• Title/Summary/Keyword: Carbon mass balance

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Evaluation of Carbon Dioxide Concentrations and Ventilation Rates in Elementary, Middle, and High Schools (초·중·고등학교의 이산화탄소 농도 및 환기량 평가)

  • Choe, Youngtae;Heo, Jung;Park, Jinhyeon;Kim, Eunchae;Ryu, Hyoensu;Kim, Dong Jun;Cho, Mansu;Lee, Chaekwan;Lee, Jongdae;Yang, Wonho
    • Journal of Environmental Health Sciences
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    • v.46 no.3
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    • pp.344-352
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    • 2020
  • Objectives: Much attention has been paid to indoor air quality. Ventilation within schools is important because of indoor air quality and its effect on health and learning performance. In this study, we evaluated the carbon dioxide (CO2) concentrations and ventilation rates in schools. Methods: This study measured the concentration of CO2 in elementary, middle, and high school classrooms over six months. The seasons during the study were summer, fall, and winter. Sensor-based monitoring was used and the basic characteristics of the classroom were investigated. The body surface area of the students was used to calculate the CO2 generation rate, and the air change per hour (ACH) was evaluated using mass balance modeling. Results: The average CO2 concentration measured in most schools exceeded 1000 ppm. The ventilation rates varied from season to season. Compared to the recommended ventilation rate of 4.9 ACH, the roughly 3 ACH calculated in this study indicates that most schools possessed insufficient ventilation. Conclusions: The concentration of CO2 in school classrooms could be an indicator of indoor air quality and can affect students' learning ability. In this study, CO2 concentrations exceeding the standard indicate a lack of ventilation along with problems with indoor air quality. Therefore, appropriate improvements are needed to overcome these problems.

The Distribution of DOM and POM and the Composition of Stable Carbon Isotopes in Streams of Agricultural and Forest Watershed Located in the Han River System (한강수계 농경지역 하천과 삼림지역 하천에서 DOM과 POM의 분포 및 안정탄소동위원소 조성비)

  • Kim, Jai-Ku;Kim, Bom-Chul;Jung, Sung-Min;Jang, Chang-Won;Shin, Myoung-Sun;Lee, Yun-Kyoung
    • Korean Journal of Ecology and Environment
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    • v.40 no.1
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    • pp.93-102
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    • 2007
  • The runoff characteristics of organic matter in turbid water were investigated in eleven tributary streams of the Han River system, Korea. The flow-weighted event mean concentrations of organic matter ranged from 1.5 to 3.2 mg $L^{-1}$ of DOM and 2.2 of 29.1 mg $L^{-1}$ of POM, respectively. The SUVA value which reflects the proportion of humic substance in organic matters was higher during the rainfall season, meaning that the runoff of refractory form increase in this period. Stable carbon isotope ratios of both POM and DOM were different among streams, which reflect the sources of organic matter. DOM isotope ratios were less depleted of $^{13}C$ than that of POM by approximately 1 to $2%_{\circ}$ ${\delta}^{13}C$ of the several turbid streams (the Mandae Stream, the Jawoon Stream, and the Daegi stream) were heavier than those of clear streams. ${\delta}^{13}C$ values in the turbid upstream tributaries were similar to those of downstream reaches (such as the Soyang River, the Sum River, and the Seo River). From the ${\delta}^{13}C$ analysis of POM it could be calculated that $C_4$ pathway contributed approximately 15.9 to 23.6% of organic matter in several turbid upstream sites, and over 20% in the three sites of large downstream reaches. On the contrary it contributed only 9.1 to 12.8% in clear streams of forest watersheds. In the Soyang River, $C_4$ pathway organic matter contributed 8.8% of the DOM pool.

