• Title/Summary/Keyword: Carbon formation

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Carbon Nanofibers with Controlled Size and Morphology Synthesized with Ni-MgO Catalyst Treated by Mechanochemical Process

  • Fangli Yuan;Ryu, Ho-Jin;Kang, Yong-Ku;Park, Soo-Jin;Lee, Jae-Rock
    • Journal of the Semiconductor & Display Technology
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    • v.3 no.1
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    • pp.9-13
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    • 2004
  • Carbon nanofibers (CNFs) with uniform diameter and controlled size were prepared from catalytic decomposition of $\textrm{C}_{2}\textrm{H}_{2}$ with Ni-MgO catalyst treated by mechanochemical (MC) process. The properties of Ni catalyst, such as size, distribution and morphology, can be governed by tuning grinding time in MC process. As a result, size and structure of CNFs can be tailored. The effect of grinding time to the as-grown CNFs was studied. CNFs with diameter from 10-70 nm were synthesized. CNFs with bundle formation sharing one tip and twisted CNFs were also synthesized with catalyst treated by MC process.

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Effect of Aluminium and Boron on Formability for Cu Bearing Extra Low Carbon Steel Sheets (Cu첨가 극저탄소 고 강도강의 가공성에 미치는 Al과 B의 영향)

  • Kim, S.I.;Chung, K.H.;Hong, M.H.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2009.05a
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    • pp.302-305
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    • 2009
  • This paper examines the effect of nitride formation on formability for Cu bearing high strength extra low carbon (ELC) steel sheets. For this purpose, we have investigated the effect of addition of aluminium (Al) and boron (B) on texture and precipitation behavior of the ELC steel during continuous annealing. Mechanical properties and microstructures of the ELC steel sheets were analyzed as well using uni-axial tensile test, electron back-scattered diffraction (EBSD) technique and transmission electron microscopy (TEM) following pilot rolling and continuous annealing. It has been found that the addition of Al and B increases the precipitation of AlN and BN. What is more, the scavange of solute nitrogen is effective in increasing the formability of the ELC steels. In addition, the Al and B addition improves the aging property of the ELC steel.

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Synthesis and Characterization of Three-dimensional Polymer Produced by Mutual Condensation of Ethylenediamine and $C_{60}$

  • Vovk, O.;Lee, Joong-Kee
    • Carbon letters
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    • v.5 no.2
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    • pp.68-74
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    • 2004
  • The polymer with contents of $C_{60}$ up to 57 wt.% was produced by mutual condensation of fullerene $C_{60}$ and ethylenediamine. The investigations of this polymer as well as pristine fullerene to comparison were carried out by FT-IR and UV-Vis spectroscopy, ToF-SIMS, TGA, and elemental analysis. At least three kinds of components was revealed as building blocks of polymer. The fullerene cage underwent only distortion but didn't destroy during formation of polymer. The pure fullerene was found as an intermediate of the thermal decomposition of polymer. The conclusion that this polymer could serve as precursor to produce carbon nanomaterial with high concentration curved graphene sheets and can be used for gas adsorption and electrochemical application was made.

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The Effect of Structure on the Fatigue of Low Carbon Steel (조직변화(組織變化)가 피로현상(疲勞現象)에 미치는 영향(影響))

  • C.S.,Kang;C.M.,Suh
    • Bulletin of the Society of Naval Architects of Korea
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    • v.9 no.2
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    • pp.33-42
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    • 1972
  • This paper was studied on the behavior, crack formation and propagation of slip bands on low carbon steel which was heat-treated in three conditions in order to change metallic structure. The specimens were tested by rotating bending fatigue testing machine and also observed the variations of grains by microscope. From the test results it was clear that fatigue endurance limit and life of low carbon steel were more increased in contrast with the case that the grain size of specimen was more decreased. Slip bands developed at oil-quenched specimen and furnace-cooled specimen. Formed cracks in the first one or two grains below the surface were approximately "planar" type, there after they followed "wavy" type. It was also found that cracks at 30% higher stress than fatigue limit were usually developed inter-granular, and cracks at 12% higher stress than fatigue limit were propagated meandering path, partly trans- and partly inter-grandular.

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Effect of Additives and Plating Conditions on Sn-Pb Alloy Film of Semiconductor Formed by High Speed Electroplating (전해도금에 의해 형성된 반도체 금속도금용 주석-납 합금피막의 첨가제 및 전해조건의 영향)

  • 정강효;김병관;박상언;김만;장도연
    • Journal of the Korean institute of surface engineering
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    • v.36 no.1
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    • pp.34-41
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    • 2003
  • Effects of additives and plating conditions of high speed electroplating were investigated. The Sn content in electrodeposit was highly decreased with increasing current density from $10A/dm^2$ to $50A/dm^2$, and the current efficiency on the cathode was decreased. The carbon content in the electrodeposit was decreased with increasing current density from $10A/dm^2$ to $30A/dm^2$, however the carbon content was highly increased in the range of $40A/dm^2$$∼50A/dm^2$. The formation of tetravalent tin and stannic oxide sludge was prevented by the addition of gallic acid in the bath. The changing of Sn content in the electrodeposit is caused by the addition of gallic acid.

