• 한국대기환경학회지
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• 제30권5호
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• pp.461-476
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• 2014

Continuous Water-Soluble Organic Carbons (WSOC) by the Particle Into Liquid Sampler - Total Organic Carbon (PILS-TOC) analyzer were measured at the Seoul intensive monitoring site from June 17 through July 5 in 2014. In addition, the 24 hour integrated PM2.5 collected by Teflon and Quartz filters were analyzed for water soluble ions by Ion chromatography (IC), WSOC by TOC from water extracts, organic carbon (OC), elemental carbon (EC) by carbon analyzer using the thermal optical transmittance (TOT) method, and mass fragment ions (m/z) related to alkanes and PAHs (Poly Aromatic Hydrocarbons) by Gas Chromatography-Mass Spectrometer-Thermal Desorption (GC/MS-TD). Based on the statistical analysis, four different Carbonaceous Thermal Distributions (CTDs) from OCEC thermal-gram were identified. This study discusses the primary and secondary sources of WSOC based on the Classified CTD, organic mass fragments, and diurnal patterns of WSOC. The results provide knowledge regarding the origins of WSOC and their behaviors.

• 한국세라믹학회지
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• 제27권8호
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• pp.956-956
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• 1990

석탄회의 탄소가 첨가된 질화반응시에 생성된 AIN, SiC 그리고 Si3N4 등의 생성물 분포를 반응온도, 시간 그리고 탄소의 첨가량에 따라 검토하였다. AIN의 조성은 시료입자가 작을수록 증가하였으며 반응온도 14500~1500℃와 약 2시간의 반응시간 그리고 약 30%의 탄소 첨가량 (시료무게 기준) 에서 최대값을 나타내었다. SiC와 Si3N4 조성변화는 서로 상반된 경향을 보였으며 반응온도가 낮고 반응시간이 작으며 그리고 탄소첨가량이 증가할 수록 SiC의 조성은 Si3N4 에 비하여 크게 나타났다.

• 한국세라믹학회지
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• 제26권3호
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• pp.416-422
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• 1989

The particle size of synthesized SiC powders was decreased with increasing carbon content when the mixture of carbon and silica was carbonized at 1, 45$0^{\circ}C$ after hydrolysis of the mixture with the ranges of 3.1 to 3.5 in the mole ratio of Carbon/Alkoxide. The reacted fraction of $\beta$-SiC nearly had nothing to do with the mole ratio of Carbon/Alkoxide. When the reaction was made by adding 0.5wt% additives in the composition of 3.1 in the mole ratio of carbon/alkoxide, the additives decreased the yield of $\beta$-SiC and its sequence was Ba2O3>B>Fe>Al>Al2O3>Si. The effect of additives promoted the transformation of $\beta$-SiC to $\alpha$-SiC form and shwoed the increasing tendency of lattice constant. The two colors of $\beta$-SiC powder came out : one was the black grey with addition of Al, Al2O3 and B the other the light grey with addition of Fe, B2O3 and Si.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2007년도 제38회 하계학술대회
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• pp.1408-1409
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• 2007

In this paper, we developed a hybrid simulation model of carbon laser ablation under the Ar plasmas consisted of fluid and particle methods. Three kinds of carbon particles, which are carbon atom, ion and electron emitted by laser ablation, are considered in the computation. In the present modeling, we adopt capacitively coupled plasma with ring electrode inserted in the space between the substrate and the target, graphite. This system may take an advantage of ${\mu}m$-sized droplets from the sheath electric field near the substrate. As a result, in Ar plasmas, carbon ion motions were suppressed by a strong electric field and were captured in Ar plasmas. Therefore, a low number density of carbon ions were deposited upon substrate. In addition, the plume motions in Ar gas atmosphere was also discussed.

• 비파괴검사학회지
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• 제26권2호
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• pp.69-76
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• 2006

