• 한국연소학회:학술대회논문집
• /
• 한국연소학회 2004년도 제29회 KOSCI SYMPOSIUM 논문집
• /
• pp.117-123
• /
• 2004

The burning characteristics of interacting coal particles in a convective flow are numerically investigated at various Reynolds numbers. The transient combustion of 2-dimensionally arranged particles, both the fixed particle distances of 5 radii to 20 radii horizontally and 3 radii to 24 radii vertically, is studied. The results obtained from the present numerical analysis reveal that the transient flame configuration and retardation of particle temperature augmentation with the horizontal or vertical particle spacing substantially influence devolatilization process and carbon conversion ratio of interacting particles. Volatile release and carbon conversion ratio of the second particle with decreasing horizontal and vertical particle spacing decrease gradually, whereas those of the first particle with decreasing vertical particle spacing increases due to flow acceleration. When the vertical particle spacing is smaller than $6R_{o}$, volatile release and carbon conversion ratio of the second particle decrease greatly due to reduction of flame penetration depth.

• 한국입자에어로졸학회지
• /
• 제5권2호
• /
• pp.45-52
• /
• 2009

Black carbon, which is a by-product of combustion of fossil fuel and biomass burning, is the component that imposes the largest uncertainty on quantifying aerosol climate effect. The direct, indirect and semi-direct climate effects of black carbon depend on its state of the mixing with other water-soluble aerosol components. The process that transforms hydrophobic externally mixed black carbon particles into hygroscopic internally mixed ones is called "aging". In most climate models, simple parameterizations for the aging time scale are used instead of solving detailed dynamics equations on the aging process due to the computation cost. In this study, a new parameterization for the black carbon aging time scale due to condensation and coagulation is presented as a function of the concentration of hygroscopic atmospheric components and the black carbon particle size. It is shown that the black carbon aging time scale due to condensation of sulfuric acid vapors varies to a large extent depending on the sulfuric acid concentration and the black carbon particle size. This result indicates that the constant aging time scale values suggested in the literature cannot be directly applied to a global scale modeling. The aging time scale due to coagulation with internally mixed aerosol particles shows an even stronger dependency on particle size, which implies that the use of a particle-size-independent aging time scale may lead to a large error when the aging is dominated by coagulation.

• 분석과학
• /
• 제32권3호
• /
• pp.77-87
• /
• 2019

High viscosity carbon black dispersions are used in various industrial fields such as color cosmetics, rubber, tire, plastic and color filter ink. However, carbon black particles are unstable to heat due to inherent characteristics, and it is very difficult to keep the quality of the product constant due to agglomeration of particles. In general, particle size analysis is performed by dynamic light scattering (DLS) during the dispersion process in order to select the optimum dispersant in the carbon black dispersion process. However, the existing low viscosity analysis provides reproducible particle distribution analysis results, but it is difficult to select the optimum dispersant because it is difficult to analyze the reproducible particle distribution at high viscosity. In this study, dynamic light scattering (DLS) and asymmetrical flow field-flow fractionation (AsFlFFF) analysis methods were compared for reproducible particle size analysis of high viscosity carbon black. First, the stability of carbon black dispersion was investigated by particle size analysis by DLS and AsFlFFF according to milling time, and the validity of analytical method for the selection of the optimum dispersant useful for carbon black dispersion was confirmed. The correlation between color and particle size of particles in high viscosity carbon black dispersion was investigated by using colorimeter. The particle size distribution from AsFlFFF was consistent with the colorimetric results. As a result, the correlation between AsFlFFF and colorimetric results confirmed the possibility of a strong analytical method for determining the appropriate dispersant and milling time in high viscosity carbon black dispersions. In addition, for nanoparticles with relatively broad particle size distributions such as carbon black, AsFlFFF has been found to provide a more accurate particle size distribution than DLS. This is because AsFlFFF, unlike DLS, can analyze each fraction by separating particles by size.

• 한국환경과학회지
• /
• 제32권3호
• /
• pp.181-189
• /
• 2023

In this study, sediment cores from unvegetated tidal flats in the Hampyeong Bay (west coastal wetland) and Dongdae Bay (south coastal wetland) were sampled, the blue carbon stock in the sediments was calculated, and the characteristics of the blue carbon stock were analyzed based on particle size of the sediments. The sediments in the Hampyeong Bay tidal flat had large particle size and low mud content, and the Dongdae bay tidal flat had small particle size and high mud content. The organic carbon content and blue carbon stock in the sediments were higher in the Dongdae tidal flat than in the Hampyeong Bay tidal flat. As a result of the regression function, in both the Hampyeong Bay and Dongdae Bay tidal flats, the sediments had the smaller particle size and higher mud contents the higher the organic carbon content and blue carbon stock. The sediments with smaller particle size had the larger specific surface area, so were feasible to adsorb and store more organic matters.

