• 제목/요약/키워드: Carbon-13

검색결과 2,004건 처리시간 0.033초

Budget and distribution of organic carbon in Taxus cuspidata forest in subalpine zone of Mt. Halla

  • Jang, Rae-Ha;Jeong, Heon-Mo;Lee, Eung-Pill;Cho, Kyu-Tae;You, Young-Han
    • Journal of Ecology and Environment
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    • 제41권1호
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    • pp.19-28
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    • 2017
  • Background: In order to investigate organic carbon distribution, carbon budget, and cycling of the subalpine forest, we studied biomass, organic carbon distribution, litter production, forest floor litter, accumulated soil organic carbon, and soil respiration in Taxus cuspidata forest in Halla National Park from February 2012 to November 2013. Biomass was calculated by using allometric equation and the value was converted to $CO_2$ stocks. Results: The amount of plant organic carbon was $13.60ton\;C\;ha^{-1}year^{-1}$ in 2012 and $14.29ton\;C\;ha^{-1}year^{-1}$ in 2013. And average organic carbon introduced to forest floor through litter production was $0.71ton\;C\;ha^{-1}year^{-1}$. Organic carbon distributed in forest floor litter layer was $0.73ton\;C\;ha^{-1}year^{-1}$ on average and accumulated organic carbon in soil was $51.13ton\;C\;ha^{-1}year^{-1}$ on average. In 2012, Amount of released $CO_2$ from soil to atmosphere was 10.93 ton $CO_2ha^{-1}year^{-1}$. Conclusions: The net ecosystem production based on the difference between net primary production of organic carbon and soil respiration was $-1.74ton\;C\;ha^{-1}year^{-1}$ releasing more carbon than it absorbed.

ALKANE의 微生物酸化의 反應條件과 炭素 및 窒素平衡 (Reaction Conditions and Carbon, Nitrogen Balance in the Course of Microbiological Oxidation of Alkane)

  • 박태원
    • 대한화학회지
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    • 제13권2호
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    • pp.187-193
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    • 1969
  • As part of an extensive program on the microbiological oxidation of hydrocarbons, reaction conditions and nutrients consumption of candida lipolytica grown on alkane as carbon source were studied. For optimum growth of yeast, the conditions of pH 5, temperature $30^{\circ}C$, carbon number $C_{16}$& $C_{18}$aeration 25.6 1/l/hr, agitation 3000 r.p.m., hydrocarbon concentration 10% were obtained. Carbon and nitrogen balance related to these conditions were also investigated. In the course of this investigation, some significant effects of pH and carbon number of hydrocarbon variation were observed.

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Recent Advances in Carbon-Nanotube-Based Epoxy Composites

  • Jin, Fan-Long;Park, Soo-Jin
    • Carbon letters
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    • 제14권1호
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    • pp.1-13
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    • 2013
  • Carbon nanotubes (CNTs) are increasingly attracting scientific and industrial interest because of their outstanding characteristics, such as a high Young's modulus and tensile strength, low density, and excellent electrical and thermal properties. The incorporation of CNTs into polymer matrices greatly improves the electrical, thermal, and mechanical properties of the materials. Surface modification of CNTs can improve their processibility and dispersion within the composites. This paper aims to review the surface modification of CNTs, processing technologies, and mechanical and electrical properties of CNT-based epoxy composites.

$CO^2$ 가스 용접된 강관파일의 피로수명 평가 (Fatigue Life Estimation of $CO^2$ Gas Arc Welded Carbon Steel Tubes)

  • 이억섭;김동준;김승권
    • 한국정밀공학회지
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    • 제15권1호
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    • pp.13-18
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    • 1998
  • In this study. the fatigue lives of two kinds of specimens made by $CO^2$ gas weld were assessed. The materials for two kinds of specimens were taken out of the virgin carbon steel tubes and the used carbon steel tubes respectively. As a result, it was found that the fatigue lives of two groups of specimens were in the same order of magnitude.

