• 제목/요약/키워드: Casting solution

검색결과 414건 처리시간 0.03초

The effect of thermodynamic stability of casting solution on the membrane inversion process morphology and permeation properties in phase inversion process

  • Kim, Jeong-Hoon;Lee, Kew-Ho
    • 한국막학회:학술대회논문집
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    • 한국막학회 1995년도 춘계 총회 및 학술발표회
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    • pp.26-27
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    • 1995
  • Most of synthetic polymeric membranes used in ultrafiltration, reverse osmosis and microfiltration processes are prepared by phase inversion(or phase separation) technique. In this technique, a homogeneous polymer solution is cast into thin film or hollow fiber shape and then immersed into a nonsolvent coagulant bath. The exchange of solvent and nonsolvent across the interface between casting solution and coagu!ant can make the casting solution phase-separate and form a membrane with a symmetric or asymmetric structure. Because of importance of this technique in membrane field, many investigations have been dedicated to elucidate the mechanism of membrane formation by phase inversion technique.[1-10] These investigation have suggested that the structure formation and permeation properties of phase inversion membrane depend on the variables such as the nature and content of casting solution and coagulant, temperature of casting solution and coagulant, and the diffusional exchange rate of solvent and nonsolvent etc. which can be related to the thermodynamic and kinetic properties of the casting system. The variables such as the nature and content of casting solution can also be the important factor affecting the structure formation and permeation property of the phase inversion membrane.

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스퀴즈 캐스팅 제조법에 의한 자동차 엔진 마운틴 브래킷 개발에 관한 연구 (A Study on the Development for the Vehicle Engine Mountion Bracket Using Squeeze Casting)

  • 김순호
    • 동력기계공학회지
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    • 제7권4호
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    • pp.44-48
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    • 2003
  • Alumium alloys casting are gaining increased acceptance in the automotive and electronic industeries and squeeze casting is the most efficient method of manufacturing such mass produced parts. This study has been investigated the microstructures and mechanical properties of Al-7.0Si-0.4Mg(AC4C)alloy fabricated by squeeze casting process for development of Engine Mountain Bracket. The microstructure of squeeze casted specimen were composed of eutectic structure Alumimim solid solution and $Mg_2Si$ precipitates. The tensile strength of as-solid solution treatment Al-7.0Si-0.4Mg alloy revealed 2985MPa. It was found that Al-7.0Si-0.4Mg alloy have good aging hardening effect results are presented to show the validity of the control method.

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A study on the squeeze casting of Al-7.0Si-0.4Mg alloy for fuel system parts

  • Kim Soon-Ho;Kim Seong-Soo
    • International Journal of Precision Engineering and Manufacturing
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    • 제6권3호
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    • pp.56-59
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    • 2005
  • Aluminum alloy casting is gaining increased acceptance in automotive and electronic industries and especially, squeeze casting is the most efficient method of mass manufacturing of such parts. In this study, the microstructures and mechanical properties of Al-7.0Si-0.4Mg(AC4C) alloy fabricated by squeeze casting process for development of fuel system parts (fuel rail) are investigated. The microstructure of squeeze cast specimen was composed of eutectic structure aluminum solid solution and $Mg_2Si$ precipitates. The tensile strength of as-solid solution treatment Al-7.0Si-0.4Mg alloy was 298.5MPa. It was found that Al-7.0Si-0.4Mg alloy had good corrosion resistance in electrochemical polarization test.

Al-7.0Si-0.4Mg 합금 자동차 연료계 부품의 스퀴즈 캐스팅에 관한 연구 (A Study on the Squeeze Casting of Al-7.0Si-0.4Mg Alloy for Fuel System Parts)

  • 김순호
    • 한국정밀공학회지
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    • 제20권12호
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    • pp.48-54
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    • 2003
  • Alumium alloys casting are gaining increased acceptance in the automotive and electronic industeries and squeeze casting is the most efficient method of manufacturing such mass produced parts. This study has been investigated the microstructures and mechanical properties of Al-7.0Si-0.4Mg (AC4C) alloy fabricated by squeeze casting process for development of Fuel system Parts (Fuel rail). The microstructure of squeeze casted specimen were composed of eutectic structure Alumimim solid solution and $Mg_2$Si precipitates. The tensile strength of as-solid solution treatment Al-7.0Si-0.4Mg ahoy revealed 298.5MPa. It was found that Al-7.0Si-0.4Mg alloy have good corrosion resistance in electrochemical polarization test.

체적수축유동이 있는 포정합금의 방향성주조에 대한 상사해 (A Similarity Solution for the Directional Casting of Peritectic Alloys in the Presence of Shrinkage-Induced Flow)

  • 유호선;정재동;이준식
    • 대한기계학회논문집B
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    • 제25권4호
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    • pp.485-495
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    • 2001
  • This paper presents a similarity solution for the directional casting of binary peritectic alloys in the presence of shrinkage-induced flow. The present model retains essential ingredients of alloy solidification, such as temperature-solute coupling, macrosegregation, solid-liquid property differences, and finite back diffusion in the primary phase. An algorithm for simultaneously determining the peritectic and liquidus positions is newly developed, which proves to be more efficient and stable than the existing scheme. Sample calculations are performed for both hypo- and hyper-peritectic compositions. The results show that the present analysis is capable of properly resolving the solidification characteristics of peritectic alloys so that it can be used for validating numerical models as a test solution.