• 대한기계학회논문집B
• /
• 제29권12호
• /
• pp.1321-1328
• /
• 2005

The burning characteristics of interacting coal particles in a convective flow are numerically investigated at various Reynolds numbers. The transient combustion of 2-dimensionally arranged particles, both the fixed particle distances of 5 radii to 20 radii horizontally and 4 radii to 24 radii vertically, is studied. The results obtained from the present numerical analysis indicate that the transient flame configuration and retardation of particle temperature augmentation with the horizontal or vertical particle spacing substantially influence devolatilization process and carbon conversion ratio of interacting particles. Volatile release and carbon conversion ratio of the second particle with decreasing horizontal and vertical particle spacing decrease gradually, whereas those of the first particle with decreasing vertical particle spacing increase due to flow acceleration. When the vertical particle spacing is smaller than $6R_0$, volatile release and carbon conversion ratio of the second particle decrease due to reduction of flame penetration depth and interference of oxygen diffusion by the first particle.

• 한국재료학회지
• /
• 제18권12호
• /
• pp.683-688
• /
• 2008

For development of a human body model for electric shock, electroconductive paints with carbon black as a filler material were developed. The characteristics of the volume resistivities of thin films fabricated using the electroconductive paints were investigated as a function of the particle sizes and content of carbon black. With a carbon black particle size over $80\;{\mu}m$, agglomeration of carbon black powders was observed. The volume resistivity of the particles increased as the porosity increased and as the amount of carbon black decreased due to the agglomeration of carbon black powders. With a particle size of $4\;{\mu}m$ and $20\;{\mu}m$, agglomeration of carbon black powders was not observed and their porosities were measured as 0.86% and 1.12% with volume resistivities of $20\;{\Omega}{\cdot}cm$ and $80\;{\Omega}{\cdot}cm$ respectively. A carbon black particle size of less than $20\;{\mu}m$ is considered to be suitable as a type of electric-shock electroconductive paint for a human body model.

• 한국입자에어로졸학회지
• /
• 제14권3호
• /
• pp.81-88
• /
• 2018

The market for improving the indoor air quality is continuously increasing, and air cleaners are the representative products. As interest in indoor air quality increases, so are the ultrafine particle which are harmful to the human body. Despite its many advantages, electrostatic precipitators are less used in indoor air due to ozone production. In this study, the carbon fiber sheet was applied to the discharge electrode and compared with the conventional tungsten wire discharge electrode. The particle collection efficiency and the amount of ozone generation were measured for 10-100 nm particles. Furthermore, it was applied to commercial air purifier with electrostatic precipitator to compare particle removal performance. The carbon fiber sheet type discharge electrode generates a small amount of ozone, and thus it can be applied to improve indoor air quality.

• 한국진공학회:학술대회논문집
• /
• 한국진공학회 2011년도 제40회 동계학술대회 초록집
• /
• pp.194-194
• /
• 2011

The effects of argon neutral beam (NB) energy on the amorphous carbon (a-C) films were investigated, while the a-C films were deposited by neutral particle beam assisted sputtering (NBAS) system. The energy of neutral particle beam can be controlled by reflector bias voltage directly as a unique operating parameter in this system. The deposition characteristics of the films investigated of Raman spectra, UV-visible spectroscopy, electrical conductivity, stress measurement system, and ellipsometer indicate the properties of amorphous carbon films can be manipulated by only NB energy (or reflector bias voltage) without changing any other process parameters. We report the effect of reflector bias voltage in the range from 0 to -1KV. By the increase of the reflector bias voltage, the amount of cross-linked sp2 clusters as well as the sp3 bonding in the a-C film coated by the NBAS system can be increased effectively and the composition of carbon thin films can be changed from nano-crystalline graphite phase to amorphous carbon phase.

• 한국수소및신에너지학회논문집
• /
• 제21권4호
• /
• pp.313-320
• /
• 2010

Carbon cloth was impregnated into PTFE emulsion. PTFE is a fluoropolymer used as a coating material in various fields due to its hydrophobicity and excellent mechanical properties. In this study, PTFE emulsion was prepared different particle size of 5~500 nm and $3{\sim}5{\mu}m$. FE-SEM and FT-IR spectroscopy were used microscopic observation and investigation of chemical structure change after PTFE coating. Mass variations, gas permeability and water contact angles were analyzed to determine a GDL performance of PTFE coated carbon cloth. PTFE coated carbon cloth show different mass increase according as PTFE concentration and the number of coating times. Water contact angle of PTFE coated carbon cloth was not effected by size of PTFE particle and the number of coating time; meanwhile, gas permeability was rapidly changed at carbon cloth coated by emulsion with size of $3{\sim}5{\mu}m$ PTFE particle.

• Carbon letters
• /
• 제16권3호
• /
• pp.215-218
• /
• 2015

Carbon micro particles with dimple patterns were produced by electro-spraying a solution of pitch in tetrahydrofuran. Particle formation depended on separation in an electrical field and volatilization of the solvent. More than 80% of the obtained carbon exhibited an average particle size of less than 50 μm. X-ray diffraction analysis suggests that the carbon with dimple patterns has increased crystallinity after heat treatment.