• Proceedings of the Korean Vacuum Society Conference
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• 2012.08a
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• pp.419-420
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• 2012

Lithium-ion battery (LIB) usually used for valuable electronic devices are extended to applications. High stability negative electrode materials for LIB were investigated using electrodeposition of nanoparticles (NPs) on the nanostructured carbon. NPs with about 70 nm diameters were evenly prepared on the graphitic carbon materials using electrodeposition process at room temperature. It was observed that the NPs were homogeneously embedded into not only external surface but bottom part of the graphitic carbon network. The graphitic carbon material covered with NPs enables facile electron transport owing to the network structure and improves structural collapse during cycling. This facile room temperature process is expected to be applicable to other anode materials such as Sn and Al for the anode of LIB.

• Carbon letters
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• v.13 no.2
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• pp.126-129
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• 2012

Nanocomposite films were made by a simple solution casting method in which multi-walled carbon nanotubes (MWCNT) and magnetite nanoparticles ($Fe_3O_4$) were used as dopant materials to enhance the electrical conductivity of chitosan nanocomposite films. The films contained fixed CNT concentrations (5, 8, and 10 wt%) and varying $Fe_3O_4$ content. It was determined that a 1:1 ratio of CNT to $Fe_3O_4$ provided optimal conductivity according to dopant material loading. X-ray diffraction patterns for the nanocomposite films, were determined to investigate their chemical and phase composition, revealed that nanoparticle agglomeration occurred at high $Fe_3O_4$ loadings, which hindered the synergistic effect of the doping materials on the conductivity of the films.

• Bulletin of the Korean Chemical Society
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• v.31 no.11
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• pp.3077-3083
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• 2010

The electrochemical detection of As(III) was investigated on a platinum-iron(III) nanoparticles modified multiwalled carbon nanotube on glassy carbon electrode(nanoPt-Fe(III)/MWCNT/GCE) in 0.1 M $H_2SO_4$. The nanoPt-Fe(III)/MWCNT/GCE was prepared via continuous potential cycling in the range from -0.8 to 0.7 V (vs. Ag/AgCl), in 0.1 M KCl solution containing 0.9 mM $K_2PtCl_6$ and 0.6 mM $FeCl_3$. The Pt nanoparticles and iron oxide were co-electrodeposited into the MWCNT-Nafion composite film on GCE. The resulting electrode was examined by cyclic voltammetry (CV), scanning electron microscopy (SEM), and anodic stripping voltammetry (ASV). For the detection of As(III), the nanoPt-Fe(III)/MWCNT/GCE showed low detection limit of 10 nM (0.75 ppb) and high sensitivity of $4.76\;{\mu}A{\mu}M^{-1}$, while the World Health Organization's guideline value of arsenic for drinking water is 10 ppb. It is worth to note that the electrode presents no interference from copper ion, which is the most serious interfering species in arsenic detection.

• Journal of Power System Engineering
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• v.18 no.2
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• pp.43-49
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• 2014

This study has been investigated on the durability of carbon fiber/epoxy composites (CFRP) in moisture environment. The carbon fiber/epoxy composites were modified to use the nanoparticles such as carbon nanotubes and titanium oxide. These hybrid composites were exposed to moisture environment for a certain period of time. Weight gain according to immersion time, quasi-static tensile test and micro-graphic characterization were investigated on the samples exposed to moisture environment. Consequently, the weight gains increased with increasing immersion time and weight gain of the hybrid composites was lower than the one of CFRP through the whole immersion time. The tensile strengths decreased with increasing immersion time and tensile strengths of the hybrid composites were higher than the one of CFRP through the whole immersion time. The CFRP were observed more degraded than hybrid compositess in moisture environment. Therefore, it was concluded that the addition of nanoparticles in CFRP could lead to improve the durability in moisture environment.

• Journal of Environmental Health Sciences
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• v.36 no.5
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• pp.343-350
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• 2010

