• Title/Summary/Keyword: Casting solvent

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Preparation of PZI Tapes by Solvent Washing Dry Method (용매세척건조법에 의한 PZT 테입 제조)

  • 신효순;윤석진;김현재
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.05a
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    • pp.300-303
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    • 1999
  • For the fast dry of the aqueous tape, the process which water was replaced by organic solvent was proposed. So-called, it was the solvent washing dry, Three organic solvents (methanol, ethanol, and acetone) were selected for the washing solvent. The weight loss of the washed tapes was measured to evaluate the dry rate of the tapes and dried tapes were examined the generation of the cracks with the variations of the organic solvent and the washing time. Methanol, ethanol, and acetone were all available organic solvents for this method. The tapes washed in methanol, ethanol, and acetone were dried rapidly for twenty minutes. After thirty minutes, the weight losses were not any more. The solvent of the lower surface tension can decreases the crack of dried tape. If solvent substitutes water completely, though it was fast dried, crack can be eliminated. The tape casting system was designed for the solvent washing dry and prepared. An homogeneous tape was established by continuous tape casting process.

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Controlling the pore size of macroporous membranes by adding non-solvent

  • Shin, Se-Jong;Im, Se-Jun;Park, Seung-Ryul;Lee, Seung-Yun;Min, Byoung-Ryul
    • Proceedings of the Membrane Society of Korea Conference
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    • 2003.07a
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    • pp.107-114
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    • 2003
  • This study investigated the effect of 2-methoxy ethanol (2-Me) non-solvent as additive included in casting solution. Macroporous polymer membranes were prepared by using polyethersufone (PES)/N-methyl-2-pyrrolidone (NMP)/2-Me casting solution and water coagulant. The phase separation co-process of the vapor-induced phase separation (VIPS) and liquid-induced phase separation (LIPS) were used by means of membrane preparation method. The pore size and pore size distribution were controlled with additive (non-solvent), and measured with Automated Perm Porometer. By increasing additive (non-solvent) in the casting solution, the membranes produced changed from finger structure to sponge structure. That is due to the different diffusion rates. At slow diffusion process, sponge-like structure was formed and at fast diffusion process, finger-like structure was formed. Also relative humidity, evaporation time, temperature of casting solution and coagulation bath etc. had effects on the pore size distribution and the porosity of the membrane.

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Unstable Inverted Phases of Di- and Tri-block Copolymers on Solution-Casting Films

  • Sun Dachun;Huang Lei;Liang Haojun
    • Macromolecular Research
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    • v.13 no.2
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    • pp.152-155
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    • 2005
  • A dynamic density functional theory is presented for the observation of the phase revolutions of a solution-casting film of di- and tri-block copolymers under solvent evaporation conditions. With the evaporation of the solvent, the inverted phases, the minor part of the component becomes the continuous phase at the higher solvent evaporation rate, as observed in this experiment. Further simulation revealed that these inverted phases are converted into the normal phase and the major part of the component becomes the continuous phase, implying that the inverted phases observed in this experiment are unstable.

The effect of thermodynamic stability of casting solution on the membrane inversion process morphology and permeation properties in phase inversion process

  • Kim, Jeong-Hoon;Lee, Kew-Ho
    • Proceedings of the Membrane Society of Korea Conference
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    • 1995.04a
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    • pp.26-27
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    • 1995
  • Most of synthetic polymeric membranes used in ultrafiltration, reverse osmosis and microfiltration processes are prepared by phase inversion(or phase separation) technique. In this technique, a homogeneous polymer solution is cast into thin film or hollow fiber shape and then immersed into a nonsolvent coagulant bath. The exchange of solvent and nonsolvent across the interface between casting solution and coagu!ant can make the casting solution phase-separate and form a membrane with a symmetric or asymmetric structure. Because of importance of this technique in membrane field, many investigations have been dedicated to elucidate the mechanism of membrane formation by phase inversion technique.[1-10] These investigation have suggested that the structure formation and permeation properties of phase inversion membrane depend on the variables such as the nature and content of casting solution and coagulant, temperature of casting solution and coagulant, and the diffusional exchange rate of solvent and nonsolvent etc. which can be related to the thermodynamic and kinetic properties of the casting system. The variables such as the nature and content of casting solution can also be the important factor affecting the structure formation and permeation property of the phase inversion membrane.

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Solvent Washing Dry Method for Aqueous Tape Casting

  • Yoon, Seok-Jin;Shin, Hyo-Soon;Park, Ji-Won;Kang, Chong-Yun;Kim, Tae-Song;Kim, Hyun-Jai
    • The Korean Journal of Ceramics
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    • v.7 no.2
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    • pp.55-57
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    • 2001
  • For the fast dry of the aqueous tape, the process which water was replaced by organic solvent was proposed. Socalled, it was the solvent washing dry. Three organic solvents (methanol, ethanol and acetone) were selected for the washing solvent. The weight loss of the washed tapes was measured to evaluate the dry rate of the tapes and dried tapes were examined the generation of the cracks with the variations of the organic solvent and the washing time. Methanol, ethanol and acetone were available organic solvents for this method. The tapes washed in methanol, ethanol and acetone were dried rapidly for twenty minutes. After thirty minutes, the weight losses were not found any more. The solvent of the lower surface tension can decreases the crack of dried tape. If solvent substitutes water completely, though it was fast dried, crack can be eliminated.

