• Title/Summary/Keyword: Castor

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Single and mixed chelants-assisted phytoextraction of heavy metals in municipal waste dump soil by castor

  • Wuana, Raymond A.;Eneji, Ishaq S.;Naku, Julius U.
    • Advances in environmental research
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    • v.5 no.1
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    • pp.19-35
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    • 2016
  • The phytoextraction of some toxic heavy metals from municipal waste dump soil by castor plant (Ricinus communis) was tested under natural and single or mixed chelant-assisted scenarios in pot microcosms. A sandy loam with total metal contents (mg/kg): Cd (84.5), Cu (114.5), Ni (70.3), Pb (57.8), and Zn (117.5), was sampled from an active dumpsite in Calabar, Nigeria and used for the study. Castor (small seed variety) was grown under natural phytoextraction or single/binary chelant (citric acid, oxalic acid, and EDTA) applications (5-20 mmol/kg soil) for 63 days. Castor exhibited no visual phytotoxic symptoms with typically sigmoid growth profiles at the applied chelant doses. Growth rates, however, decelerated with increase in chelant dose. Post-harvest biomass yields were higher under chelant application than for natural phytoextraction. Both root and shoot metal concentrations (mg/kg) increased quasilinearly and significantly ($p{\leq}0.05$) with increase in chelant dose, furnishing maximum levels as: Cd (55.6 and 20.9), Cu (89.5 and 58.4), Ni (49.8 and 19.6), Pb (32.1 and 12.1), and Zn (99.5 and 46.6). Ranges of translocation factors, root and shoot bioaccumulation factors were 0.21-3.49, 0.01-0.89 and 0.01-0.51, respectively. Overall, the binary chelant treatments were less toxic for R. communis growth and enhanced metal accumulation in shoots to a greater extent than the single chelant scenarios, but more so when EDTA was present in the binary combination. This suggests that the mixed chelants could be considered as alternative treatments for enhanced phytoextraction and revegetation of degraded waste dump soils.

Cross-linkable Waterborne Polyurethane based on Castor Oil as an Efficient Binder for Silicon Anodes (실리콘 음극용 효과적인 바인더로서 가교결합이 가능한 캐스터 오일 기반의 수분산 폴리우레탄)

  • Lee, Yong Hun;Kim, Eunji;Lee, Jin Hong
    • Applied Chemistry for Engineering
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    • v.32 no.6
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    • pp.607-612
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    • 2021
  • Silicon (Si) is one of the promising active materials to replace the widely used graphite because of its low electrochemical potential and high theoretical capacity. However, Si anodes still face in problems with the huge volume expansion and continuous decomposition of the electrolyte during repeated charge and discharge processes. To address these issues, a cross-linkable waterborne polyurethane (CWPU) based on a bio-oil, castor oil, was prepared and reacted with Tris(2,3-epoxypropyl) isocyanurate (TGIC) linkers, resulting in the formation of a mechanically robust 3D network structure. Si anodes fabricated with the CWPU-TGIC exhibited stable cycling performances and excellent discharge capacities. The results revealed that the CWPU-TGIC binder efficiently accommodates the large volume change for Si anode during charge and discharge cycles. Overall, the eco-friendly binder shows great promise in improving the electrochemical performances of Si anodes.

Lipase를 이용한 피마자유의 methanolysis

  • Yang, Jung-Seok;Jeon, Gyu-Jong;Heo, Byeong-Gi;Yang, Ji-Won
    • 한국생물공학회:학술대회논문집
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    • 2001.11a
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    • pp.621-634
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    • 2001
  • The characteristics of enzymatic methanolysis of castor oil were investigated as a clean technology. Among 16 lipases tested in this study, Novozym 435 showed the highest activity in methanolysis. Solvents had different effects on the methanolysis of castor oil according to weight percent (wt%) of Novozym 435. Heptane showed best activity with 1 wt% of Novozym 435, while isopropyl ether gave the best yield of ricinoleic acid methyl ester with 0.5 wt% of that. Ricinoleic acid methyl ester was obtained in 86% of yield through the methanolysis of castor oil catalyzed by Novozym 435 (1.0 wt%) during 24hr.