This study was performed to investigate laboratory workers' exposures to airborne nanoparticles at a university laboratory where acid treatment experiments were conducted on the surfaces of engineered carbon nanotubes (CNTs). The surface area concentrations, number concentrations, and mass concentrations of airborne nanoparticles were measured at personal breathing zones (PBZs) for various tasks using direct reading instruments. For all three metrics, airborne nanoparticle concentrations during the experiments were higher than background levels measured before and after the experiments for all three metrics. Among the various tasks that were performed as part of these experiments, one task that involved filtering a mixture of acid and CNTs showed the highest concentrations in all three metrics, with concentrations of $116.6\;{\mu}m^2$/cc, 24320 pt/cc, and $9.0\;{\mu}g/m^3$, respectively. Nanoparticle surface area concentrations measured at a representative area fluctuated with those at the PBZs in the laboratory. This result indicates that nanoparticles generated during the experiments were not just limited to the PBZs of the workers but were also present throughout the room, potentially exposing co-located workers. CNTs were detected by a transmission electron microscope in an air sample collected while handling the CNTs. All the tasks were performed inside fume hoods, with the sliding sashes open to their required heights. It was noted that the capture velocities of the fume hoods were much lower than the American National Standards Institute (ANSI)'s recommendation level (0.4 to 0.6 m/s). In conclusion, this study showed that, due to inadequate control, laboratory researchers performing acid treatment experiments on surfaces of CNTs were exposed to airborne nanoparticles generated during the tasks.

• Bulletin of the Korean Chemical Society
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• v.33 no.2
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• pp.625-628
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• 2012

We investigated the interaction between polyynes (linear carbon chains) and various metal nanoparticles (Ag, Au, and Cu) to provide insight into the optical properties of metal-polyynes systems prepared by different experimental techniques. Polyynes were produced by laser ablation in deionized water, metal nanoparticles solutions, and copper chloride solution. Metal nanoparticles complexes with polyynes were analyzed by Raman, surface-enhanced Raman scattering, and UV-vis spectroscopy.

• Bulletin of the Korean Chemical Society
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• v.31 no.12
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• pp.3852-3855
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• 2010

• Journal of Ocean Engineering and Technology
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• v.28 no.1
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• pp.64-68
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• 2014

This study was conducted to investigate the durability of carbon fiber/epoxy composites (CFRP) in a saline water environment. The carbon fiber/epoxy composites were modified to use nanoparticles such as carbon nanotubes and titanum oxide. These hybrid composites were exposed to a saline water environment for a certain period. The weight gain according to the immersion time, a quasi-static tensile test, and micro-graphic characterization were used to investigate the samples exposed to the saline water environment. The weight gains increased with increasing immersion time. The weight gains of the hybrid composites were lower than that for pure CFRP throughout the entire immersion time. The tensile strengths decreased with increasing immersion time. The tensile strengths of the hybrid composites were higher than that of the pure CFRP throughout the entire immersion time. The pure CFRP was observed to be more degraded than the hybrid composites in the saline water environment. Therefore, it was concluded that the addition of nanoparticles to CFRP could lead to improved durability in a saline water environment.

• 한국신재생에너지학회:학술대회논문집
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• 2009.06a
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• pp.652-655
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• 2009

The bimodal porous carbons were synthesized by using imprinting method with templates of SBA-15 particle and silica sphere and applied as supporting materials for the electro-catalyst of polymer electrolyte fuel cell (PEFC). The silica spheres with diameter size of 100 nm and SBA-15 particle having 200 nm -250 nm diameter and 700 nm -900 nm length were synthesized in this work. The bimodal porous carbons (S100) were prepared by using the silica spheres and SBA-15 as templates and mesophase pitch as a carbon source. The PtRu nanoparticle of ca. 1.9 nm were supported on the bimodal porous carbon support and the resulting PtRu/S100 catalysts was tested by the cyclic voltammetry. The use of bimodal porous carbon showed in comparable electro-catalytic activities with commercial catalyst. Though unclear effects of bimodal porosity of supports could be obtained in the scope of this study, morphological advantage in electrical conductivity can be considered on the electro-catalytic activity.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.23 no.4
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• pp.323-332
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• 2013

Objectives: This study was conducted in order to investigate the diesel exhaust particle(DEP) concentrations in the thirteen parking lots of large shopping complex. Methods: The real-time black carbon(BC) concentration was determined using an Aethalometer, and elemental/organic carbon concentration was determined according to the method of the National Institute for Occupational Safety and Health(NIOSH) 5040. The particle number concentration(NC), lung deposited surface area concentration(LDSA) and geometric mean diameter(GMD) were determined using a DiSCmini aerosol monitor. Results: The average concentration of BC, EC, OC, NC, LDSA and GMD were $19.1{\mu}g/m^3$, $12.6{\mu}g/m^3$, $51.5{\mu}g/m^3$, $94,000particles/cm^{-3}$, $298{\mu}m^2/cm^{-3}$ and 57 nm in all parking lots, respectively, approximately 3-fold higher than those found in the urban outdoor. The average concentration of BC were $21.3{\mu}g/m^3$ in underground parking lots, 3-fold higher than above parking lots. Conclusions: Therefore, the parking lots at the large shopping complex can be considered a potentially dangerous environment with a high concentration of DEP nanoparticles.