• Proceedings of the Korean Vacuum Society Conference
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• 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
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• pp.237.2-237.2
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• 2016

A pure hafnium-carbide (HfC) coating layer was deposited onto carbon/carbon (C.C) composites using a vacuum plasma spray system. By adopting a SiC buffer layer, we successfully integrated C.C composites with a $100-{\mu}m-thick$ protective coating layer of HfC. Compared to the conventional chemical vapor deposition process, the HfC coating process by VPS showed increased growth rate, thickness, and hardness. The growth behavior and morphology of HfC coatings were investigated by FE-SEM, EDX, and XRD. From these results, it was shown that the addition of a SiC intermediate layer provided optimal surface conditions during the VPS procedure to enhance adhesion between C.C and HfC (without delamination). The thermal ablation test results shows that the HfC coating layer perfectly protected inner C.C layer from thermal ablation and oxidation. Consequently, we expect that this ultra-high temperature ceramic coating method, and the subsequent microstructure that it creates, can be widely applied to improve the thermal shock and oxidation resistance of materials under ultra-high temperature environments.

• Journal of the Korean Ceramic Society
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• 제46권3호
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• pp.234-241
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• 2009

In this study, CNT/$TiO_2$ composites derived from various titanium alkoxides and multiwalled carbon nanotubes (MWCNTs) were synthesized and characterized. Surface areas and pore volumes of the CNT/$TiO_2$ samples showed catastrophic decrease due to deposition of titanium compounds. Scanning electron microscopy (SEM) results indicated that the MWCNTs were homogenously decorated and well-dispersed onto/into the composites without apparent agglomeration of $TiO_2$ particles. In the X-ray diffraction (XRD) patterns, peaks of anatase and rutile phase were observed. The energy dispersive X-ray spectroscopy (EDX) spectra revealed the presence of major elements such as C and O with strong Ti peaks. According to the photocatalytic results, MB removal by a treatment with CNT/$TiO_2$ composites seems to have an excellent removal effect as order of CTIP, CTNB and CTPP composites due to a photolysis of the supported $TiO_2$, the radical reaction and the adsorptivity and absorptivity of the MWCNTs.

• Journal of the Korean Ceramic Society
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• 제35권7호
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• pp.740-748
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• 1998

The inertia friction properties of C/C composites manufactured by the processes of pressure and at-mospheric carbonizaton with a commerciallized and two kinds of modified coal-tar pitch as a matrix pre-cursor were investigated. The modifications of a pitch such as the introduction of mesophase and the ad-dition of sulphur into a raw pitch were not effective for a impregnation efficiency conducted in a vacuum and at the same time in a pressure of 5kg/cm2 due to the increase of the pitch viscosity. There was not a difference in the densification increment between the pitch modifications however it was revealed that a pressure carbonization was more advantageous than an atmospheric in the densification and the formation of anisotropic carbon matrix. The friction and wear propertis of C/C having higher degree of matrix cry-stallization higher density and hardness of friction surface showed superiority. As the braking energy was increased the friction coefficients were decreased and reached almost same level at the high kinetic energy of 99.6kJ. The wear trends at 99.6kJ were different from the behaviors of friction ceofficient under the same energy in which an oxidation wear is being considered along with a mechnical wear although the wear rates were almost similar to the friction coefficient at the low energy.

• Journal of the Korean Ceramic Society
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• 제48권5호
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• pp.433-438
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• 2011

In this study, CdS combined activated carbon/$TiO_2$ (CdS-AC/$TiO_2$) composites were prepared by a sol-gel method to improve the photocatalytic performance of $TiO_2$. These composites were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDX) and UV-vis analysis. The photocatalytic activities were examined by the degradation of methylene blue (MB) under visible light irradiation. The photodegradation rate of MB under visible light irradiation reached 90.1% in 120 min. The kinetics of MB degradation was plotted alongside the values calculated from the Langmuir-Hinshelwood equation. The 0.2 CAT sample showed the best photocatalytic activity, which might be due to an increase in the photo-absorption effect by activated carbon and the cooperative effect of CdS.

• Journal of the Korean Ceramic Society
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• 제46권6호
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• pp.554-560
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• 2009

We investigate a method for the electrochemical preparation of titanium dioxide/carbon nanotube ($TiO_2$/CNT) composites involving the electroplating of Ti in a titanium n-butoxide (TNB) electrolyte into a CNT matrix. The Brunauer-Emmett-Teller (BET) surface areas of $TiO_2$/CNT composites decrease as the electrochemical operating time increases. Changes in XRD patterns show a typical anatase type on the $TiO_2$/CNT composite prepared with a CNT matrix by the electroplating method in a TNB solution. In SEM micrographs, the titanium complex particles are uniformly distributed on the CNT surface. The results of chemical elemental analysis for the $TiO_2$/CNT composites show that most of the spectra for these samples produce stronger peaks for carbon and Ti metal than for any other element. Finally, the prominent photoelectrocatalytic activities of the $TiO_2$/CNT composites can be attributed to the combined effects of photodegradation of $TiO_2$, electron assistance of CNT, and the application of a sufficient voltage.