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Antidiarrhoeal activity of Arque-Ajeeb, a compound formulation of Unani medicine in rats

  • Khan, M. Aleem;Khan, Naeem A.;Qasmi, Iqbal A.;Ahmad, Ghufran;Zafar, Shadab
    • Advances in Traditional Medicine
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    • v.4 no.2
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    • pp.87-90
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    • 2004
  • The efficacy of Arque-Ajeeb (AA), a compound formulation of Unani medicine was investigated for antidiarrhoeal activity against barium sulphate-induced gut motility and castor oil-induced diarrhoea in rats. The control, standard and test groups of experimental animals were administered with distilled water (p.o.), lomotil (p.o.) and AA (0.007 ml and 0.014 ml/100 g, p.o.) respectively. Barium sulphate and castor oil were administered after 15 and 60 min respectively in each group of first and second experiment. The distance traveled by barium sulphate in small intestine was measured after 15 and 30 min of barium sulphate administration and diarrhoea was observed every 30-min for six hour after castor oil administration. Oral administration of AA caused significant reduction in diarrhoea. AA may have the potential to reduce the diarrhoea in rats.

Antidiarrheal Effect of LacteolTM-Loperamide Combination on Castor oil-induced Mice Model

  • Hwang, Se-Hee;Sung, Hee-Jin;Chung, Yong-Ho;Ryu, Jei-Man;Seong, Seung-Kyoo
    • Biomolecules & Therapeutics
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    • v.10 no.4
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    • pp.236-239
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    • 2002
  • The goal of this study was to evaluate the antidiarrheal efficacy of $Lacteol^{TM}$-loperamide combination against the mouse model of secretory diarrhea. Secretory dirrhea was induced in mice by p.o. administration of castor oil (0.3 ml). Antidirrheal effects of $Lacteol^{TM}$-loperamide combination were compared with each individual component. $Lacteol^{TM}$-loperamide combination was the most potent among these agents, eliminating diarrhea in 100% of mice at a dose 1360/4 mg/kg (Lacteol/loperamide, respectively). In this study, we also measured changes of bodyweight as another indicator of the dirrhea, based on the assumption that lower bodyweight loss represented reduced fecal passage. The bodyweight loss of $Lacteol^{TM}$-loperamide combination administered group was 4 times lower than that of vehicle control. These findings indicate that $Lacteol^{TM}$-loperamide combination may be more potent than individual component in its antidiarrheal action, so we are going to challenge this combination for further study and clinical evaluation.

Comparison of Dry Matter Production in Reed canarygrass Varieties (Reed canarygrass 품종의 건물 생산성 비교)

  • 이주삼;류수훈;이경은
    • Asian Journal of Turfgrass Science
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    • v.7 no.2_3
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    • pp.121-127
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    • 1993
  • This experiment was carried out to compare the varietal differences of dry matter production in rend canarygrass. The varieties examined were Common, Venture, Castor, Palaton and Venture. Reed canarygrass was harvested three times annually, 1st cut(1O, May), 2nd cut(31, July), and 3rd cut(10, Oct.), respectively. The results were summarized as follows ; 1. Dry matter yield were not significant difference between varieties and for the interaction of variety$\times$cut. But, there was significant difference between cuts. 2. There was not significant difference in dry matter yield between the first cut and second cut. But, the dry matter yield of the third cut was poor than the other two cuts. Thus, the average dry matter yield of varieties were 806.1 kg, 730.8kg and 495.8kg /l0a in the first, second and third cut, respectively. 3. In Venture and Palaton, the percentage of dry matter distribution in spring was higher than that of other varieties. In Common, Castor and Vantage, they were not significantly different between the percentage of dry matter distribution in each cut. Above the results suggested that the first group of varieties(Venture and Palaton) were suited to meadow and last group of varieties(Common, Castor and Vantage) were suited to pasture. 4. Average total dry matter yield of varieties was 2,032kg /l0a/yr,(ranged from 1,922kg to 2,180 kg /l0a /yr.)