The Environmental Impacts of Seasonal Variation on Characteristics of Geochemical Parameters in Lake Shihwa, Korea (시화호의 계절변화에 따른 지화학적 환경요인 특성 연구)

  • Kim Tae-Ha;Park Yong-Chul;Lee Hyo-Jin;Kim Dong-Hwa;Park Jun-Kun;Kim Sung-Jun;Lee Mi-Yeon
    • Journal of Environmental Science International
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    • v.13 no.12
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    • pp.1089-1102
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    • 2004
  • Seasonal variation of biogeochemical characteristics was determined in Lake Shihwa from October 2002 to August 2003. When the lake was artificially constructed for the freshwater reservoir in 1988, the development of the strong haline density stratification resulted in two-layered system in water column and hypoxic/anoxic environment prevailed in the bottom layer due to oxidation of accumulated organic matters in the lake. Recently, seawater flux to the lake through the sluice has been increased to improve water quality in the lake since 2000, but seasonal stratification and hypoxic bottom layer of the lake still developed in the summer due to the nature of artificially enclosed lake system. As the lake is still receiving tremendous amount of organic matters and other pollutants from neighboring streams during the rainy summer season, limited seawater flux sluicing into the lake may not be enough for the physical and biogeochemical mass balance especially in the summer. The excess of accumulated organic matters in the bottom layer apparently exhausted dissolved oxygen and affected biogeochemical distributions and processes of organic and inorganic compounds in the stratified two-layered environment in the summer. During the summer, ammonia and dissolved organic carbon remarkably increased in the bottom layer due to the hypoxic/anoxic condition in the bottom layer. Phosphate also increased as the result of benthic flux from the bottom sediment. Meanwhile, dissolved organic carbon showed the highest value at the upstream area and decreased along the salinity gradient in the lake. In addition to the sources from the upstream, autochthonous origin of particulate organic carbon from algal bloom in the lake might be more important for sustaining aggravated water quality and development of deteriorated bottom environment in the summer. The removal of trace metals could be attributed to scavenging by strong insoluble metal-sulfide compounds in the hypoxic/anoxic bottom layer in the summer.

Research on Development of Turbo-generator with Partial Admission Nozzle for Supercritical CO2 Power Generation (부분 유입 노즐을 적용한 초임계 이산화탄소 발전용 초고속 터보발전기 개발 연구)

  • Cho, Junhyun;Shin, Hyung-ki;Kang, Young-Seok;Kim, Byunghui;Lee, Gilbong;Baik, Young-Jin
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.41 no.4
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    • pp.293-301
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    • 2017
  • A Sub-kWe small-scale experimental test loop was manufactured to investigate characteristics of the supercritical carbon dioxide power cycle. A high-speed turbo-generator was also designed and manufactured. The designed rotational speed of this turbo-generator was 200,000 rpm. Because of the low expansion ratio through the turbine and low mass flowrate, the rotational speed of the turbo-generator was high. Therefore, it was difficult to select the rotating parts and design the turbine wheel, axial force balance and rotor dynamics in the lab-scale experimental test loop. Using only one channel of the nozzle, the partial admission method was adapted to reduce the rotational speed of the rotor. This was the world's first approach to the supercritical carbon dioxide turbo-generator. A cold-run test using nitrogen gas under an atmospheric condition was conducted to observe the effect of the partial admission nozzle on the rotor dynamics. The vibration level of the rotor was obtained using a gap sensor, and the results showed that the effect of the partial admission nozzle on the rotor dynamics was allowable.

Characteristics of Coal Slurry Gasification under Partial Slagging Operating Condition (부분 용융 운전 조건에서 석탄슬러리 가스화 운전 특성)

  • Lee, Jin Wook;Chung, Seok Woo;Lee, Seung Jong;Jung, Woohyun;Byun, Yong Soo;Hwang, Sang Yeon;Jeon, Dong Hwan;Ryu, Sang Oh;Lee, Ji Eun;Jeong, Ki Jin;Kim, Jin Ho;Yun, Yongseung
    • Korean Chemical Engineering Research
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    • v.52 no.5
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    • pp.657-666
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    • 2014
  • Coal gasification technology is considered as next generation clean coal technology even though it uses coal as fuel which releases huge amount of greenhouse gas because it has many advantages for carbon capture. Coal or pet-coke slurry gasification is very attractive technology at present and in the future because of its low construction cost and flexibility of slurry feeding system in spite of lower efficiency compared to dry feeding technology. In this study, we carried out gasification experiment using bituminous coal slurry sample by integrating coal slurry feeding facility and slurry burner into existing dry feeding compact gasifier. Especially, our experiment was conducted under fairly lower operation temperature than that of existing entrained-bed gasifier, resulting in partial slagging operation mode in which only part of ash was converted to slag and the rest of ash was released as fly ash. Carbon conversion rate was calculated from data analysis of collected slag and ash, and then cold gas efficiency, which is the most important indicator of gasifier performance, was estimated by carbon mass balance method. Fairly high performance considering pilot-scale experiment, 98.5% of carbon conversion and 60.4% of cold gas efficiency, was achieved. In addition, soundness of experimental result was verified from the comparison with chemical equilibrium composition and energy balance calculations.