• Journal of the Korean Ceramic Society
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• 제46권4호
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• pp.357-364
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• 2009

We investigate a method for the electrochemical preparation of titanium dioxide/carbon nanotube ($TiO_2$/CNT) composites involving the electroplating of Ti in a titanium n-butoxide (TNB) electrolyte into a CNT matrix. The BET surface areas of $TiO_2$/CNT composites decreased as electrochemical operating time increased. Changes in XRD patterns showed a typical anatase type on the $TiO_2$/CNT composite prepared with a CNT matrix by the electroplating method in the TNB solution. In SEM micrographs, the titanium complex particles were uniformly distributed on the CNT surface. The results of chemical elemental analysis for the $TiO_2$/CNT composites showed that most of the spectra for these samples produced stronger peaks for carbon and Ti metal than those of any other element. Finally, the prominent photoelectrocatalytic (PEC) activities of the $TiO_2$/CNT composites could be attributed to the combined effects of photodegradation of $TiO_2$, electron assistance of CNT and the application of a sufficient voltage.

• Journal of the Korean Ceramic Society
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• 제38권1호
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• pp.52-55
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• 2001

Polyacrylonitrile(PAN)-based 탄소섬유와 epoxy resin matrix 내에 장착된 PAN-based 탄소섬유의 전기저항을 탄소섬유와 파괴될 때까지 인장강도를 증가시키며 측정하였다. 탄소섬유가 끊어져 측정 계기가 open-circuit을 나타내기 전까지 탄소섬유의 전기저항 값은 strain이 증가할수록 증가하였으며, epoxy resin은 탄소섬유의 저항값 측정에 거의 영향을 미치지 않았다. 탄소섬유의 저항값 변화는 strain에 대해 정확도 1% 이내로 예측(calibrate)할 수 있었으며 재현성 또한 우수하였다. 따라서 탄소섬유는 재료의 기계적 강도를 증가시키기 위해 사용될 수 있을 뿐만 아니라 구조재료의 파괴를 예측할 수 있는 스마트 센서로서도 사용할 수 있다는 가능성을 확인하였다.

• Proceedings of the Korean Ceranic Society Conference
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• 한국세라믹학회 2000년도 춘계총회,특별강연,심포지움,연구발표회
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• pp.71.1-71.1
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• 2000

• Journal of Ceramic Processing Research
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• 제21권2호
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• pp.170-191
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• 2020

As interest in environmental pollution has increased, research in the field of filtration has been concentrated. While various types of filters have been developed, research on nanomaterial filtration has been limited. Since then, the development of new materials such as carbon nanotubes (CNTs) has accelerated the study of new filters. Especially, CNTs have been among the most attractive materials ever synthesized for the development of nano-technologies. However, there are fundamental technical problems to be solved the development of new CNT composites. One of these problems is the development of a CNTs filter with excellent adsorption behavior and a filter that is capable of filtering a specific substance. In addition, it is necessary to develop a technology to increase the uniform distribution of CNTs, and to reduce the high processing cost of CNT composite production. In general, the chemical pathways for the production of CNTs include hydrocarbon gases, such as methane (CH4) and acetylene (C2H2), through metal nanoparticle catalysts. However, nano-metal particles have a strong coagulation phenomenon at high temperature by catalytic chemical vapor deposition (CCVD) method. In this review, attempts were made by applying three different reaction techniques to form CNTs on biomorphic carbon materials (BCM) coated with catalyst materials to control the shape and size of CNTs. Hierarchical carbon substrates with pore size of 100 ~ 300 ㎛ were developed using carbonization reaction. Linde type A (LTA) zeolite, silicalite-1, and mesoporous SiO2 template crystals were simultaneously synthesized and coated on the BCM by an in-situ hydrothermal process to synthesize high-yield CNTs composites.

• Journal of Ceramic Processing Research
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• 제20권4호
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• pp.388-394
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• 2019

In this study, high-purity single-walled carbon nanotubes (SWCNTs) were prepared by removing the unreacted metal constituents and amorphous carbon impurities using a post-annealing process. Unlike conventional thermal processing techniques, this technique involved different gas atmospheres for efficient removal of impurities. A heat treatment was conducted in the presence of chlorine, oxygen, and chlorine + oxygen gases. The nanotubes demonstrated the best characteristics, when the heat treatment was conducted in the presence of a mixture of chlorine and oxygen gases. The scanning electron microscopy, transmission electron microscopy, ultraviolet absorbance, and sheet resistance measurements showed that the heat treatment process efficiently removed the unreacted metal and amorphous carbon impurities from the as-synthesized SWCNTs. The high-purity SWCNTs exhibited improved electrical conductivities. Such high-purity SWCNTs can be used in various carbon composites for improving the sensitivity of gas sensors.