Hydrogen Bonding-Driven Assembling of Thin Multiwalled Carbon Nanotubes (수소결합에 의한 얇은 다중벽 탄소나노튜브의 자기조립)

  • Han, Joong-Tark;Kim, Sun-Young;Woo, Jong-Seok;Lee, Gun-Woong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.426-427
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    • 2007
  • Here we describe the formation of a self-assembled film of thin multiwalled carbon Nanotubes(t-MWNT) modified with hydroxy groups through hydrogen peroxide treatment. Morphologies of t-MWNT films could be controlled by the various coating method, such as filtering, drop casting, spraying method, etc. The results show that on densification of the CNT suspension during drying, multiple hydroxy group-modified MWNTs can be self-assembled through strong surface hydrogen bond interaction while MWNTs usually exist an entangled state in the film. The interaction between t-MWNT was illustrated from Raman spectrum of spray coated films.

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Effect of Environment on the Tribological Behavior of Si-incorporated Diamond-like Carbon Films (실리콘이 첨가된 다이아몬드상 카본 필름의 트라이볼로지적 특성에 미치는 환경변화의 영향)

  • 양승호;공호성;이광렬;박세준;김대은
    • Tribology and Lubricants
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    • v.16 no.3
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    • pp.188-193
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    • 2000
  • An experimental study was performed to discover the effect of environment on the tribological behavior of Si-incorporated diamond-like carbon(Si-DLC) film slid on a steel ball. The films were deposited on Si(100) wafers by a radio-frequency glow discharge of mixtures of benzene and dilute silane gases. Experiments using a ball-on-disk test-rig was performed in vacuum, dry air and ambient air conditions. It was observed that coefficient of friction decreased as the environment changed from vacuum, to dry air. Chemical analyses of debris suggested that low and stable friction is closely related to the formation of silicon-rich oxide debris and the rolling action.

Effect of Carbon on Wear Resistance in Self-lubricating Fe-Cr-C-Mn-Cu Alloys

  • Kim, Ki Nam;Shin, Gyeong Su;Park, Myung Chul;Lee, Sung Yong;Yun, Jae Yong;Kim, Seon Jin
    • Korean Journal of Metals and Materials
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    • v.50 no.9
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    • pp.637-643
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    • 2012
  • Recently, because of safety and environmental concerns, there has been a tendency to introduce solid self-lubricating composites for bearing materials. In this paper, we developed Fe-Cr-C-Mn-Cu cast composite alloys as a self-lubricating composite and investigated the effect of carbon on the formation of protective tribofilms during sliding. The wear resistance of these materials was mainly affected by carbon concentrations due to the fact that in particular wear passed from delamination to tribo-oxidation, reducing the wear rate. The improved wear resistance likely resulted from protective tribofilms that formed on the surface during sliding.

Efficient Carbonization of ABS Rubber via Iodine Doping

  • Park, Chiyoung;Kim, Chae Bin
    • Elastomers and Composites
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    • v.57 no.1
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    • pp.9-12
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    • 2022
  • Herein, a facile approach for the development of effective and low-cost carbon precursors from acrylonitrile-butadiene-styrene (ABS) rubber is reported. ABS rubber with a negligible char yield can be converted into an excellent carbon precursor with approximately 54% char yield under a nitrogen atmosphere at 800℃ by simple iodine doping and subsequent heating at 110℃ under an inert atmosphere. The enhanced char yield is attributed to the improved intermolecular interactions between the ABS chains caused by the formation of covalent bonds between the butadiene segments, along with the newly developed charge-charge interactions and other indiscriminate radical-radical couplings. The charges and radicals involved in these interactions are also generated by iodine doping. We believe that this study will be useful for the development of low-cost carbon precursors.

Validity assessment of aspect ratios based on Timoshenko-beam model: Structural design

  • Emad Ghandourah;Muzamal Hussain;Mohamed A. Khadimallah;Mashhour Alazwari;Mohamed R. Ali;Mohammed A. Hefni
    • Computers and Concrete
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    • v.31 no.1
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    • pp.1-7
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    • 2023
  • In this paper, Timoshenko-beam model is developed for the vibration of double carbon nanotubes. The resulting frequencies are gained for axial wave mode and length-to-diameter ratios. The natural frequency becomes more prominent for lower length-to-diameter ratios and diminished for higher ratios. The converse behavior is observed for axial wave mode with clamped-clamped and clamped-free boundary conditions. The frequencies of clamped-free are lower than that of clamped-clamped boundary condition. The eigen solution is obtained to extract the frequencies of double walled carbon nanotubes using Galerkin's method through axial deformation function. Computer softer MATLAB is used for formation of frequency values. The frequency data is compared with available literature and found to be in agreement.