• Title/Summary/Keyword: Carbon-clay

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Changes in Benzo(a)pyrene Content During Processing of Corn Oil (옥수수 기름의 제조공정별 벤조피렌 함량 변화)

  • Kim, Duk-Sook;Lee, Keun-Bo
    • Food Science and Preservation
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    • v.16 no.1
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    • pp.75-81
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    • 2009
  • Benzo(a)pyrene[B(a)P] levels were determined in processed oils and by-products of corn oil, and removal protocol was formulated. The cause of high level B(a)P contents in corn oil was established. Corn germ had a B(a)P level more than 80% that of whole corn. B(a)P content in final deodorized corn oil was $2.15{\mu}g/kg$, after the usual refining process. B(a)P contents less than $2.0{\mu}g/kg$ could not be attained by routine refining process. However, deodorized corn oil, with B(a)P level of $0.09{\mu}g/kg$, could be prepared by treatment of oil with approximately 2% (w/w) mixed granules(acidic clay:active carbon= 90:10[w/w]). The optimal amount of active carbon was 10% (w/w) that of acidic clay;higher levels of active carbon was not required. The optimal particle size of active carbon was $50{\sim}100$ mesh, removal of B(a)P from bleached corn oil was efficient at this mesh size.

Properties of Low Carbon Type Hydraulic Cement Binder Using Waste Recycle Powder (무기계 재생원료를 사용한 저탄소형 수경성 시멘트 결합재의 특성)

  • Song, Hun;Shin, Hyeon-Uk;Tae, Sung-Ho
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.1
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    • pp.22-28
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    • 2019
  • Cement is a basic material for the construction industry and it requires high temperature sintering when manufacturing cement. $CO_2$ emissions from raw materials and fuels are recognized as new environmental problems and efforts are underway to reduce them. Techniques for reducing $CO_2$ in concrete are also recommended to use blended cement such as blast furnace slag or fly ash. In addition, the construction waste generated in the dismantling of concrete structures is recognized as another environmental problem. Thus, various methods are being implemented to increase the recycling rate. The purpose of this study is to utilize the inorganic raw materials generated during the dismantling of the structure as a raw material for the low carbon type cement binder. Such as, waste concrete powder, waste cement block, waste clay brick and waste textile as raw materials for low carbon type cement binder. From the research results, low carbon type cement binder was manufactured from the raw material composition of waste concrete powder, waste cement block, waste clay brick and waste textile.

Nanoconfinement of Hydrogen and Carbon Dioxide in Palygorskite (팔리고스카이트 내 수소 및 이산화탄소 나노공간한정)

  • Juhyeok Kim;Kideok D. Kwon
    • Korean Journal of Mineralogy and Petrology
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    • v.36 no.4
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    • pp.221-232
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    • 2023
  • Carbon neutrality requires carbon dioxide reduction technology and alternative green energy sources. Palygorskite is a clay mineral with a ribbon structure and possess a large surface area due to the nanoscale pore size. The clay mineral has been proposed as a potential material to capture carbon dioxide (CO2) and possibly to store eco-friendly hydrogen gas (H2). We report our preliminary results of grand canonical Monte Carlo (GCMC) simulations that investigated the adsorption isotherms and mechanisms of CO2 and H2 into palygorskite nanopores at room temperature. As the chemical potential of gas increased, the adsorbed amount of CO2 or H2 within the palygorskite nanopores increased. Compared to CO2, injection of H2 into palygorskite required higher energy. The mean squared displacement within palygorskite nanopores was much higher for H2 than for CO2, which is consistent with experiments. Our simulations found that CO2 molecules were arranged in a row in the nanopores, while H2 molecules showed highly disordered arrangement. This simulation method is promising for finding Earth materials suitable for CO2 capture and H2 storage and also expected to contribute to fundamental understanding of fluid-mineral interactions in the geological underground.

Study on the Utilization of Barite in Making Carbon Film Ceramic Resistor (탄소피막 저항기용 자기소체 제조에 있어 Barite 활용에 관한 연구)

  • 박정현;전병세;배원태
    • Journal of the Korean Ceramic Society
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    • v.19 no.2
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    • pp.95-100
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    • 1982
  • Instead of barium carbonate, domestic barite was used as the flux in manufacturing theinsulating porcelain. To avoid the problems arising from the decomposition of barite in the body during firing, BaO.$Al_2O_3$ was synthesized at $1300^{\circ}C$ for 5 hours. synthetic BaO.$Al_2O_3$ was mixed with other materials such as kaoline, alumina, clay, dolomite. The RO content (CaO. MgO. BaO) of the batches was varied from range of 4 to 14wt. % at 2wt. % - intervals, and firing temperature was varied from 1280 to 140$0^{\circ}C$-at 4$0^{\circ}C$ intervals The properties such as water absorption, bulk density. mechnical strength, specific resistance, and linear shrinkage were measured. The body containing 12 wt.% of RO content showed the satisfactory for the application in the Fixed Carbon Film Resistor.