차세대 원자로로 부각되고 있는 고온가스로에서는 윈자로에서는 고온 안정성 및 핵분열생성물 차단 성능이 우수한 TRISO(tri-isotropic) 핵연료를 사용하고 있다. TRISO 핵연료 입자는 직경이 약 1mm인 구 형태로 입자의 중심에는 직경 0.5mm의 핵연료 커널(kernel)이 포함되며 커널 외곽을 코팅 층이 에워싸고 있다. 이 코팅 층은 완충(buffer) PyC(pyrolytic carbon)층, 내부 PyC층, SiC층, 그리고 외부 PyC층으로 구성되어 있다. 각 코팅 층의 두께는 수십-백${\mu}m$ 범위이고 사양으로 정해져 있으며, 본 연구에서는 각 코팅 층의 두께를 비파괴적으로 측정하기 위하여 마이크로포커스 X-선 발생장치와 고해상도 X-선 평판(flat panel) 검출기초 구성된 정밀한 X-선 래디오그래피 장치를 개발하였다. 개발된 마이크로 X-선 래디오그래피 장치를 이용하여 $UO_2$ 핵물질 $ZrO_2$를 커널로 사용한 모의 TRISO 핵연료 입사에 대한 투과 영상을 획득한 후 디지털 영상처리 기술을 이용하여 코팅 층 사이의 경계선이 구분 가능하도록 영상을 개선하고 디지털 영상처리 알고리듬을 개발하여 코팅 층의 두께를 파동으로 측정하였다.

• 한국재료학회:학술대회논문집
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• 한국재료학회 2009년도 추계학술발표대회
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• pp.27.2-27.2
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• 2009

Grinding characteristics for aluminium and carbon nanotubes (CNTs) powder during traditional and planetary ball milling investigated from the viewpoint of particle behaviour with the aimat developing CNT-dispersed samples ground based on powder metallurgy routes.In this work, a comparison between the pure aluminium and CNT input aluminium grinding was carried out to determine grinding time effect on size reduction.We observed that the use of the curly small-diameter multi-walled carbon nanotubes (MWCNTs) attributed to the beneficial role of the MWCNTs as grinding aids. It is suggested that careful choices of the sizes of CNTs and Al powders would allow fine-grinding of composite particles with uniformly distributed CNT reinforcements thereby ensuring improved properties of the final composites produced by low-temperature compacting.

• 한국세라믹학회지
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• 제25권4호
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• pp.415-423
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• 1988

Mixtures of carbon and silica (about 0.46${\mu}{\textrm}{m}$) which was synthesized by the hydrolysis of ethyl silicate, the molar ratio of silica/carbon was fixed as 1/10(weight ratio : 1/2), were nitrided in the temperature range 135$0^{\circ}C$~150$0^{\circ}C$. The phse of the product Si3N4 was $\alpha$ phase and the morphology was hexagnoal prism and the nitridation reaction was completed in 5 hrs at 150$0^{\circ}C$ or 7hrs at 145$0^{\circ}C$. The reaction rate above 150$0^{\circ}C$ was diffusion-controlled, following Jander equation. Activation energy Q was derived from the Arrhenius plot and the value was about 101kcal/mol. Axis ratio of Lattice constants(c/a) was 0.726 and unit volume was $\AA$3, the larger the molar ratio of carbon/Alkoxide was, the smaller the particle size of $\alpha$Si3N4 was.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2005년도 춘계학술대회 논문집
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• pp.1136-1139
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• 2005

As alternative materials for bipolar plate of PEM Fuel Cells, carbon composites were fabricated by compression molding. In this study, four types of nano particles, such as Carbon nanotubes, Carbon black, GX-15 and P-15 were mixed with epoxy resin to provide electric conductivity and structural properties. By increasing pressure during molding and volume ratio of nano particles, the physical contact among particles was improved resulting in increased electric conductivity. Surface resistance test showed, P-15 particles have the highest electric conductivity.

• 한국환경과학회지
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• 제7권4호
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• pp.541-548
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• 1998

Aqueous phase adsorption of phenols by granular activated carbon was studied in a batch adsorption vessel. Adsorption Isotherms of phenol(Ph), p-chlorophenol(PCP) and p-nitrophenol (PNP) from aqueous solution on granular activated carbon have been obtained. The experimental data were analyzed by the surface and pore diffusion models. Both models could be applied to predict the adsorption phenomena. However, the pore diffusion model was slightly better than the surface diffusion model In representing the experimental data for the initial concentration changes. Therefore, the pore diffusion model was used to predict the change of operating variables such as the agitation speed and Particle size of adsorbent which have influence on the film resistance and intraparticle diffusion.

• 공업화학
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• 제16권3호
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• pp.408-412
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• 2005

Magadiite 주형에 pyrolized fuel oil (PFO)를 층간 삽입, 열처리하여 층간에 탄소 박막을 형성하고 magadiite 주형을 제거함으로서 다공성 층상탄소를 합성하였다. 층상카본은 주형과 유사한 판상 구조이며, d-spacing은 ~0.7 nm로서 일정한 값을 보여주었다. 비표면적은 주형의 형태, 혼합비율, 소성시간에 따라 $147{\sim}385m^2/g$ 크게 다른 값을 나타내었다.