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http://dx.doi.org/10.4191/KCERS.2009.46.3.234

Preparation and Photonic Properties of CNT/TiO2 Composites Derived from MWCNT and Organic Titanium Compounds  

Oh, Won-Chun (Department of Advanced Materials & Science Engineering, Hanseo University)
Publication Information
Abstract
In this study, CNT/$TiO_2$ composites derived from various titanium alkoxides and multiwalled carbon nanotubes (MWCNTs) were synthesized and characterized. Surface areas and pore volumes of the CNT/$TiO_2$ samples showed catastrophic decrease due to deposition of titanium compounds. Scanning electron microscopy (SEM) results indicated that the MWCNTs were homogenously decorated and well-dispersed onto/into the composites without apparent agglomeration of $TiO_2$ particles. In the X-ray diffraction (XRD) patterns, peaks of anatase and rutile phase were observed. The energy dispersive X-ray spectroscopy (EDX) spectra revealed the presence of major elements such as C and O with strong Ti peaks. According to the photocatalytic results, MB removal by a treatment with CNT/$TiO_2$ composites seems to have an excellent removal effect as order of CTIP, CTNB and CTPP composites due to a photolysis of the supported $TiO_2$, the radical reaction and the adsorptivity and absorptivity of the MWCNTs.
Keywords
MWCNT; Titanium alkoxide; SEM; XRD; EDX; Photolysis;
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Times Cited By KSCI : 8  (Citation Analysis)
Times Cited By SCOPUS : 3
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1 P. Vincent, A. Brioude, C. Journet, S. Rabaste, S.T. Purcell, J. Le Brusq, and J.C. Plenet, 'Inclusion of Carbon Nanotubes in a $TiO_2$ Sol-gel Matrix,' J. Non-Crystalline Solids, 311 130-37 (2002)   DOI   ScienceOn
2 R. Ulbricht, S.B. Lee, X. Jiang, K. Inoue, M. Zhang, S. Fang, R.H. Baughman, and A.A. Zakhidov, 'Transparent Carbon Nanotube Sheets as 3-D Charge Collectors in Organic Solar Cells,' Solar Energy Materials and Solar Cells, 91 [5] 416-19 (2007)   DOI   ScienceOn
3 N.B. Jackson, S.G. Thoma, S. Kohler, and T. M. Nenoff, 'Zirconium-titanium Phosphate Acid Catalysts Synthesized by Sol Gel Techniques,' Studies in Surface Science and Catalysis, 118 643-49 (1998)   DOI
4 S. Yang, W. Zhu, J. Wang, and Z. Chen, 'Catalytic Wet Air Oxidation of Phenol Over $CeO_2-TiO_2$ Catalyst in the Batch Reactor and the Packed-bed Reactor,' J. Hazardous Materials, 153 [3] 1248-53 (2008)   DOI   ScienceOn
5 X.H. Xia, Z.J. Jia, Y. Yu, Y. Liang, Z. Wang, and L.L. Ma, 'Preparation of Multi-walled Carbon Nanotube Supported $TiO_2 and its Photocatalytic Activity in the Reduction of CO_2 with H_2O$,' Carbon, 45 717-21 (2007)   DOI   ScienceOn
6 H. Kominami, J. Kato, Y. Takada, Y. Doushi, B. Ohtani, S. Nishimoto, M. Inoue, T. Inui, and Y. Kera, 'Novel Synthesis of Microcrystalline Titanium(IV) Oxide Having High Thermal Stability and Ultra-high Photocatalytic Activity: Thermal Decomposition of Titanium(IV) Alkoxide in Organic Solvents,' Catalysis Latters, 46 235-40 (1997)   DOI
7 W.C. Oh and M.L. Chen, 'Synthesis and Characterization of $CNT/TiO_2$ Composites Thermally Derived from MWCNT and Titanium (IV) n-butoxide,' Bull. Kor. Chem. Soc., 29 [1] 159-64 (2008)   DOI   ScienceOn
8 P.M. Ajayan, 'Nanotubes from Carbon,' Chem. Rev., 99 [7] 1787-92 (1999)   DOI   ScienceOn
9 R.H. Baughman, A.A. Zakhidov, and W.A. de Heer, 'Carbon Nanotubes-the Route Toward Applications,' Science, 297 [5582] 787-92 (2002)   DOI   ScienceOn
10 W.C. Oh, A.R. Jung, and W.B. Ko, 'Preparation of Fullerene/TiO2 Composite and its Photocatalytic Effect, ' J. Industrial and Engineering Chemistry, 13 [7] 1208-14 (2007)
11 W. Wang, P. Serp, P. Kalck, and J.L. Faria, 'Visible Light Photodegradation of Phenol on MWCNT-$TiO_2$ Composite Catalysts Prepared by a Modified Sol-gel Method,' J. Molecular Catalysis A: Chemical, 235 194-99 (2005)   DOI   ScienceOn
12 J.W. Patrick, 'Porocity in Carbon Characterization and Applications,' pp. 28-30, Edward Arnold, London, 1995
13 M.L. Chen, Y.S. Ko, and W.C. Oh, '$Carbon/TiO_2$ Prepared from to Pitch and their Photocatalytic Activity', Carbon Science, 8 [1] 6-11 (2007)
14 W.C. Oh, Synthesis and Characterization of Fe-containing $AC/TiO_2$ Composites and their Photodegradation Effect for the Piggery Waste, Environ. Eng. Res., 13 [2] 85-92 (2008)   DOI   ScienceOn