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Some DTPA Extractable Micronutrients in Different Hill Forest Soils of Chittagong Region, Bangladesh

  • Akhtaruzzaman, Md.;Osman, K.T.;Sirajul Haque, S.M.
    • Journal of Forest and Environmental Science
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    • v.32 no.1
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    • pp.20-26
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    • 2016
  • DTPA (Diethelene-triamine pentaacetic acid) extractable micronutrients of surface soil samples from six different locations of Cox's Bazar and Chittagong districts were studied. All the soils under study were sufficient in DTPA extractable Fe, Mn and Cu contents. The available Zn contents in soils of Dulhazara, Chengchhari and Faissakhali under study were also above the critical limit while soils at Fulchhari, Hasnabad and CU were deficient in available Zn. The study also showed that DTPA extractable Fe content had the significant and positive relationships with clay and soil organic carbon. On the hand, negative and significant relationship was observed between extractable Mn and soil pH while DTPA extractable Zn and Cu were positively and significantly correlated with soil organic carbon of the studied area.

A Study on the Estimation Method of the Environmental Load Intensity for Analyzing GHG Reduction Effect of Han-Ok

  • Kim, Sunghee
    • Architectural research
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    • v.15 no.3
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    • pp.143-150
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    • 2013
  • The Korean government recently has rediscovered the potential value of Han-Ok, the Korean traditional house, as an eco-friendly building. In order to objectively verify the environmental performance of Han-Ok as a low carbon green building, this paper suggests the analysis method of GHG emission load of Korean traditional house, based on Life Cycle Assessment, which is commonly abbreviated to "LCA". The environmental impacts caused by building construction and operation can be analyzed through the sum of input and output data from every phase. The study particularly describes the GHG reduction effect by using traditional building materials such as wood products, traditional clay roof tiles, and mud, which are mainly used to construct Han-Ok. Also the study proposes the method for comparative analysis of quantity of GHG emissions in building's entire life cycle so that the data can be used as a reliable basis to optimize the environmental performance of building.

Permeabilities of Korean Earthenware Containers and Their Potential for Packaging Fresh Produce

  • Seo, Gyeong-Hee;Chung, Sun-Kyung;An, Duck-Soon;Lee, Dong-Sun
    • Food Science and Biotechnology
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    • v.14 no.1
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    • pp.82-88
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    • 2005
  • Ethnic Korean onggi earthenwares were fabricated using different clay formulations and glazing treatments. Their permeability properties against oxygen, carbon dioxide, and moisture were measured at $20^{\circ}C$ and examined from the aspect of food preservation. Onggi walls consisted of micropores that offered higher gas and moisture permeation rates when compared with other food packaging materials. Earthenware walls were unique in having $CO_2/O_2$ permeability ratios of 0.60-1.00. Gas and moisture permeabilities were lower, with wall structure having lower porosity and surface glazing. Results revealed onggi jar packages of grape fruits could attain wide range of $O_2$ and $CO_2$ concentrations. Onggi containers present good opportunity to obtain optimum packaging conditions for respiring or ripening products, depending on commodity type.

A Study on Properties of Domestic Fly Ash and Utilization as an Insulation material (국산 Fly Ash의 특성 및 단열재로의 이용에 관한 연구)