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Synthesis and Properties of Eco-friendly Waterborne Polyurethane according to Bio-polyol Contents (바이오폴리올 함량에 따른 친환경 수분산 폴리우레탄의 합성 및 특성)

  • Chang, Yoon Hee;Jeong, Boo-Young;Cheon, JungMi;Chun, Jae Hwan;Huh, PilHo
    • Journal of Adhesion and Interface
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    • v.23 no.2
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    • pp.33-38
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    • 2022
  • In this study, we report on the synthesis and properties of eco-friendly waterborne polyurethane (WPU) according to bio-polyol contents. It was successfully synthesized by the different polyester polyol (DT-1040) and castor oil based polyol (COP) ratios. The glass transition temperature (Tg) of the synthesized bio polyol based waterborne polyurethane was around -70 ℃ and -30 ℃, and it was confirmed that the Tg range was widened as the COP content increased. In addition, as the COP content increased, the tensile strength decreased, and optimum adhesive strength showed when DT-1040:COP ratio was 7:3.

The Effects of a Chain Extending Agent and Crosslinking Agent on the Toughness of Castor Oil based Polyurethane-Epoxy IPNs (Castor Oil형 폴리우레탄-에폭시 IPNs에서 사슬연장제와 가교제의 영향에 의한 강인성)

  • Kim, Jong-Seok;Yang, Yeong-Seok
    • Applied Chemistry for Engineering
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    • v.10 no.5
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    • pp.639-643
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    • 1999
  • Interpenetrating polymer networks(IPNs) composed of castor oil(CO) polyurethane(PU) and epoxy resin were prepared by the simultaneous polymerization technique. Two types of PU were prepared using 1,4-butanediol(BD) and BD/trimethylolpropane(TMP) as a chain extending agent and crosslinking agent. The PU/epoxy based on BD as a chain extending agent showed more shift in the damping peak than PU/epoxy based on BD/TMP as the PU content was increased. BDPU/epoxy simultaneous interpenetrating polymer networks(SINs) had a better compatibility than BD/TMP-PU/epoxy SINs. For both systems, it was postulated that unique network formation of PU/epoxy SINs as a chain extending agent and crosslinking agent had occurred to a significant extent of phase mixing. The types of chain extender in the PU were found to be an important factor in determining the phase mixing of the IPNs. When the BD/TMP-PU reaction was faster than epoxy network, the extent of phase mixing was retarded by decreasing entanglement of networks. It was found that both PU/epoxy SINs provided enhanced flexural properties and fracture toughness, fracture surfaces of BDPU/epoxy and BD/TMP-PU/epoxy SINs showed the localized shear deformation and generation of stress whitening associated with the cavitation.

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Synthesis and Characterization of Lithium Dual Complex Grease (Lithium Dual Complex 그리이스의 합성 및 특성연구)

  • 최웅수;권오관;문탁진;유영홍
    • Tribology and Lubricants
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    • v.1 no.1
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    • pp.80-87
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    • 1985
  • Lithium dual complex grease was prepared through the second continuous saponification reaction of a complex gellant system whose essential components comprised of a selected hydroxy fatty acid, lithium hydroxide monohydrate and boric acid to have a fiber structure of chemical, thermal and mechanical stability at high temperatures. An optimum amount of complex gellant was found to be 14% (NLGI #2), and an addition of castor wax of 1.5% provided an excellent performance properties, especially. The oil separation, oxidation stability, water wash-out property, shear stability, extreme pressure and wear property of thus prepared were tested by the ASTM and KS methods, and a characteristic result was obtained.