• Title/Summary/Keyword: Carbon-carbon composite

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Electrochemical characterization of activated carbon-sulfur composite electrode in organic electrolyte solution

  • Kim, Dongyoung;Park, Soo-Jin;Jung, Yongju;Kim, Seok
    • Carbon letters
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    • v.14 no.2
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    • pp.126-130
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    • 2013
  • In this study, we present a more electrochemically enhanced electrode using activated carbon (AC)-sulfur (S) composite materials, which have high current density. The morphological and micro-structure properties were investigated by transmission electron microscopy. Quantity of sulfur was measured by thermogravimetric analysis analysis. The electrochemical behaviors were investigated by cyclic voltammetry. As a trapping carbon structure, AC could provide a porous structure for containing sulfur. We were able to confirm that the AC-S composite electrode had superior electrochemical activity.

Electrochemical Characteristics of Silicon-carbon Composite Anodes for Lithium Rechargeable Batteries

  • Lee, Jaeho;Won, Sora;Shim, Joongpyo;Park, Gyungse;Sun, Ho-Jung;Lee, Hong-Ki
    • Transactions on Electrical and Electronic Materials
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    • v.15 no.4
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    • pp.193-197
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    • 2014
  • Si-carbon composites as anode materials for lithium rechargeable batteries were prepared simply by mixing Si nanoparticles with carbon black and/or graphite through a solution process. Si nanoparticles were well dispersed and deposited on the surface of the carbon in a tetrahydrofuran solution. Si-carbon composites showed more than 700 mAh/g of initial capacity under less than 20% loading of Si nanoparticle in the composites. While the electrode with only Si nanoparticles showed fast capacity fading during continuous cycling, Si-carbon composite electrodes showed higher capacities. The cycle performances of Si nanoparticles in composites containing graphite were improved due to the role of the graphite as a matrix.

NUMERICAL SIMULATION OF THE CARBONIZATION PROCESS IN THE MANUFACTURING OF CARBON-CARBON COMPOSITES (탄소-탄소 복합재료의 제조 과정 중 탄화과정의 수치 해석에 관한 연구)

  • Kim, Jungin;Khalid Lafdi;Lee, Woo-Il
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 1999.11a
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    • pp.219-222
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    • 1999
  • A method for numerical simulation of the carbonization process in manufacturing of a carbon-carbon composite is developed. A general theory, which consists of analyses of heat and mass transfer together with stress and displacement predictions, is constructed. A homogeneous, single phase, isotropic material is selected and a computer program is developed for an arbitrary 2-dimensional geometry using FEM. Material properties are obtained through experiments and references, and are modeled effectively to serve the simulation purpose. The validity of the simulation is verified through several comparisons with experimental data, where close agreements are observed. Finally, examples of actual applications are considered to exhibit the capability and utilization of the code in process optimization.

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Characteristics of DMFC Using High Porous Active Carbon as an Uncatalysed Diffusion Layer in Anode Electrode

  • Jung, Doo-Hwan;Shin, Dong-Ryul
    • Carbon letters
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    • v.1 no.1
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    • pp.27-30
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    • 2000
  • Performance of direct methanol fuel cell using high porous active carbon as an uncatalysed diffusion layer in anode (composite electrode) has been evaluated. Effects of porous active carbon in anode were investigated by galvanostatic method and Fourier Transform Infrared spectroscopy. The single cell was operated with 2.5 M methanol at temperature of $80-120^{\circ}C$ and showed performance of $210-510\;mA/cm^2$ at 0.4V. By replacing conventional electrode with composite electrode, the increment of $290\;mA/cm^2$ in current density was obtained at $90^{\circ}C$and 0.4V. The potential decay of the single cell was about 14.5% for 20 days operation.

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Preparation of a Semi-Conductive Thin Film Sensor for Measuring Occlusal Force

  • Yu, Siwon;Kim, Nari;Lee, Youngjin
    • Journal of Sensor Science and Technology
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    • v.24 no.2
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    • pp.88-92
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    • 2015
  • In order to study the semi-conductive characteristics of carbon black-filled ethylene-propylene-diene monomer (EPDM) composite film, which is used for measuring occlusal force, composite samples with volume ratios of carbon black to EPDM ranging from 30% to 70% were prepared. The process of making a composite film consists of two steps, which involve the preparation of a slurry composition and the fabrication of a thin film using solution casting and a lamination process. To prepare the slurry composition, we dispersed carbon black nanoparticles into an organic solvent before mixing with an EPDM solution in toluene. The mechanical and electrical properties of the resulting carbon black-filled EPDM film were then investigated, and the results showed that the electrical resistance of a film decreases with the increase in the carbon black content. Furthermore, improved elastic recovery was observed after cross-linking the EPDM.