  • 박금철;임태영
    • Journal of the Korean Ceramic Society
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    • v.20 no.2
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    • pp.135-146
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    • 1983
  • This study is to investigate the properties of domestic fly ash for utilization as data in regard to fly ash which is by-product of domestic coal powder plants and the possibility of utilization as insulation material of domestic fly ash. Composition refractoriness size distribution density contents of hollow particles and crystalline phase were examined as the properties of domestic fly ash. As to the fired test pieces of fly ash by itself that varied contents of hollow particles with four kinds and of the fly ash-clay-saw dust system linear shrinkage bulk density app. porosity compressive strength thermal conductivity and structures were investigated for the possibility of utilization as an insulation material. The results are as follows : 1. The properties of the fly ash I) The constituent particle of the fly ash is spherical and it contains not a few hollow particles (floats by water 0.30-0.50 floats by $ZnCl_2$ aq.(SpG=1.71) 6.97-16.72%). ii) The chemical compositions of fly ash are $SiO_243.9-54.1%$ , $Al_2O_321.0-30.7%$ Ig loss is 7.4-24.1% and the principal of Ig loss is unburned carbon. iii) Fly ash was not suitable to use for mortar and concrete mixture because Ig. loss value is higher than 5% 2. Utilization as insulation material I) The test pieces of original fly ash floats by water floats by ZnCl2 aq(SpG=1.71) p, p t by ZnCl2 aq.(SpG=1.71) that were fired at 110$0^{\circ}C$ represented 0.11-0.18 kcal/mh$^{\circ}$ C as thermal conductivity value. ii) The test pieces which (76.5-85.5) wt% fly ash-(8.5, 9.5) wt% clay-(5.0-15.0) wt% saw dust system(68.0-72.0) wt% fly ash -(17.0-18.0)wt% clay-(10.0-15.0) wt% saw dust system and 59.5 wt% fly ash-25.5 wt% clay-15.0wt% saw dust system were fired at 110$0^{\circ}C$ the thermal conductivity was less than 0.1Kcal/mh$^{\circ}$ C. iii) In view of thermal conductivity and economic aspect insulation materials which added saw dust as blowing agent and clay as inorganic binder are better than that of fly ash as it is or separated hollow fly ash particles. iv) When the saw dust contents increased in the (59.5-90.0) wt% saw dust system and when amount of clay de-creased and firing temperature decreased under the condition of equal addition of saw dust app. porosity increased but bulk density compressive strength and thermal conductivity decreased.

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Analysis on the Seepage Behavior of Organic Contaminants in Soil (토양에서 유기화합물질의 침투 거동 연구)

  • Lee, Jun Ho;Han, Sun Hyang;Park, Kap Song
    • Journal of Korean Society on Water Environment
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    • v.29 no.4
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    • pp.489-496
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    • 2013
  • Ground water underlying soil is vulnerable to pollution by organic chemicals through their percolation through the soil system. This study was conducted to provide information on the seepage behavior of organic chemical contaminants in clay, silty and sandy soils. Chloroform, 1,1,1-trichloroethane and trichloroethylene are readily transported through the soil; their percolated mass were 4.6-19.2 percent of the total mass applied. Tetrachloroethylene, 1,2-dichlorobenzene and 1,3-dichlorobenzene were retarded by soils due to sorption. Between 0.6 and 4.8 percent of the material applied to the surface percolated within the experimental period. Carbon tetrachloride was attenuated considerably by passage through soils. Only 0.1-0.4 percent of the mass reached the groundwater. Significant degradation of bromoform was observed. Apparent breakdown of intermediates of the brominated compounds were detected. Transformations of the brominated compounds appear to be the result of both biological and chemical processes. The effect of soil type on the mobility of organic chemical contaminants was considerable. The organic contaminants moved faster in sandy soil than in either clay or silty soils.

The Removal of Algae by Pre-oxidation (전산화 공정을 이용한 조류제거)

  • Son, Hee-Jong;Jung, Chul-Woo;Bae, Sang-Dae;Choi, Young-Ik;Kang, Lim-Seok
    • Journal of Environmental Science International
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    • v.18 no.3
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    • pp.289-298
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    • 2009
  • The blue-green algae which caused odor problem in the tap water are difficult to precipitate in sedimentation basin and clogged the filter void rapidly. The studies of this paper were not only oxidation, coagulation and sedimentation processes for effectively removing blue-green algae but yellow clay and polyamine for verification as coagulants aids. The results of this research are summarized as follows: Higher ozone dose(C) and longer contact time(T) were needed for a high degree of removing blue-green algae efficiency. the removal rate of blue-green algae was proportional to the $C\times T$ value. The removal percent of chlorophyll-a by sedimentation and filter without pre-ozonation was about 75% but 1 mg/L pre-ozonation could increase the removal percent of chlorophyll-a to 99% and more pre-ozonation could remove completely. Though the removal efficiency of turbidity could increased by high dose of chlorination, the dissolved organic carbon was increased. More chlorine dose from 4 to 10 mg/L dissolved organic carbon was decreased. Using yellow clay as coagulant aids increased density of floc so the settling velocity of floc become rising but polyamine could not increase settling velocity of floc though it could formated large floc.