• Title/Summary/Keyword: Carbonation velocity

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Preparation of Regenerated Cellulose Fiber via Carbonation (II) - Spinning and Characterization -

  • Oh Sang Youn;Yoo Dong Il;Shin Younsook;Kim Hak Yong;Kim Hwan Chul;Chung Yong Sik;Park Won Ho;Youk Ji Ho
    • Fibers and Polymers
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    • v.6 no.2
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    • pp.95-102
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    • 2005
  • Sodium cellulose carbonate (CC-Na) dissolved in $8.5\;wt\%$ NaOH/ZnO (100/2-3, w/w) aqueous solution was spun into some acidic coagulant systems. Diameter of regenerated cellulose fibers obtained was in the range of $15-50\;{\mu}m$. Serrated or circular cross sectional views were obtained by controlling salt concentration or acidity in the acid/salt/water coagulant systems. Velocity ratio of take-up to spinning was controlled up to 4/1 with increasing spinning velocity from 5 to 40 m/min. Skin structure of was developed at lower acidity or higher concentration of coagulants. Fineness, tenacity and elongation of the regenerated cellulose fibers were in the range of 1.5-27 denier, 1.2-2.2 g/d, and $8-11.3\;\%$, respectively. All of CC-Na and cellulose fibers spun from CC-Na exhibited cellulose II crystalline structure. Crystallinity index was increased with increasing take-up speed.

A Study on the Corrosion Properties of Reinforcing bar and Performance Evaluation of Repair Material and Method for Reinforced Concrete Structure by Exposure Experiment under the Coastal and Normal Atmosphere Environment (해양 및 일반대기환경의 폭로실험에 의한 철근콘크리트구조물 보수재료.공법의 성능평가 및 철근의 부식특성에 관한 연구)

  • Nam Jeong-Soo;Roh Kyung-Min;Shin Seung-Bong;Kim Young-Sun;kim Gyu-Yong;Kim Moo-Han
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2006.05a
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    • pp.167-171
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    • 2006
  • In this study, for the establishment of the performance evaluation methods of repair material and method for reinforced concrete structure and the quality control standards of durability recovery method, the quantitative exposure data by exposure experiment under the coastal and normal atmosphere environment is accumulated and analyzed. Investigating and evaluating the result of exposure experiment during 30 months of exposure age under the coastal and normal atmosphere environment, carbonation depth and chlorideion penetration depth very little penetrated than cover depth. It seems reasonable to conclude that main cause of corrosion of reinforcing bar are inner chloride-ion and macro cell from the result of corrosion area and corrosion velocity. Accordingly, it is considered that fundamental data on the performance evaluation and quality control standards of repair material and method could be presented through continuous exposure test in the future.

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A Study on the Engineering Properties of Concrete Using High Volume of Volcanic Ash (화산재를 대량 사용한 콘크리트의 특성)

  • Jo Byung Wan;Koo Ja Kap;Park Seung Kook;Lee Yeon Jin
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.05b
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    • pp.33-36
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    • 2005
  • Recently, the use of volcanic-ash as a part of cement content in concrete is very common. But, it has been indicated that the compressive strength of concrete using large amount of volcanic-ash as a part of cement content in early age is low and carbonation velocity is fast. To solve those problems, High Volume Volcanic-Ash Concrete which contained large amount of volcanic-ash as a part of fine aggregate has been proposed. This is an experimential study to compare and analyze the properties of High Volumn Volcanic-Ash Concrete according to the replacement method and ratio of volcanic-ash. For this purpose, the mix proportion of concrete according to the replacement method(PL, C10, C150, A10, A100, A150) And then slump, setting time, bleeding, compressive strength, tensile strength and carbornation test were performed. According to test results, it was found that the compressive strength of the concrete using the volcanic-ash as a part of fine aggregate(A) was higher than that of the concrete using the volcanic-ash as a part of cement content(C). And, the compressive strength of the A concrete increased in early age as well as in long tern age as the volcanic-ash content increased.

