• International Journal of Automotive Technology
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• v.6 no.5
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• pp.445-451
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• 2005

Most of the pollutants from passenger cars are emitted during the cold-transient phase of the FTP-75 test. In order to reduce the exhaust emissions during the cold-transient period, it is essential to warm up the catalyst as fast as possible after the engine starts, and the Unburned Exhaust Gas Ignition (UEGI) technology was developed through our previous studies to help close-coupled catalytic converters (CCC) reach the light-off temperature within a few seconds after cold-start. The UEGI system operates by igniting the unburned exhaust mixture by glow plugs installed upstream of the catalyst. The flame generates a high amount of heat, and if the heat is concentrated on a specific area of monolith surface, then thermal crack or failure of the monolith could occur. Therefore, it is very important to monitor the temperature distribution in the CCC during the UEGI operation, so the local temperatures in the monolith were measured using thermocouples. Experimental results showed that the temperature of CCC rises faster with the UEGI technology, and the CCC reaches the light-off temperature earlier than the baseline case. Under the conditions tested, the light-off time of the baseline case was 62 seconds, compared with 33 seconds for the UEGI case. The peak temperature is well under the thermal melting condition, and temperature distribution is not so severe as to consider thermal stress. It is noted that the UEGI technology is an effective method to warm up the catalyst with a small amount of thermal stress during the cold start period.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2009.11a
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• pp.130-133
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• 2009

The sequence of the propellant supply is very important for the reliable and safe operation of a LRE combustion test. So combustion performance tests were performed to find an optimum test sequence by changing supply time of propellants and purge gas in the moment of ignition and extinction. The liquid rocket engine consisted of a catalytic ignitor and six swirl-coaxial injectors which used hydrogen peroxide and kerosene. Conclusively, an optimum sequence was found for stable combustion in the moment of ignition and extinction.

• 한국연소학회:학술대회논문집
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• 2002.11a
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• pp.237-240
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• 2002

Micro catalytic reactors are alternative propulsion device that can be used on a nano satellite. When used with a monopropellant, $H_2O_2$, a micro catalytic reactor needs only one supply system as the monopropellant reacts spontaneously on contact with catalyst and releases heat without external ignition, while separate supply lines for fuel and oxidizer are needed for a bipropellant rocket engine. Additionally, $H_2O_2$ is in liquid phase at room temperature, eliminating the burden of storage for gaseous fuel and carburetion of liquid fuel. In order to design a micro catalytic reactor, an appropriate catalyst material must be selected. Considering the safety concern in handling the monopropellants and reaction performance of catalyst, we selected hydrogen peroxide at volume concentration of 70% and perovskite redox catalyst of lantanium cobaltate doped with strondium. Perovskite catalysts are known to have superior reactivity in reduction-oxidation chemical processes. In particular, lantanium cobaltate has better performance in chemical reactions involving oxygen atom exchange than other perovskite materials. In the present study, a process to prepare perovskite type catalyst, $La_{0.8}Sr_{0.2}CoO_3$, and measurement of its propellant decomposition performance in a test reactor are described.

• Journal of Advanced Marine Engineering and Technology
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• v.25 no.6
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• pp.1260-1271
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• 2001

The simulation program which predicts the gas behavior in a spark ignition engine has been developed and verified by the comparison with the experimental results foy the MPI engine, naturally aspirated and turbochared engines with a carburettor. First paper describes the calculations of the behavior of gas in the intake and exhaust system. The generalized method of characteristics including friction, heat transfer, area change and entropy gradients was used to analyse the pipe flow The constant-Pressure model was applied for the analysis of the flow through engine valved, and the constant-pressure perfect-mixing model was applied for the flow at manifold junction. The concept of the sudden area change was used for the muffler and catalytic convertor. Fer the plenum chamber in an MPI engine, constant-pressure model and constant-volume model were both examined. Through the comparison of predicted results with experiments, the simulation program was verified by showing good prediction of the behavior of IC engine qualitatively and quantitatively under wide range of operating conditions.

• Korean Journal of Materials Research
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• v.17 no.7
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• pp.382-385
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• 2007

[ $LaFeO_3$ ] powders were prepared as the oxidation catalyst materials to reduce the emission of particulate matters from diesel engine and their catalytic effects on the oxidation of carbon were investigated. Solution combustion method was employed for the powder synthesis, which uses highly exothermic and selfsustaining reactions. In this study $LaFeO_3$ powders were synthesized at $400^{\circ}C$ as varying the ratio ($\Phi$) of fuel (citric acid) and oxidizer (metal nitrate), and their phase and carbon ignition property were examined. As $\Phi$ decreases, the crystallinity of synthesized $LaFeO_3$ powders enhanced. By calcining at $700^{\circ}C$, all the powders synthesized at various $\Phi$ fully crystallized. The calcined $LaFeO_3$ powders showed carbon ignition temperature as low as $501{\sim}530^{\circ}C$, which implied the decrease of the ignition temperature by $120{\sim}150^{\circ}C$.