15 Y. Yu, J.C. Yu, J.G. Yu, Y.C. Kwok, Y.K. Che, J.C. Zhao, L. Ding, W.K. Ge, and P.K. Wang 'Enhancement of Photocatalytic Activity of Mesoporous $Tio_2$ by using Carbon Nanotubes,' Appl. Cat. B: Environ, 289 186-96 (2005)   DOI   ScienceOn
16 Z.S. Guan, X.T. Zhang, Y. Ma, Y.A. Cao, and J. N. Yao, 'Photocatalytic Activity of TiO2 Prepared at Low Temperature by a Photo-assisted Sol-gel Method,' J. Mater. Res., 16 [4] 907-09 (2001)   DOI   ScienceOn
17 W.Wang, P. Serp, P. Kalck, C.G. Silvia, and J.L. Faria, 'Preparation and Characterization of Nonostructured MWCNT-$TiO_2$ Composite Materials for Photocatalytic Water Treatment Applications,' Materials Research Bulletin, 43 958-67 (2008)   DOI   ScienceOn
18 A. Jitianu, T. Cacciaguerra, R. Benoit, S. Delpeux, F. Beguin, and S. Bonnamy, 'Synthesis and Characterization of Carbon Nanotubes-$TiO_2$ Nanocomposites,' Carbon, 42 1147-51 (2004)   DOI   ScienceOn
19 M.L. Chen, J.S. Bae and W.C. Oh, 'Photocatalytic Effect for the Carbon-coated TiO2 Prepared from Different Heat Treatment Temperature,' Analytical Science & Technology, 19 [6] 460-67 (2006)
20 S.M. Yuen, C.C. Ma, C.Y. Chung, Y.H. Hsiao, C.L. Ching, and A.D. Yu, 'Preparation, Morphology and Electrical Properties of $TiO_2$ Coated Multiwalled Carbon Nanotube/epoxy Composites,' Composites: Part A, 39 119-23 (2008)   DOI   ScienceOn
21 W.C. Oh, and M.L. Chen, 'Electro-chemical Preparation of $TiO_2/$ACF Composites with TNB Electroyte and Their Photocatalytic Effect,' J. Ceramic Processing Research, 9 [2] 100-06 (2008)
22 S.H. Chien, Y. C. Liou, and M.C. Kuo, 'Preparation and Characterization of Nonosized Pt/Au Particles on $TiO_2$-nanotubes,' Synthetic Metals, 152 333-36 (2005)   DOI   ScienceOn
23 W.C. Oh, and Y.R. Na, 'Photocatalytic Oxidation for Organic Dye using Phenol Resin-based Carbon-titania Composites,' J. Kor. Ceram. Soc., 45 [1] 36-42 (2008)   과학기술학회마을   DOI   ScienceOn
24 D. He, L. Yang, S. Kuang, and Q Cai, 'Fabrication and Catalytic of Pt and Ru Decorated $TiO_2$/CNTs Catalyst for Methanol Electrooxidation,' Elctrochemistry Communications, 9 2467-2472 (2007)   DOI   ScienceOn
25 W.C. Oh, J.S. Bae, and M.L. Chen, 'Preparation of Carboncoated $TiO_2$ at Different Heat Treatment Temperatures and their Photoactivity,' Carbon Science, 7 [4] 259-65 (2006)
26 W.C. Oh, and A.R. Jung, 'Properties and Photocatalytic Activity of Pitch-binded ACF/$TiO_2$ Composites,' J. Kor. Ceram. Soc., 45 [3] 150-56 (2008)   과학기술학회마을   DOI   ScienceOn
27 W.C. Oh, and T.S. Park, 'Comparative Analysis of the Physical Properties and Photocatalytic Effects for $C/TiO_2$ Complexes Derived from Titanium n-butoxide,' Environ. Eng. Res., 12 [5] 218-23 (2007)   과학기술학회마을   DOI   ScienceOn
28 W.C. Oh, and M.L. Chen, 'Synthesis and Characterization of CNT/$TiO_2$ Composites Thermally Derived from MWCNT and Titanium (IV) N-butoxide,' Bull. Korean Chem. Soc., 29 [1] 159-64 (2008)   DOI   ScienceOn
29 W.C. Oh, S.B. Han, and J.S. Bae, 'The Analysis for the HCl Modification Effect and Formation of $TiO_2$ on Activated Carbon Fiber Surface,' Analytical Science & Technology, 20 [4] 279-88 (2007)
30 M. Inagaki, Y. Hirose, T. Matsunage, T. Tsumura, and M. Toyoda, 'Carbon Coating of Anatase-type $TiO_2$ Through their Precipitation in PVA Aqueous Solution,' Carbon, 41 2619-24 (2003)   DOI   ScienceOn
31 T. Matsunaga, and M. Inagaki, Proceeding of the 32nd annual meeting in Carbon Society of Japan, pp. 270-71, 2004
32 M.L. Chen, F.J. Zhang, and W.C. Oh, 'Photocatalytic degradation of Methylene Blue by CNT/$TiO_2$ Composites Prepared from MWCNT and Titanium N-butoxide with Benzene,' J. Kor. Ceram. Soc., 45 [11] 651-57 (2008)   과학기술학회마을   DOI   ScienceOn
33 G. Cao, 'Nanostructures & Nanomaterials,' pp. 344-5, Imperial College Press, 2004
34 G. Zhang, L. Wang, K. Shen, D. Zhao, and H. S. Freeman, 'Hydrogenation of o-chloronitrobenzene on a Pd/C Catalyst Doped with Metal Oxide Nanoparticles,' Chemical Engineering J., 141 [1-3] 368-74 (2008)   DOI   ScienceOn
35 Y. Yu, J.C. Yu, C.Y. Chan, Y.K. Che, J.C. Zhao, and L. Ding, 'Enhancement of Adsorption and Photocatalytic Activity of $TiO_2$ by using Carbon Nanotubes for the Treatment of Azo Dye,' Appl. Cat. B: Environ., 61 1-11 (2005)   DOI   ScienceOn