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Characterization of Organic Solvent Resistant Membranes

  • 전종영;김윤조;탁태문
    • Proceedings of the Membrane Society of Korea Conference
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    • 1994.10a
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    • pp.62-63
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    • 1994
  • The membrane technology is more convenient and economical way in the separation field than conventional technology such as distillation, extration, crystallization, and so on. Therefore, membrane are used as efficient tools for the separation and concentration of molecular mixture in many industrial area. Although the polymeric membrane have various advantage, they have disadvantages as well. One of them is a poor resistance to organic solvent. Therefore, organic solvent resistant membranes were prepared by soluble polyimide. prepared by phase inversion method. The membranes were The homogeneous polymer solutions were obtained by the two different method ; the one is that the polymer sythesized was completely dissolved in a solvent to prepare a membrane casting solution, the other is that a membrane casting solution was prepared by the unit process from the viscose solution of polymerization.

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Preparation and characterization of polyethersulfone microfiltration membrane by 2-methoxy ethanol nonsolvent additive

  • Shin, Se-Jong;Kim, Hyung-Sik;Min, Byoung-Ryul
    • Proceedings of the Membrane Society of Korea Conference
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    • 2004.05a
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    • pp.166-169
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    • 2004
  • Microfiltration membranes were prepared from aromatic polyethersulfone (PES) polymer, using aprotic solvent (N-methyl-2-pyrrolidone, NMP) and non-solvent additive (2-methoxy ethanol, 2-ME) by the phase inversion co-process of the vapor-induced phase inversion (VIPI) and the nonsolvent-induced phase inversion (NIPI). According to the change of the additive amount, the solvent amount and the relative humidity, membrane characterization was studied. The non-solvent additive in casting solution played an important role in membrane morphology. During the vapor-induced phase inversion, the relative humidity led to water sorption on the surface of casting dope at which pore formation was generated. The prepared membranes were characterized by scanning electron microscope observations, measurements of capillary flow porometer and pure water flux (PWP). Also the thermodynamic and kinetic properties of membrane-forming system were studied through coagulation value, light transmittance and viscosity.

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Solvent Vapor Annealing Effects in Contact Resistances of Zone-cast Benzothienobenzothiophene (C8-BTBT) Transistors

  • Kim, Chaewon;Jo, Anjae;Kim, Heeju;Kim, Miso;Lee, Jaegab;Lee, Mi Jung
    • Journal of the Korean Ceramic Society
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    • v.53 no.4
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    • pp.411-416
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    • 2016
  • Benzothienobenzothiophene ($C_8-BTBT$) is a soluble organic small molecule material with high crystallinity resulting from its strong self-organizing properties. In addition, the high mobility and easy fabrication of $C_8-BTBT$ make it very attractive in terms of organic thin-film transistors. In this work, we made $C_8-BTBT$ thin films by using the zone-casting method; we also used an organic solvent to treat the devices with solvent vapor annealing to improve the electrical properties. As a result, we confirmed improved mobility, threshold voltage, and subthreshold swing after solvent vapor annealing. To prove the effect of solvent vapor annealing, we used the simultaneous extraction model to extract the contact resistance from the current-voltage curve. We confirmed that the electrical properties improved with decreasing contact resistance.

Rheology of Slurries and Effects of Polymer Volume Ratio in Aqueous PZT Tape Casting

  • Yoon, Seok-Jin;Shin, Hyo-Soon;Lee, Dong-Kyun;Kang, Chong-Yun;Park, Ji-Won;Kim, Hyun-Jai
    • The Korean Journal of Ceramics
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    • v.7 no.1
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    • pp.16-19
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    • 2001
  • For the fast dry of the aqueous tape, the process which water was reaplaced by organic solvent was proposed. Socalled, it was the solvent washing dry. Three organic solvents (methanol, ethanol and acetone) were selected for the washing solvent. The weight loss of the washed tapes was measured to evaluate the dry rate of the tapes and dried tapes were examined the generation of the cracks with the variations of the organic solvent and the washing time. Methanol, ethanol and acetone were available organic solvents for this method. The tapes washed in methanol, ethanol and acetone were dried rapidly for twenty minutes. After thirty minutes, the weight losses were not found any more, The solvent of the lower surface tension can decreases the crack of dried tape. If solvent substitutes water completely, though it was fast dried, crack can be eliminated.

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