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Estimation of Compressive Strength for Existing Concrete Structures by Non-Destructive Tests (비파괴시험에 의한 기존 콘크리트 구조물의 압축강도 추정)

  • 구봉근;오병환;김영의;김태봉;한승환
    • Magazine of the Korea Concrete Institute
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    • v.6 no.6
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    • pp.159-172
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    • 1994
  • The relmund hammer test and ultrasonic pulse velocity test methods are commonly used to determine the in-situ compressive strength of concrete. One of the special feature of these methods is that they cannot give consistent and reliable results for variety of structures. In particular, very old existing structures have been generally received sreious environmental affectsand thus the strength prediction will be different from normal structures. The purpose of the present study is, therefore, to propose realistic equations to predict the in-situ strengths of actual old concrete structures. The rebound hammer and ultrasonic pulse velocity tests, carbonation depth measurments and core compressive strength measurements have been carried out for very old hydraulic and seacoast concrete structures spanning from one to about seventy years in age. From these test results, the strength-rebound number relations, the strength-pluse velocity relatinns and the strength-rebound number-pluse velocity relations have been obtained through multiple regression analysis. The present study indicates that the existing equations by nondestructive tests give quite different results from the present data. The proposed equations reasonably well predict the measured data for old concrete structures, especially for low strength concrete. The prediction equations proposed here can be efficiently used in determining the in-situ strength of old concrete structures.

Performance Evaluation of Repair Material and Method for Reinforced Concrete Structure by Long Term Exposure Experiment (장기폭로실험에 의한 철근콘크리트 구조물의 보수재료.공법 성능평가)

  • Kim, Moo-Han;Kim, Gyu-Yong;Cho, Bong-Suk;Kim, Young-Duck;Kim, Young-Sun
    • Journal of the Korea Concrete Institute
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    • v.19 no.1
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    • pp.39-46
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    • 2007
  • In this study, for the establishment of the performance evaluation methods and the quality control standards of durability recovery method, the quantitative exposure data by long term exposure test under the coast and normal atmosphere is accumulated and analyzed. Investigating and evaluating the result of exposure test during 30 months of exposure age under the coastal and normal atmosphere environment, carbonation depth and chloride-ion penetration depth very little penetrated than cover depth. It seems reasonable to conclude that main cause of Corrosion of reinforcing bar are chloride-ion and macro cell from the result of corrosion area and corrosion velocity. Therefore, it is considered to be applied as the fundamental data on the performance evaluation and quality control standards of repair material and method through continuous exposure test in the future.

Evaluation on the Shrinkage and Durability of Cementless Alkali-Activated Mortar (무(無)시멘트 알칼리 활성(活性) 모르타르의 수축(收縮) 및 내구성(耐久性) 평가(評價))

  • Koh, Kyung-Taek;Ryu, Gum-Sung;Lee, Jang-Hwa;Kang, Hyun-Jin
    • Resources Recycling
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    • v.20 no.3
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    • pp.40-47
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    • 2011
  • In this study, we investigated the strength, shrinkage and durability of alkali-activated mortar using blast furnace slag only, and admixed with blast-furnace slag and fly ash as cementious materials in oder to develop cementless alkali-activated concrete. In order to compare with the alkali-activated mortar, the normal mortar using ordinary portland cement was also test. In view of the results, we found out that strength development, the resistance to shrinkage and freezing-thawing of the cementless alkali-activated mortar have better than the mortar using ordinary portland cement. Especially, using the combined with blast furnace slag and fly ash develop high strength of above 60 MPa, reduce shrinkage of about 40% and improve freezing-thawing durability of approximately 20%, but promote the velocity of carbonation of 2~3 times.