Significance of Aspect and Understory Type to Leaf Litter Redistribution in a Temperate Hardwood Forest

  • Lee, Do-Won;Yoo, Ga-Young;Oh, Sung-Jin;Shim, Jee H.;Kang, Sin-Kyu
    • Animal cells and systems
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    • v.3 no.2
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    • pp.143-147
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    • 1999
  • Annual production and redistribution of leaf litter were compared among three distinct understory patches in a temperate hardwood forest dominated by Quercus mongolica, Kalopanax pictus, Acer pseudo-sieboldianum, and Carpinus cordata. Two patches were located on a southwest-facing slope: one with an understory dominated by herbaceous plants (Patch S), and the other covered with evergreen dwarf bamboo, Sasa borealis (patch SS). The third patch was on the opposite slope with an understory dominated by herbaceous plants (Patch N). Annual leaf litterfall was averaged 330 g m$^{-2} yr$^{-2}$ in the three patches from 1994 to 1998. From mid-September 1996 to mid-September 1997, net transport of leaf litter over patch bound-aries was 1,824g m$^{-1}$ from Patch S to SS, 1,465g m$^{-1}$ from Patch S to N, and 886 g m$^{-1}$ from Patch SS to N. The amounts moving downslope out of Patch S, SS, and N were 2,548, 471, and 588g m$^{-1}$, respectively. When a mass balance approach was employed for the data of leaf litter transport, the results were relatively consistent with 216, 631, and 724g m$^{-2}$ of leaf litter stores in Patch S, SS, and N, respectively, in April 1997. This study suggests that leaf litter redistribution is largely regulated by aspect and understory type and exerts a significant effect on carbon processes in the forest ecosystem.

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Dynamic Modeling of Gasification Reactions in Entrained Coal Gasifier (석탄 가스화 반응의 동적 거동 전산 모사)

  • Chi, Jun-Hwa;Oh, Min;Kim, Si-Moon;Kim, Mi-Young;Lee, Joong-Won;Kim, Ui-Sik
    • Transactions of the Korean hydrogen and new energy society
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    • v.22 no.3
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    • pp.386-401
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    • 2011
  • Mathematical models for various steps in coal gasification reactions were developed and applied to investigate the effects of operation parameters on dynamic behavior of gasification process. Chemical reactions considered in these models were pyrolysis, volatile combustion, water shift reaction, steam-methane reformation, and char gasification. Kinetics of heterogeneous reactions between char and gaseous agents was based on Random pore model. Momentum balance and Stokes' law were used to estimate the residence time of solid particles (char) in an up-flow reactor. The effects of operation parameters on syngas composition, reaction temperature, carbon conversion were verified. Parameters considered here for this purpose were $O_2$-to-coal mass ratio, pressure of reactor, composition of coal, diameter of char particle. On the basis of these parametric studies some quantitative parameter-response relationships were established from both dynamic and steady-state point of view. Without depending on steady state approximation, the present model can describe both transient and long-time limit behavior of the gasification system and accordingly serve as a proto-type dynamic simulator of coal gasification process. Incorporation of heat transfer through heterogenous boundaries, slag formation and steam generation is under progress and additional refinement of mathematical models to reflect the actual design of commercial gasifiers will be made in the near futureK.