• Transactions of the Korean Society of Automotive Engineers
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• v.9 no.2
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• pp.67-74
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• 2001

A synchronized secondaty air injection method has been developed to hydrocarbon emission by injecting secondary air intermittently into exhaust port. The method has been tested in a single cylinder spark-ignition engine operating at cold-steady / cold-start conditions. Effects of air injection timing, intake pressure and engine air-fuel ratio have been investigated at cold-steady condition. Also, hydrocarbon emission and exhaust gas temperature with catalytic conberter are compared with a continuous SAI method and base condition at cold-start condition. Resules show that hydrocarbon reduction rate and exhaust gas temperature are sensitive to the timing of synchronized SAI. At cold-steady condition, HC emission is minimum at engine air-fuel ratio of 10. At cold-start condition, the accumulated hydrocarbon emission during the first 120 s decreases about 56% and 22% with the synchronized and continuous SAI, respectively, compared to that of base condition.

• Journal of the Korean Ceramic Society
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• v.52 no.5
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• pp.350-355
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• 2015

To develop ceramic composite anodes of solid oxide fuel cells without metal catalysts, a small amount of barium carbonate was added to an $(La_{0.8}Sr_{0.2})(Cr_{0.5}Mn_{0.5})O_3(LSCM)$ - YSZ ceramic composite anode and its catalytic effects on the electrode performance were investigated. A barium precursor solution with citric acid was used to synthesize the barium carbonate during ignition, while a barium precursor solution without citric acid was used to create hydrated barium hydroxide. The addition of barium carbonate to the ceramic composite anode caused stable fuel cell performance at 1073 K; this performance was higher than that of a fuel cell with $CeO_2$ catalyst; however, the addition of hydrated barium hydroxide to the ceramic composite anode caused poor stability of the fuel cell performance.

• 한국신재생에너지학회:학술대회논문집
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• 2009.06a
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• pp.353-356
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• 2009

A pivotal mechanical balance of plant for 75kW class molten carbonate fuel cells comprise of a catalytic burner and an ejector which has been designed and tested in KEPRI(Korea Electric Power Research Institute). The catalytic burner, which oxidizes residual fuel in the anode tail gas, was operated at several conditions. Some problems arose due to local overheating or auto-ignition, which could limit the catalyst life. The catalytic burner was designed by considering both gas mixing and gas velocity. Test results showed that the temperature distribution is very uniform. In addition, an ejector is a fluid machinery to be utilized for mixing fluids, maintaining vacuum, and transporting them. The ejector is placed at mixing point between the anode off gas and the cathode off gas or the fresh air Several ejectors were designed and tested to form a suction on the fuel tail gas and balance the differential pressures between anode and cathode over a range of operating conditions. The tests showed that the design of the nozzle and throat played an important role in balancing the anode tail and cathode inlet gas pressures. The 75kW MCFC system built in our ejector and catalytic burner was successfully operated from Novembe, 2008 to April, 2009. It recorded the voltage of 104V at the current of 754A and reached the maximum generating power of 78.5kW DC. The results for both stand-alone and integration into another balance of plant are discussed.

• Proceedings of the KSME Conference
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• 2000.11b
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• pp.150-155
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• 2000

Exhaust emissions from vehicles are the main source of air pollution. Many researchers are trying to find the way of reducing vehicle emissions, especially in the cold transient period of the FTP-75 test. In this study, UEGI (Unburned Exhaust Gas Ignition) technology, warming up the close-coupled catalytic converter (CCC) by igniting the unburned exhaust mixture using two glow plugs installed in the upstream of the catalyst, was developed. It was applied to an exhaust system with a hydrocarbon adsorber to ensure an effective reduction of HC emission during the cold start period. Results showed that the CCC reaches the light-off temperature (LOT) in a shorter time compared with the baseline exhaust system, and HC and CO emissions are reduced significantly during the cold start.

• Transactions of the Korean Society of Automotive Engineers
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• v.15 no.3
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• pp.10-17
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• 2007

Design of experiments (DOE) technique has been used to design an exhaust heat exchanger to reduce the exhaust gas temperature under high load conditions in a spark-ignition engine. The DOE evaluates the influence and the interaction of a selected eight design parameters of the heat exchanger affecting the cooling performance of the exhaust gas through a limited number of experiments. The heat exchanger was installed between the exhaust manifold and the inlet of the close-coupled catalytic converter (CCC) to reduce thermal aging. To maximize the heat transfer between exhaust gas and coolant, fins were implemented at the inner surface of the heat exchanger. The design parameters consist of the fin geometry (length, thickness, arrangement, and number of fin), coolant direction, heat exchanger wall thickness, and the length of the heat exchanger. The acceptable range of each design parameter is discussed by analyzing the DOE results.