Strength Development and Durability of Geopolymer Mortar Using the Combined Fly ash and Blast-Furnace Slag (플라이애시와 고로슬래그 미분말을 혼합 사용한 지오폴리머 모르타르의 강도발현 및 내구성)

  • Ryu, Gum-Sung;Koh, Kyung-Taek;Lee, Jang-Hwa
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.1 no.1
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    • pp.35-41
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    • 2013
  • In this study, we investigated the strength development and durability of geopolymer mortar using blast furnace slag only, and admixed with blast-furnace slag and fly ash as cementious materials in oder to develop cementless geopolymer concrete. In order to compare with the geopolymer mortar, the normal mortar using ordinary portland cement was also test. In view of the results, we found out that strength development, the resistance to freezing-thawing of the geopolymer mortar have better than the mortar using ordinary portland cement. Especially, using the combined with blast furnace slag and fly ash develop high strength of above 60 MPa, and improve the resistance of freezing-thawing of approximately 20%, but promote the velocity of carbonation of 2.2~3.5 times.

An Experimental Study on Engineering Properties of Self-healing Mortar according to PCC(Powder Compacted Capsule) Size and Mixing Ratio (PCC(Powder Compacted Capsule) 크기 및 혼입율에 따른 자기치유 모르타르의 공학적 특성에 관한 실험적 연구)

  • Jae-In, Lee;Chae-Young, Kim;Se-Jin, Choi
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.10 no.4
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    • pp.514-522
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    • 2022
  • In this study, as part of a study to improve the self-healing performance of concrete structures by applying self-healing capsules made of cementitious materials to cement composite materials, the engineering characteristics of mortars according to PCC(Powder Compacted Capsule) size and mixing ratio were compared and analyzed. For this, fluidity, compressive strength, reload test, carbonation, ultrasonic velocity, and water permeability characteristics were measured according to PCC size and mixing ratio of mortar. As a result of the measurement, the fluidity and compressive strength increased as the mixing ratio of PCC increased, and in the case of the load reload test, the healing ratio increased as the mixing ratio of PCC increased in the 03PC formulation. In the case of water permeability test, it was found that when PCC was used, the reduction ratio of water flow was up to 35 % higher than that of Plain, and when PCC with a size of 0.3 to 0.6 mm was mixed with 15 %, it was found to be effective in improving the crack healing ratio of the mortar.

Improvement of Durability and Change of Pore Structure for Concrete Surface by the Penetrative Surface Protection Agent (함침계 표면보호제에 의한 콘크리트 표면의 세공구조 변화 및 내구성 향상)

  • Kang, Suk-Pyo;Kim, Jung-Hwan
    • Journal of the Korea Concrete Institute
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    • v.18 no.1 s.91
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    • pp.125-132
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    • 2006
  • Recently, surface finishing and protection materials were developed to restore performance of the deteriorated concrete and inhibiting corrosion of the reinforcing-bar. For this purpose, surface protection agent as well as coatings are used. Coatings have the advantage of low Permeability of $CO_2,\;SO_2$ and water. However, for coatings such as epoxy, urethane and acryl, long-term adhesive strength is reduced and the formed membrane of those is blistered by various causes. Also when organic coatings are applied to the wet surface of concrete, those have a problem with adhesion. On the other hand, surface protection agent penetrates into pore structure in concrete through capillary and cm make a dense micro structure in concrete as a result of filling effect. Furthermore, the chemical reaction between silicate from surface protection agent and cement hydrates can also make a additional hydration product which is ideally compatible with concrete body. The aim of this study is to examine the effect of penetrative surface protection agent(SPA) by evaluating several concrete durability characteristics. The results show that the concrete penetrated surface protection agent exhibited higher durability characteristics for instance, carbonation velocity coefficient, resistance to chemical attack and chloride ion penetration than the plain concrete. These results due to formation of a discontinuous macro-pore system which inhibits deterioration factors of concrete by changed the pore structure(porosity and pore size distributions) of the concrete penetrated surface protection agent.