using ·OH generated on the anode. Pt anode electrodes with high durability and long-term operability have a low oxygen evolution potential, making them unsuitable for electrochemical oxidation processes. Therefore, to apply Pt electrodes that are suitable for long-term operation and large-scale processes, it is necessary to develop a new method for improving the decomposition rate of organic materials. This study introduces a method to improve the decomposition rate of organic materials when using a Pt anode electrode in the electrochemical oxidation process for the treatment of organic decontamination liquid waste. Electrochemical decomposition tests were performed using sodium dodecylbenzenesulfonate (SDBS) as a representative organic material and a Pt mesh as the anode electrode. Y₂O₃ particles were introduced into the electrolytic cell to improve the decomposition rate. The decomposition rate significantly improved from 21% to 99%, and the current efficiency also improved. These results can be applied to the electrochemical oxidation process without additional system modification to enhance the decomposition rate and current efficiency.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1998년도 하계학술대회 논문집 G
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• pp.2315-2317
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• 1998

There has been extensive efforts about robot path planning. Some major approaches are the roadmap approach, potential field approach and the cell decomposition approach. However, most of the path planning methods proposed so far based on above approaches consider the terrains filled with binary obstacles, i.e., if there exists an obstacle, robot simply cannot pass the location. In this paper, A mobile robot path planning method based on the cell decomposition technique for mobile robot that takes account of the terrain with varing degrees of travers-ability is discussed.

• 전자공학회논문지B
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• 제33B권9호
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• pp.37-48
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• 1996

In this paper, for the single s-a-E fault detected in a triangular cellular permutation network (TCPN), we propose a method which can tolerate a fault by reconfiguring the netowrk and analyze the possibilities of the reconfiguration. The network is set up through iterative decomposition of a permutation into the right or left coset. For the s-a-E fault of a cell which is to be transpositioned for an increasing order mapping, we cna reconfigure it merely by switching te decomposition scheme from right coset to left coset or vice versa. Also for a decreasing order mapping, we make a detour around the faulty cell. Reconfiguring with the redundant connectivity of a TCPN, we could realize form 17% to 90% of the permutation for the number of inputs from 4 to 40. REconfiguration of the network by exchanging the first input with the last input and the first output with the last output resulted in more than 99% realization of the permutation. Also with the exchange of all inputs and outputs with neighboring cells, we could have 100% realization of the permutation.

• 한국수소및신에너지학회논문집
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• 제24권5호
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• pp.413-420
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• 2013

Effect of inherent volatile matters in fuels on electrochemical reactions of anode was investigated for a single direct carbon fuel cell (DCFC). Raw coals used as power source in the DCFC release light gases into the atmosphere under the operating temperature of DCFC ($700^{\circ}C$) by thermal decomposition and only char remained. These exhausted gases change the gas composition around anode and affect the electrochemical oxidation reaction of system. To investigate the effect of produced gases, comparative study was conducted between Indonesian sub-bituminous coal and its char obtained through thermal treatment, carbonizing. Maximum power density of raw coal ($52mW/cm^2$) was appeared higher than that of char ($37mW/cm^2$) because the gases produced from the raw coal during thermal decomposition gave additional positive results to electrochemical reaction of the system. The produced gases from coals were analyzed using TGA and FT-IR. The influence of volatile matters on anodic electrolyteelectrode interface was observed by the equivalent circuit induced from fitting of impedance spectroscopy data.

• 한국인터넷방송통신학회논문지
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• 제24권3호
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• pp.15-20
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• 2024

무인 항공기의 경로 계획은 고정 및 동적 장애물을 포함하는 복합 환경에서 장애물 충돌을 회피하는 것이 중요하다. RRT나 A^*와 같은 경로 계획 알고리즘은 고정된 장애물 회피를 효과적으로 수행하지만, 고차원 환경일수록 계산 복잡도가 증가하는 한계점을 가진다. 강화학습 기반 알고리즘은 복합적인 환경 반영이 가능하지만, 기존 경로 계획 알고리즘과 같이 고차원 환경일수록 훈련 복잡도가 증가하여 수렴성을 기대하기 힘들다. 본 논문은 셀 분해 알고리즘을 활용한 강화학습 모델을 제안한다. 제안한 모델은 학습 환경을 세부적으로 분해하여 환경의 복잡도를 감소시킨다. 또한, 에이전트의 유효한 행동을 설정하여 장애물 회피 성능을 개선한다. 이를 통해 강화학습의 탐험 문제를 해결하고, 학습의 수렴성을 높인다. 시뮬레이션 결과는 제안된 모델이 일반적인 환경의 강화학습 모델과 비교하여 학습 속도를 개선하고 효율적인 경로를 계획할 수 있음을 보여준다.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2006년도 하계학술대회 논문집 Vol.7
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• pp.28-29
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• 2006

When photovoltaic module is used for a long time, its performance decreases due to several reasons. In this paper, we focus on the possibilities mainly contributing to the degraded efficiency of the polycrystalline silicon photovoltaic modules. The analysis is based on the modules that have been used for 15 years. These are two main reasons that cause the efficiency degradation, the corrosion and thermal decomposition. The former phenomenon of electrode is mainly due to the moisture from damaged back sheet in some module. However the other reason of the degraded efficiency comes from the thermal decomposition, which can not be observed from the outside but only by experiment. In this study, the comparison between the efficiency of normal modules and degradation modules is presented. Module having degraded cell was seen to cause increase of series resistance by about 80%, in comparison to normal samples efficiency which reduce by about 20%. This study shows that the effects of series resistances on module performance are critical. These effects must be understood and taken into consideration when analyzing performance degradation.