• Title/Summary/Keyword: CathodeThermal

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Electrical Properties of $LI_2O-V_2O5-TeO_2$ Glasses for Solid State Electrolyte (전해절용 $Li_2O-V_2O_5-TeO_2$ 계 글라스 세라믹스의 전기적 특성)

  • Lee, Chang-Hee;Park, Jae-Hyeon;Son, Myung-Mo;Lee, Hun-Soo;Gu, Hal-Bon;Park, Hee-Chan
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.11a
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    • pp.304-304
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    • 2006
  • Ternary tellurite glassy systems ($Li_2O-V_2O_5-TeO_2$) have been synthesised using Vanadium oxide as a network former and Lithium oxide as network modifier. The addition of a metal oxide makes them electric or mixed electric-ionic conductors, which are of potential interest as cathode materials for solid-state batteries. This glass-ceramics crystallized from the $Li_2O-V_2O_5-TeO_2$ system are particularly interesting, because they exhibit high conductivity (up to $5.63{\times}10^{-5}$ S/cm) at room temperature the glass samples were prepared by quenching the melt on the copper plate and the glass-ceramics were heat-treated at crystallizing temperature determined from differential thermal analysis (DTA). The electric DC conductivity result have been analyzed in terms of a small polaron-hopping model.

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A Study on the Low-energy Large-aperture Electron Beam Generator (저에너지 대면적 전자빔 발생장치 개발에 관한 연구)

  • Jo, Ju-Hyeon;Choe, Yeong-Uk;Lee, Hong-Sik;Im, Geun-Hui;U, Seong-Hun;Lee, Gwang-Sik
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.48 no.12
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    • pp.785-790
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    • 1999
  • This research has been carried out to develop a low-energy large-aperture pulsed electron beam generator (LELA), 200keV 1A, for industrial applications. One of the most important feature of this electron beam generator is large electron beam cross section of $190cm^2$. Low energy electron beam generators have been used for water cleaning, flue gas cleaning, and pasteurization, etc. In these applications the cross sectionof the e-beam is related to reaction efficiency. Another important feature of this LELA EB generator is easy maintenance because of its simple structure and relatively low vacuum operation compared to the conventional EB generators. The conventional EB generators need to be scanned because the small cross section thermal electron emitters are used in the conventional EB generators which have small EB cross section. In this research, we use the secondary electrons generated by ion bombardment on the HV cathode surface as a electron source. Therefore we can make any shape of EB cross section without scanning.

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Microstructures and Optical Properties of Composite Crystals in the System (Bi2O3)0.85.(Nb2O5)0.15-6Bi2O3.SiO2 ((Bi2O3)0.85.(Nb2O5)0.15-6Bi2O3.SiO2계 복합다결정체의 미세구조와 광학적 특성)

  • 김호건
    • Journal of the Korean Ceramic Society
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    • v.26 no.1
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    • pp.139-145
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    • 1989
  • An eutectic melt in the system(Bi2O3)0.85·(Nb2O5)0.15-6Bi2O3·SiO2 was unidirectionally solidfield at a rate of 0.5mm/h under a thermal gradient of 100℃/cm. Double crucibles and seed crystal plate were used in order to botain the composite crystals which had uniform microstructure throughout the ingot. The obtained composite crystals showed uniform microstructure, in which needle-like δ-(Bi2O3)0.85·(Nb2O5)0.15 crystals were arrayed in parallel in a matrix of γ-6Bi2O3·SiO2 single crystal. It was found that the <110> direction of δ-(Bi2O3)0.85·(Nb2O5)0.15 crystal was essentially parallel to the <111> direction of γ-6Bi2O3·SiO2 crystal in the composite crystals. A transverse thin plate of the composite crystals showed a high resolution optical transmission like an optical fiber array, and sharp chatoyancy was observed in the cabochon shaped composite crystals. Then, this may be useful for applications such as screen of a cathode ray tube or artificial cat's eye gem stones.

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Analysis on the heat-resisting method of the electrolytic metal reduction reactor in the test facility for the spent fuel waste (사용후핵연료 시험시설에서 전기 금속 전환반응기의 내열 방안 분석)

  • 김영환;윤지섭;정재후;홍동희;박기용;진재현
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2003.06a
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    • pp.776-779
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    • 2003
  • To reduce the storage space of spent fuel used at the atomic power plants in the over the world, the uranium elements contained in the spent fuel is being extracted and effectively stored. For this, the spent fuel are oxidized and deoxidized. In this study, it is produced the heat-resisting methods about the spent fuel management technology research and test facility for the spent fuel waste for spent fuel minimized. The first considered processes in the facility are the electrolytic metal reduction reactor process. Since the electrolytic metal reduction reactor is operated at the high temperature range, we have to consider the heat-resisting methods for the devices. For the heat-resisting methods, we have searched and analyzed technical reference for the heat-resisting methods. We have calculated thermal stress and strain of each devices by the commercial analysis software, ANSYS. D.S. It is experimented for inspecting confidence rate of analysis results. By using the results, we have analyzed the problems of parts and determined the heat-resisting material, commercial parts, and the size of parts and O-ring. Based on these results, it is produced the heat-resisting methods of magnesia filter, cathode, and reactor for the electrolytic metal reduction reactor.