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제주도 용천동굴 석순(YC-2)에 기록되어 있는 한반도의 소빙하기 (Little Ice Age recorded in the YC-2 stalagmite of the Yongcheon Cave, Jeju Island (South Korea))

  • 지효선;우경식;양동윤
    • 대기
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    • 제20권3호
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    • pp.261-271
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    • 2010
  • Carbon isotopic compositions of the YC-2 stalagmite in Yongcheon Cave were analyzed to delineate paleoclimatic variations near Korean peninsula for the past historical period. The YC-2 stalagmite is about 68 mm long and annual growth laminae are distinctively identified. Because the number of growth laminae is at least 242, the stalagmite can be estimated to be at least 241 years old. At about 15 mm from the bottom, one thick brown growth lamina is observed, and this lamina was likely to have been formed when the stalagmite ceased to grow, making the hiatus. High resolution, carbon isotope data indicate past fluctuations of East Asia monsoonal intensity (intimately related to the amount of precipitation). Based on the carbon isotope trend, the stalagmite can be divided into three stages (Stages I, II and III). The highest carbon isotopic compositions of Stage I (${\delta}^{13}C$=-3.3~0.4‰, PDB) indicate that the stalagmite grew during the Little Ice Age when cold and dry climate prevailed with less vegetation. Stage II is characterized by a transitional period from cold and dry to warm and wet climate with a increasing trend of carbon isotopic compositions (${\delta}^{13}C$=-9.6~-0.6‰) and this period indicates the weakening of the Little Ice Age climate. This decreasing trend also suggests that Little Ice Age was terminated near middle 1870's around Korean peninsula. Relatively low carbon isotopic compositions during Stage III (${\delta}^{13}C$=-11.0~-8.0‰) indicates that the climate was changed to warm and wet conditions which are similar to the present.

Methanol Oxidation Effect on Carbon Supported Pt Particles Studied by 13C NMR, XRD, and TEM

  • Han, Kee Sung;Han, Oc Hee
    • Bulletin of the Korean Chemical Society
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    • 제27권8호
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    • pp.1121-1126
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    • 2006
  • Methanol oxidation effect on carbon supported Pt was investigated as a function of Pt content in a sample which is closely correlated with Pt particle sizes. After prolonged methanol oxidation the Pt particle size did not change within the experimental error ranges. The $^{13}C$ chemical shift and linewidth of CO adsorbed on Pt show non-linear behavior simply due to the Pt particle size difference. The Pt size variation difference between this work and the previous reports of the particle growths is explained by the experimental temperature difference.

A Study on Spin-Rotational Relaxation of Methyl Carbon-13 in Toluene and 2-Chloro-p-Xylene

  • Hyun Namgoong;Lee, Woong
    • 한국자기공명학회논문지
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    • 제2권1호
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    • pp.66-83
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    • 1998
  • Study on spin-rotation relaxation of nuclear spins located on a methyl group can reveal valuable dynamic information related to the internal rotation of methyl group itself. Toward this end we have measured methyl carbon-13 spin-rotation of methyl group itself. Toward this end we have measured methyl carbon-13 spin-rotational relaxation rate in toluene and 2-chloro-p-xylene over the temperature range of 179-363K. To interpret the temperature dependence of measured spin-rotational relaxation rate we have revised the temperature dependence of measured spin-rotational relaxation rate we have revised the expression derived thus far by other authors and reproduced experimental data on the basis of the newly derived expression. The results confirmed that our expression leads to better agreement with experimental data than the previous one over observed temperature range, especially at high temperature.

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Variations in carbon and nitrogen stable isotopes and in heavy metal contents of mariculture kelp Undaria pinnatifida in Gijang, southeastern Korea