Controlling the pore size of macroporous membranes by adding non-solvent

  • Shin, Se-Jong;Im, Se-Jun;Park, Seung-Ryul;Lee, Seung-Yun;Min, Byoung-Ryul
    • 한국막학회:학술대회논문집
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    • 한국막학회 2003년도 The 4th Korea-Italy Workshop
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    • pp.107-114
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    • 2003
  • This study investigated the effect of 2-methoxy ethanol (2-Me) non-solvent as additive included in casting solution. Macroporous polymer membranes were prepared by using polyethersufone (PES)/N-methyl-2-pyrrolidone (NMP)/2-Me casting solution and water coagulant. The phase separation co-process of the vapor-induced phase separation (VIPS) and liquid-induced phase separation (LIPS) were used by means of membrane preparation method. The pore size and pore size distribution were controlled with additive (non-solvent), and measured with Automated Perm Porometer. By increasing additive (non-solvent) in the casting solution, the membranes produced changed from finger structure to sponge structure. That is due to the different diffusion rates. At slow diffusion process, sponge-like structure was formed and at fast diffusion process, finger-like structure was formed. Also relative humidity, evaporation time, temperature of casting solution and coagulation bath etc. had effects on the pore size distribution and the porosity of the membrane.

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전자기 연속 주조법을 이용한 의료용 타이타늄 합금 제작에 관한 연구 (Fabrication of Titanium alloy by Electromagnetic Continuous Casting (EMCC) Method for Medical Applications)

  • 최수지;이현재;백수현;현승균;정현도;문병문
    • 한국주조공학회지
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    • 제38권1호
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    • pp.9-15
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    • 2018
  • Electromagnetic continuous casting (EMCC) was used to fabricate Ti-6Al-4V alloys with properties suitable for medical applications. Ti-6Al-4V alloy ingots fabricated by EMCC were subjected to heat treatment, such as residual stress removing (RRS), furnace cooling after solution treatment (ST-FC) and water-cooling after solution treatment (ST-WC), in order to obtain characteristics suitable for the standard. After component analysis, the microstructure and mechanical properties (tensile strength and elongation) were evaluated by ICP, gas analysis, OM, SEM, a Rockwell hardness tester and universal testing machine. The Ti-6Al-4V alloy ingot fabricated by EMCC was fabricated without segregation, and the lamellar structure was observed in the RRS and ST-FC specimens. The ST-WC specimen showed only martensite structure. As a result of evaluating the mechanical properties based on the microstructure results, we found that the water-cooled heat treatment condition after the solution treatment was most suitable for the Ti-6Al-4V ELI standard.

Unstable Inverted Phases of Di- and Tri-block Copolymers on Solution-Casting Films

  • Sun Dachun;Huang Lei;Liang Haojun
    • Macromolecular Research
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    • 제13권2호
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    • pp.152-155
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    • 2005
  • A dynamic density functional theory is presented for the observation of the phase revolutions of a solution-casting film of di- and tri-block copolymers under solvent evaporation conditions. With the evaporation of the solvent, the inverted phases, the minor part of the component becomes the continuous phase at the higher solvent evaporation rate, as observed in this experiment. Further simulation revealed that these inverted phases are converted into the normal phase and the major part of the component becomes the continuous phase, implying that the inverted phases observed in this experiment are unstable.

수처리용 정밀여과 멤브레인의 제조 및 특성 연구 (Preparation and Characterization of Microfiltration Membranes for Water Treatment)

  • 정보람;김노원
    • 멤브레인
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    • 제24권1호
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    • pp.50-62
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    • 2014
  • 상 전이 공정을 이용하여 polysulfone계 비대칭 정밀 여과막을 제조하였다. Polysulfone/N-methyl-2-pyrrolidone/polyvinylpyrrolidone/phosphoric acid계로 이루어진 casting 용액을 사용하였으며 응고조로는 물을 사용하였다. 멤브레인 제조공정에 적용된 상 전이 공정으로 증기 유도 상 전이 공정을 적용하였으며 상대습도 74%에서 캐스팅 판의 온도와 노출 시간을 조절한 결과 기공의 크기와 구조에 있어 변화를 관찰할 수 있었다. 제조된 멤브레인의 구조는 SEM과 microflow permporometer를 사용하여 조사하였다. Phosphoric acid의 첨가는 조밀한 스펀지 형태의 멤브레인을 느슨한 스펀지 형태의 멤브레인으로 변화시켰으며 촉매량의 Phosphoric acid 첨가로도 평균 기공크기는 거의 $0.2{\mu}m$ 정도 커지고 유량도 약 3,000 LMH가 증가하였다. 캐스팅 판의 온도와 노출 시간의 변화는 표면층의 구조, 기공의 크기 및 공극률에 큰 변화를 가져옴을 확인할 수 있었다.

Coupled approach of analytical and numerical methods for shape prediction in sheet casting process

  • Chae, Kyung-Sun;Lee, Seong-Jae;Ahn, Kyung-Hyun;Lee, Seung-Jong
    • Korea-Australia Rheology Journal
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    • 제13권3호
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    • pp.131-139
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    • 2001
  • A coupled approach is proposed for the prediction of sheet profile in sheet casting process, which combines one-dimensional analytical method on planar elongational flow region and three-dimensional numerical method on the other region. The strategy is constructed from the observations that the flow domain of sheet casting process can be separated into two parts based old the flow kinematics. The flow field in the central region of sheet, over which the planar elongational flow dominates, is possibly replaced by one-dimensional analytical solution. Then only a partial flow domain near the edge region of sheet, where the flow kinematics cannot be described by the planar elongational flow itself, requires three-dimensional numerical simulation. Good agreement is observed between the coupled approach developed in this study and the full three-dimensional numerical simulation previously developed and reported by the authors. This coupled approach may have provided flexibility with low costs to accommodate a wide range of die sizes in sheet casting process.

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