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Study on the Optimization of Superhydrophobic Coating for the Durability of Gas Diffusion Layer in Alkaline Fuel Cells (알카라인 연료전지 가스확산층 내구성 향상을 위한 초발수 코팅 최적화 연구)

  • Kim, Soong Yeon;Seo, Minhye;Uhm, Sunghyun
    • Applied Chemistry for Engineering
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    • v.28 no.6
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    • pp.691-695
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    • 2017
  • Optimization study was carried out to improve the durability of the gas diffusion layer (GDL) in alkaline fuel cell cathode by the use of highly stable PDMS superhydrophobic coating. Two different commercial GDLs were selected as substrates. Coating temperature and viscosity of PDMS were controlled for the stability of structure in microporous layer of GDL as well as uniform coating according to thermal characteristics of GDL. Regardless of PDMS viscosity, highly stable superhydrophobicities were obtained with both GDLs at $200^{\circ}C$. After the accelerated test, however, 28BC GDL coated with 1000 CS PDMS showed the best durability with the lowest loss of superhydrophobicity.

Synthesis of LiCoO2 Powders using Recycled Cobalt Precursors from Waste WC-Co Hard Metal (폐 WC-Co계 초경합금에서 추출된 코발트 재생 원료를 이용한 LiCoO2 입자 합성 연구)

  • Yang, Hee-Seung;Pee, Jae-Hwan;Kim, Yoo-Jin
    • Journal of Powder Materials
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    • v.18 no.3
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    • pp.277-282
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    • 2011
  • [ $LiCoO_2$ ] a cathode material for lithium rechargeable batteries, was prepared using recycled $Co_3O_4$. First, the cobalt hydroxide powders were separated from waste WC-Co hard metal with acid-base chemical treatment, and then the impurities were eliminated by centrifuge method. Subsequently, $Co_3O_4$ powders were prepared by thermal treatment of resulting $Co(OH)_2$. By adding a certain amount of $Li_2CO_3$ and $LiOH{\cdot}H_2O$, the $LiCoO_2$ was obtained by sintering for 10 h in air at $800^{\circ}C$. The synthesized $LiCoO_2$ particles were characterized by X-ray diffraction (XRD) and Scanning Electron Microscope (SEM) analysis.

Ion Beam Assisted Deposition System의 제작 및 자동화

  • 손영호
    • Proceedings of the Korean Vacuum Society Conference
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    • 1998.02a
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    • pp.27-27
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    • 1998
  • 진공기술의 응용과 진공환경의 이용은 더 이상 논하지 않더라도 산업 전반에 그 충요성이 점점 더 커가고 있다. 이러한 여건에도 불구하고 진공율 이용하는 system 개밟의 국산화는 수 입하는 system으$\mid$ 수에 비하여 절대적으로 부족하며, 또한 개발하는 system의 자동화는 거의 이 루어지지 않고 있으며, 자동화된 진공판련 system은 거의 대부분 수입에 의흔하고 있다. 실험 실 규모에서부터 System올 하나하나 개밭하고, 이톨 자동화하는 노력과 일이 진행됨다면 산업 응용에 있어서도 자연스럽게 자동화된 system으$\mid$ 개발이 이루어 질 것이다 .. system 자동화는 상 품수명의 단축과 이에 따른 다품종 소량을 요구하는 시장수요에 대응하고, 인력절감과 고풀짙 화로 생산성 향상의 요구에 대응하기 위하여 필요하다. 본 연 구에 서 는 e-beam evaporator로 evaporation하면 서 ion beam으로 assist하여 thin film율 제 작하는 IBAD vacuum system율 싫 계 및 제 작하고[1,2], PLC[3,떼톨 이 용하여 system 자동화톨 하였다 .. thin film 제작 process는 먼저 기본 진공상태로 만뚫고 난 뒤, e-beam evaporator로 e evaporation하면서 ion beam source로 assist하여 substrate 011 thin film율 제조한다 226;. thin film올 제 조하면서 thickness monitor로 sample의 thickness rate톨 control 하고, sample의 균얼성과 밀착 성을 고려하여 substrate톨 rotation 및 heating 할 수 있도록 싫계, 제작하였다. 양질의 박막올 제조하기 위해서 진공환경이 좋은 상태로 제공되어야 한다. 이톨 위하여 oil free operation 0 I 가 능한 dry pump와 turbo molecular pump로 고진공 배기 하였다. 진공도의 흑점은 thermal effect 툴 고려하여 cold cathode ion gauge률 사용하였고, intro chamber와 main chamber 사이에는 g gate valve톨 설치하여 벌도로 운용되도록 하였다. 이러한 process를 박막의 두께, 진공도, 시 간, 온도, 공정 동의 조건올 기훈으로 자동화한 것이다. 또한 정전과 단수에 대한 interlock 기능 도 고려하였다.하였다.