  • Shim, JeongHee;Kim, Jeong Bae;Hwang, Dong-Woon;Choi, Hee-Gu;Lee, Yoon
    • ALGAE
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    • 제32권4호
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    • pp.349-357
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    • 2017
  • Korean mariculture Undaria pinnatifida was collected during the months of January, February, March, and December of 2010, as well as from January of 2011 to investigate the changes in the carbon and nitrogen stable isotope ratios (${\delta}^{13}C$ and ${\delta}^{15}N$) and heavy metal with respect to it growth and to identify the factors that influence such changes. The blades of U. pinnatifida showed ${\delta}^{13}C$ and ${\delta}^{15}N$ in the range (mean) of -13.11 to -19.42‰ (-16.93‰) and 2.99 to 7.57‰ (4.71‰), respectively. Among samples with the same grow-out period, those that weighed more tended to have higher ${\delta}^{13}C$ suggesting a close association between the carbon isotope ratio and growth rate of U. pinnatifida. Indeed, we found a very high positive linear correlation between the monthly average ${\delta}^{13}C$ and the absolute growth rate in weight ($r^2=0.89$). Nitrogen isotope ratio tended to be relatively lower when nitrogen content in the blade was higher, probably due to the strengthening of isotope fractionation stemming from plenty of nitrogen in the surrounding environment. In fact, a negative linear correlation was observed with the nitrate concentration in the nearby seawaters ($r^2=0.83$). Concentrations of Cu, Cd, Pb, Cr, Hg, and Fe in the blades showed a rapid decrease in their concentration per unit weight in the more mature U. pinnatifida. Specifically, compared to adult samples, Cu, Hg, and Pb were concentrated by 30, 55, and 73 folds, respectively, in the young blades. Therefore, U. pinnatifida tissue ${\delta}^{13}C$ is as an indirect indicator of its growth rate, while ${\delta}^{15}N$ values and heavy metal concentrations serve as tracers that reflect the environmental characteristics.

Biological Significance of Essential Fatty Acids/Prostanoids/Lipoxygenase-Derived Monohydroxy Fatty Acids in the Skin

  • Ziboh, Vincent-A.;Cho, Yunhi;Mani, Indu;Xi, Side
    • Archives of Pharmacal Research
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    • 제25권6호
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    • pp.747-758
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    • 2002
  • The skin displays a highly active metabolism of polyunsaturated fatty acids (PUFA). Dietary deficiency of linoleic acid (LA), an 18-carbon (n-6) PUFA, results in characteristic scaly skin disorder and excessive epidermal water loss. Although arachidonic acid (AA), a 20-carbon (n6) PUFA, is metabolized via cyclooxygenase pathway into predominantly prostaglandin $E_2(PGE_2)$ and $PGF_{2{\alpha}}$, the metabolism of AA via the 15-lipoxygenase (15-LOX) pathway, which is very active in skin epidermis and catalyzes the transformation of M into predominantly 15S-hydroxyeicosatetraenoic acid (15S-HETE). Additionally, the 15-LOX also metabolizes the 18-carbon LA into 13S-hydroxyoctadecadienoic acid (13S-HODE), respectively. Interestingly, 15-LOX catalyzes the transformation of $dihomo-{\gamma}-linolenic$ acid (DGLA), derived from dietary gamma-linolenic acid, to 15S-hydroxyeicosatrienoic acid (15S-HETrE). These monohydroxy fatty acids are incorporated into the membrane inositol phospholipids which undergo hydrolytic cleavage to yield substituted-diacylglycerols such as 13S-HODE-DAG from 13S-HODE and 15S-HETrE-DAG from 15S-HETrE. These substituted-monohydroxy fatty acids seemingly exert anti-inflammatory/antiproliferative effects via the modulation of selective protein kinase C as well as on the upstream/down-stream nuclear MAP-kinase/AP-1/apoptotic signaling events.

활성탄 및 제올라이트 13X를 충진한 흡착탑에서 파과곡선을 이용한 흡착등온식 상수의 결정 (Determination of Adsorption Isotherm Parameters by Breakthrough Curves in Activated Carbon and Zeolite 13X Packed Bed)

  • 강성원;민병훈;서성섭
    • 공업화학
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    • 제16권1호
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    • pp.131-138
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    • 2005
  • 활성탄과 제올라이트 13X에 대한 벤젠의 정적흡착실험으로부터 Freundlich isotherm과 Toth isotherm을 구하였으며 똑같은 흡착제로 충진된 흡착탑을 이용하여 벤젠의 파과곡선을 측정하였다. 파과시간과 벤젠 분압의 관계를 해석하여 Freundlich isotherm의 파라미터를 결정하였다. 파과실험 결과의 해석으로부터 예측되는 벤젠의 흡착량이 정적 실험 결과로부터 예측되는 것과 비교적 잘 일치하였다. 활성탄에 대한 동적 실험 결과에서 좀 더 대칭형태에 가까운 파과곡선이 얻어져서 제올라이트 13X에 비해 더 적은 오차가 나타났다.