Numerical Analysis of Integrated Fuel Processing System Considering Thermo-Chemical Energy Balance (열/화학적 에너지 평형을 고려한 통합 연료 개질 시스템의 수치적 연구)

  • Noh, Junghun;Jung, Hye-Mi;Jung, Un-Ho;Yoon, Wang-Lai;Um, Sukkee
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.111.1-111.1
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    • 2010
  • This paper focuses on a systematic configuration of steam reforming fuel processor, particularly designed for small and medium sized hydrogen production application. In a typical integration of the fuel processor, there exist significant temperature gradients over the entire system which has negative effect on both catalyst life-time and system performance. Also, the volumetric inefficiency should be avoided to obtain the possible compactness for the commercial purpose. In the present work, the computational analysis will be performed to gain the fundamental insight on the transport phenomena and chemical reactions in the reformer consisting of preheating, steam reforming (SR), and water gas shift (WGS) reaction beds in the flow direction. Also, the fuel processing system includes a top-fired burner providing necessary thermal energy for endothermic catalytic reactor. A fully two-dimensional numerical modeling for a integrated fuel processing system is introduced for in-depth analysis of the heat and mass transport phenomena based on surface kinetics and catalytic process. In the model, water gas shift reaction and decomposition reaction were assumed to be at equilibrium. A kinetic model was developed and then computational results were compared with the experimental data available in the literature. Finally, the case study was done by considering the key parameters, i.e. steam to carbon (S/C) ratio and temperature. The computer-aided models developed in this study can be greatly utilized for the design of advanced fast-paced compact fuel processors research.

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A Study on Simulator for Environment Control of Agricultural Production Facility - Construction of Basic System with Numerical Model - (농업생산시설의 환경조절용 시뮬레이터에 관한 연구 - 수치모델에 의한 기본시스템 구축 -)

  • 손정익;최규홍
    • Journal of Bio-Environment Control
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    • v.5 no.2
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    • pp.111-119
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    • 1996
  • The purpose of this study is to construct the main system of simulator for the environment control of agricultural production facilities. The model describing the system was based on the energy and mass balance in an unsteady - state situation. The model consist of the three major parts : the main model, the light model, and the environmental control model, and each part was separated to be developed individually. The main model which is the core of this system includes the thermal model, the soil model, the ventilation model, the cultivation model, and the carbon dioxide model. And also the environmental control model includes the thermal curtain model, the heater/cooler model and the underground heat exchanger model. The equations used in this model were written in analog programming methods using PCSMP The simulator was evaluated through comparison between simulated and measured temperatures controlled during daytime and night. The results showed good agreements between the predicted and measured temperatures.

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Fresh Produce Container Operated with a Routine of Hypobaric Application, CO2 Injection and Diffusion Tube Opening for Keeping Beneficial Modified Atmosphere

  • Park, Su Yeon;An, Duck Soon;Lee, Dong Sun
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.26 no.2
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    • pp.53-60
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    • 2020
  • A concept of household container to create and keep the modified atmosphere (MA) beneficial for fresh produce mix was devised and tested under typical chilled storage conditions of 3℃. The container system containing mixed products is initialized by applying weak hypobaric condition (0.9 atm) and subsequently injecting CO2 gas at an appropriate low level (0.03 atm). The passive atmosphere modification by produce respiration is then induced to reach a target until gas diffusion tube of proper dimension starts to open. The design was made to attain quasi-steady state mass balance of O2, CO2 and N2 to maintain the desired MA through the storage. Interrupted opening for taking out or placing some products was to reinitialize the loop of control logic. The developed concept was tested by the container which held commodities of spinach, pak choi, oyster mushroom, peeled onion, strawberry and cut carrot. The target optimum MA of 11% O2 and 10% CO2 (0.11 and 0.10 atm, respectively) was set to avoid injurious range of O2 and CO2 concentrations for any commodities. The developed container system could work to reach and maintain beneficial MA of 0.10-0.12 atm O2 and 0.07-0.10 atm CO2 close to the target during the storage contributing to quality retention of products measured in weight loss, chlorophyll content of spinach, ascorbic acid content of pak choi, color of onion, texture of oyster mushroom, bacterial count of strawberry and carotenoids of carrot. The container system shows potential to improve current preservation practice of fresh produce mix on consumers' level.