• 한국연소학회:학술대회논문집
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• 2003.05a
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• pp.153-158
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• 2003

Catalytic Combustion used to be applied to specific conditions because of the characteristics different from flame combustion. However, many researches are focused on widening the applicant range of catalytic combustion with the competences of catalytic combustion. The development of many catalytic combustion appliances is one of the trials to overcome the restrictions of reaction and maximize the merits. In this research, past developments of appliances are depicted and new conceptual system will be introduced - sequential system. Sequential catalytic combustion system is composed of units - existing catalytic heat exchangers. This system is performed with parallel in composition and serially in operation. First, the burden of the preheating can be dramatically reduced. Second, stable operation control is expected. Lastly, Capacity expansion is flexible.

• 한국연소학회:학술대회논문집
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• 2002.11a
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• pp.65-69
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• 2002

Catalytic combustion known as one of the traditional oxidation methods of VOC gas is restricted to its applicable fields because of its reaction characteristics. But recently innovative improvement of catalytic endurance makes its applicable range broader from MEMs to industrial power generation. Therefore, control technologies based on the catalytic combustion characteristics are researched and developed dynamically. Especially, the stable control of catalytic combustion is an essential factor in a view of maximizing its efficiency. In this research, the fuel equivalence ratio and the preheating temperature of mixture gas is controlled by catalytic combustion system enhanced in heat transfer with high temperature heat exchanger. As a result, the combustion characteristics of system was investigated, and both passive and active control type were compared and analyzed.

• 한국연소학회:학술대회논문집
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• 2002.06a
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• pp.79-84
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• 2002

The catalytic heat exchanger was designed which employs the regenerative preheating system of combustion air. The characteristics of the catalytic heat exchanger have been experimentally studied at the various operating parameters. The results showed that the mixture velocity did not affect significantly the performance of catalytic combustor whereas the preheating temperature of combustion air affected significantly the conversion rate. The complete conversion was achieved in the catalyzed honeycomb at a preheating temperature of $370-390^{\circ}C$, a mixture velocity of 0.53 $^{\sim}$ 0.75 m/s and an equivalence ratio of 0.19 $^{\sim}$ 0.27. The heat exchange efficiency of the catalytic heat exchanger appeared to be about 75 % when the air of room temperature was used as a working fluid. The results showed that both the heat balance of the system and the mixture conditions determine its stable catalytic combustion.

• Proceedings of the KSME Conference
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• 2008.11b
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• pp.3049-3052
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• 2008

MCFC(molten carbonate fuel cell) power generation system is prime candidate for the utilization of fossil based fuels to generate ultra clean power with a high efficiency. In the MCFC power plant system, a combustor performs a role to supply high temperature mixture gases for cathode and heat for reformer by using the stack off-gas of the anode which includes a high concentration of $H_2O$ and $CO_2$. Since a combustor needs to be operated in a very lean condition and to avoid excessive local heating, catalytic combustor is usually used. The catalytic combustion is accomplished by the catalytic chemical reaction between fuel and oxidizer at catalyst surface, different from conventional combustion. In this study, a mathematical model for the prediction of internal flow and catalytic combustion characteristics in the catalytic combustor adopted in the MCFC power plant system is suggested by using the numerical methods. The numerical simulation models are then implemented into the commercial CFD code. After verifying result by comparing with the experimental data and calibrated kinetic parameters of catalytic combustion reaction, a numerical simulation is performed to investigate the variation of flow and combustion characteristics by changing such various parameters as inlet configuration and inlet temperature. The result show that the catalytic combustion can be effectively improved for most of the case by using the perforated plate and subsequent stable catalytic combustion is expected.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 2002.11a
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• pp.133-140
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• 2002

Catalytic combustion known as one of the traditional oxidation methods of VOC gas is restricted to its applicable fields because of its reaction characteristics. But recently innovative improvement of catalytic endurance makes its applicable range broader from MEMs to industrial power generation. Therefore, control technologies based on the catalytic combustion characteristics are researched and developed dynamically. Especially, the stable control of catalytic combustion is an essential factor in a view of maximizing its efficiency. In this research, the fuel equivalence ratio and the preheating temperature of mixture gas is controlled by catalytic combustion system enhanced in heat transfer with high temperature heat exchanger. As a result the combustion characteristics of system was investigated, and both passive and active control type were compared and analyzed.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 2004.05a
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• pp.197-200
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• 2004

Compared to conventional flame combustion, catalytic combustion had the advantage of oxidation of V.O.C. gas which was high voluminous, low caloric mixture flow. However, the temperature of mixture gas should be over the one of catalytic reaction start and the control of reaction on the catalytic surface tends to be vulnerable. To overcome these obstacles, composition of both catalytic combustor and heat exchanger was devised and named the sequential catalytic combustion system. In this system, only trigger unit needed preheating process for transient starting time. Once trigger unit was ignited, the next unit w3s supplied heat to ignite from that and same process was performed to the last one sequentially. When it come to steady state, whole mixture gas was oxidated at each unit simultaneously and preheating for trigger unit was not needed any more. System of 100 kcalh/hr capacity was devised and operated successfully.