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High Frequency and High Luminance AC-PDP Sustaining Driver

  • Choi Seong-Wook;Han Sang-Kyoo;Moon Gun-Woo
    • Journal of Power Electronics
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    • v.6 no.1
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    • pp.73-82
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    • 2006
  • Plasma display panels (PDPs) have a serious thermal problem, because the luminance efficiency of a conventional PDP is about 1.5 1m/W and it is less than $3\~5\;lm/W$ of a cathode ray tube (CRT). Thus there is a need for improving the luminance efficiency of the PDP. There are several approaches to improve the luminance efficiency of the PDP and we adopted a driving PDP at high frequency range from 400kHz up to over 700kHz. Since a PDP is regarded as an equivalent inherent capacitance, many types of sustaining drivers have been proposed and widely used to recover the energy stored in the PDP. However, these circuits have some drawbacks for driving PDPs at high frequency ranges. In this paper, we investigate the effect of the parasitic components on the PDP itself and on the driver when the reactive energy of the panel is recovered. Various drivers are classified and evaluated based on their suitability for high frequency drivers. Finally, a current-fed driver with a DC input voltage bias is proposed. This driver overcomes the effect of parasitic components in the panel and driver. It fully achieves a ZVS of all full-bridge switches and reduces the transition time of the panel polarity. It is tested to validate the high frequency sustaining driver and the experimental results are presented.

A Study on High Frequency Sustaining Driver for Improving Luminance Efficiency of AC-PDP (AC-PDP의 광효율 향상을 위한 고주파 구동회로에 관한 연구)

  • Choi, Seong-Wook;Han, Sang-Kyoo;Moon, Gun-Woo
    • Proceedings of the KIPE Conference
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    • 2005.07a
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    • pp.380-384
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    • 2005
  • Plasma display panel (PDP) has a serious thermal problem, because the luminance efficiency of the conventional PDP is about 1.5 lm/W and it is less than $3{\sim}5$ lm/W of cathode ray tube (CRT). Thus there is a need for improving the luminance efficiency of the PDP There are several approaches to improve the luminance efficiency of the PDP and we adopt the driving PDP at high frequency range from 400 kHz up to over 700 kHz. Since a PDP is regarded as an equivalent inherent capacitance, many types of sustaining drivers have been proposed and widely used to recover the energy stored in the PDP. However, these circuits have some drawbacks for driving PDP at high frequency range. In this paper, we investigate the effect of the parasitic components of PDP itself and driver when the reactive energy of panel is recovered. Various drivers are classified and evaluated whether it is suitable for high frequency driver, and finally current-fed type with do input voltage biased is proposed. This driver overcomes the effect of parasitic component in panel and driver and fully achieves ZVS of all full-bridge switches and reduces the transition time of the panel polarity.

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Modeling for the Performance Analysis of a Tubular SOFC/MGT Hybrid Power System (원통형 고체산화물 연료전지와 마이크로 가스터빈 하이브리드 시스템의 성능해석을 위한 모델링)

  • Song, T.W.;Sohn, J.L.;Kim, J.H.;Kim, T.S.;Ro, S.T.;Suzuki, K.
    • Proceedings of the KSME Conference
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    • 2004.04a
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    • pp.2070-2075
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    • 2004
  • Performance of a solid oxide fuel cell (SOFC) can be enhanced by converting thermal energy of its high temperature exhaust gas to mechanical power using a micro gas turbine (MGT). A MGT plays also an important role to pressurize and warm up inlet gas streams of the SOFC. In this study, the influence of performance characteristics of the tubular SOFC on the hybrid power system is discussed. For this purpose, detailed heat and mass transfer with reforming and electrochemical reactions in the SOFC are mathematically modeled, and their results are reflected to the performance analysis. The analysis target is 220kWe SOFC/MGT hybrid system based on the tubular SOFC developed by Siemens-Westinghouse. Special attention is paid to the ohmic losses in the tubular SOFC counting not only current flow in radial direction, but also current flow in circumferential direction through the anode and cathode.

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