Reducing the friction and the wear of carbon fiber composites with micro-grooves (미소채널 구조를 이용한 탄소 섬유 복합재료 면의 마찰 및 마모 감소)

  • Lee H.G.;Lee D.G.
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2005.06a
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    • pp.855-859
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    • 2005
  • Carbon fiber polymeric composites have been widely used in bearing materials under high pressure without oil-lubrication due to their self-lubricating characteristics. However, the severe wear of carbon composite surface occurs due to the generation of wear debris when the pressure applied on the composite surface is higher than the critical value of composite surface. In this work, in order to remove wear debris continuously during sliding operation, composite specimens with many micro-grooves on their sliding surfaces were devised. To investigate the effect of wear debris on the tribological behavior of carbon/epoxy composites, dry sliding tests were performed with respect to applied pressure using the composite specimens with and without micro-grooves. From the measurement of friction coefficients and wear rates, a model for the effect of wear debris on the friction and wear of composites was proposed.

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Cure Monitoring and Nondestructive Evaluation of Carbon Fiber/Epoxy Composites by the Measurements of Electrical Resistance and AE

  • Lee Sang-Il;Yoon Dong-Jin;Park Joung-Man
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2004.10a
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    • pp.264-267
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    • 2004
  • Cure monitoring and nondestructive characteristics of carbon fiber/epoxy composites were evaluated by the measurements of electrical resistance and acoustic emission (AE). Logarithmic electrical resistivity of the untreated single-carbon fiber composite increased suddenly to infinity when the fiber fracture occurred, whereas that of the electrodeposited composite increased relatively broadly up to infinity. As curing temperature increased. logarithmic electrical resistivity of steel fiber increased. On the other hand, electrical resistance of carbon fiber decreased due to the intrinsic electrical properties based on the band theory. The apparent modulus of the electrodeposited composite was higher than that of the untreated composite due to the improved interfacial shear strength (IFSS).

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Interfacial Properties and Curing Behavior of Carbon Fiber/Epoxy Composites using Micromechanical Techniques and Electrical Resistivity Measurement (Micromechanical 시험법과 전기적 고유저항 측정을 이용한 탄소섬유강화복합재료의 계면 물성과 경화거동에 관한 연구)

  • 이상일;박종만
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2000.11a
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    • pp.17-21
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    • 2000
  • Logarithmic electrical resistivity of the untreated or thin diameter carbon fiber composite increased suddenly to the infinity when the fiber fracture occurred by tensile electro-micromechanical test, whereas that of the ED or thick fiber composite increased relatively broadly up to the infinity. Electrical resistance of single-carbon fiber composite increased suddenly due to electrical disconnection by the fiber fracture in tensile electro-micromechanical test, whereas that of SFC increased stepwise due to the occurrence of the partial electrical contact with increasing the buckling or overlapping in compressive test. Electrical resistivity measurement can be very useful technique to evaluate interfacial properties and to monitor curing behavior of single-carbon fiber/epoxy composite under tensile/compressive loading.

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Iron Oxide-Carbon Nanotube Composite for NH3 Detection (산화철-탄소나노튜브 나노복합체의 암모니아 가스센서 응용)

  • Lee, Hyundong;Kim, Dahye;Ko, DaAe;Kim, Dojin;Kim, Hyojin
    • Korean Journal of Materials Research
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    • v.26 no.4
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    • pp.187-193
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    • 2016
  • Fabrication of iron oxide/carbon nanotube composite structures for detection of ammonia gas at room temperature is reported. The iron oxide/carbon nanotube composite structures are fabricated by in situ co-arc-discharge method using a graphite source with varying numbers of iron wires inserted. The composite structures reveal higher response signals at room temperature than at high temperatures. As the number of iron wires inserted increased, the volume of carbon nanotubes and iron nanoparticles produced increased. The oxidation condition of the composite structures varied the carbon nanotube/iron oxide ratio in the structure and, consequently, the resistance of the structures and, finally, the ammonia gas sensing performance. The highest sensor performance was realized with $500^{\circ}C/2h$ oxidation heat-treatment condition, in which most of the carbon nanotubes were removed from the composite and iron oxide played the main role of ammonia sensing. The response signal level was 62% at room temperature. We also found that UV irradiation enhances the sensing response with reduced recovery time.

Two-Layered Microwave Absorber of Ferrite and Carbon Fiber Composite Substrate

  • Han-Shin Cho;Sung-Soo Kim
    • Journal of Magnetics
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    • v.3 no.2
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    • pp.64-67
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    • 1998
  • Microwave absorbing properties of ferrite-epoxy composite (absorbing layer) attached on the carbon fiber polymer composite (reflective substrate) are analyzed on the basis of wave propagation theory. A modified equation for wave-impedance-matching at the front surface of absorbing layer including the effect of electrical properties of the quasi-conducting substrate is proposed. Based on this analysis, the frequency and layer dimension that produce zero-reflection can be estimated from the intrinsic material properties of the obsorbing layer and the substrate. It is demonstrated that the microwave reflectivity of carbon fiber composite has a strong influence on the microwave absorbance of front magnetic layer.

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