• Journal of the Korean Society of Combustion
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• v.10 no.1
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• pp.20-26
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• 2005

In the present study, catalytic combustion of hydrogen-air premixture in a millimeter scale monolith coated with Pt catalyst was investigated. As the combustor size decreases, the heat loss increases in proportion with the inverse of the scale of combustion chamber and combustion efficiency decreases in a conventional type of combustor. Combustion reaction assisted by catalyst can reduce the heat loss by decreasing the reaction temperature at which catalytic conversion takes place. Another advantage of catalytic combustion is that ignition is not required. Platinum was coated by incipient wetness method on a millimeter scale monolith with cell size of $1{\times}1mm$. Using this monolith as the core of the reaction chamber, temperatures were recorded at various locations along the flow direction. Burnt gas was passed to a gas chromatography system to measure the hydrogen content after the reaction. The measurements were made at various volume flow rate of the fuel-air premixture. The gas chromatography results showed the reaction was complete at all the test conditions and the reacting species penetrated the laminar boundary layer at the honeycomb and made contact with the catalyst coated surface. At all the measuring locations, the record showed monotonous increase of temperature during the measurement duration. And the temperature profile showed that the peak temperature is reached at the point nearest to the gas inlet and decreasing temperature along the flow direction.

• Journal of Environmental Science International
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• v.18 no.3
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• pp.283-288
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• 2009

This is a study on the volatile organic compounds(VOCs) concentrator with zeolite adsorptive honey rotor and catalytic combustion system for abating VOCs emitted from printing industry. VOCs emitted from the printing industry is mainly caused by organic solvent of printing ink. The content of organic solvents in printing ink varies from 40% to 75% and its content in the gravure ink is higher than that in any other ink. The average concentrations of each VOCs are 139 ppm for toluene, 152.1 ppm for MEK, 256.9 ppm for methanol and 42.9 ppm for isopropyl alcohol. We used zeolite honeycomb for absorbent of VOCs concentrator and palladium for catalyst combustion system. This system abated over 96% of emitted total VOCs, 98% of toluene, 100% of MEK, 92% of methanol and, 100% of isopropyl alcohol. It is concluded that the low-leveled high-volume VOCs emitted from printing process were removed almost by concentrator with zeolite adsorptive honey rotor and catalytic combustion system.

• 한국신재생에너지학회:학술대회논문집
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• 2010.06a
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• pp.132.1-132.1
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• 2010

Anode off-gas of high temperature fuel cells such as MCFC still contain combustible components such as hydrogen, carbon monoxide and hydrocarbon. Thus, it's very important to fully burn anode off-gas and use the generated heat in order to increase system efficiency. In the present study, catalytic combustors have been applied to high temperature MCFC system so that the combustion of anode-off gas can be boosted up. Since the performance of catalytic combustor directly depends on the combustion catalyst, this study has been focused on the experimental investigation on the combustion characteristics of multiple commercial catalysts having different structures and compositions. In order to determine the design conditions of the catalytic combustor, parameters such as inlet temperature, space velocity and excess air ratio have been varied and optimized for combustor design. Results show that $H_2$ in off-gas assists $CH_4$ combustion in a way that it decreases minimum inlet temperature limit and increases maximum space velocity while keeping high fuel conversion efficiency.

• 한국연소학회:학술대회논문집
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• 2001.11a
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• pp.83-89
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• 2001

Most technologies of reduction process used in the heat treatment of existent metal products are related to metals applied to bolts and parts of automobiles, and nonmetal such as copper. Heating conditions and reduction gases produced in above processes depend on types of products to be treated thermally but heating systems employ electricity commonly and the reduction gases are separated into additional production equipment and a gas dryer and inefficiently provided into the system. Electrical heating system has the advantage of convenient temperature-control but is not economical because of disadvantages of high electricity-running cost and extra installation cost of a transformer. Accordingly, development of the system which has economical heating mode in which provision of reduction gas and heating conditions are unified is necessary for improvement of economy and efficiency in current reduction processes. This study aimed to develop a new advanced heat treatment furnace using catalytic combustion. thereby minimizing the cost during heating, supplying heat and reductive gas at the same time and controlling operating condition freely by changing electrical heating system to heating system by the gas combustion and regeneration of wasted heat.