• Title/Summary/Keyword: Carbon flow

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Physical and Mechanical Properties of Low Carbon Green Concrete (저탄소 그린콘크리트의 물리·역학적 특성)

  • Cho, Il Ho;Sung, Chan Yong
    • Journal of The Korean Society of Agricultural Engineers
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    • v.55 no.3
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    • pp.123-128
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    • 2013
  • This study was performed to evaluate the slump flow, air content, setting time, compressive strength, adiabatic temperature rise and diffusion coefficient of chloride used ordinary portland cement, crushed coarse aggregate, crushed sand, river sand, fly ash, limestone powder, blast furnace slag powder and superplasticizer to find optimum mix design of low carbon green concrete for structures. The performances of low carbon green concrete used fly ash, limestone powder and blast furnace slag powder were remarkably improved. This fact is expected to have economical effects in the manufacture of low carbon green concrete for structures. Accordingly, the fly ash, limestone powder and blast furnace slag powder can be used for low carbon green concrete material.

High power $CO_2$ laser beam welding for low carbon steels (저탄소강의 고출력 $CO_2$ 레이저 빔 용접)

  • 김재도
    • Journal of Welding and Joining
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    • v.7 no.4
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    • pp.12-21
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    • 1989
  • Laser beam welding parameters have experimentally investigated, using a continuous wave 3kW $CO_2$ laser with the various travel speeds, beam mode and laser beam power in low carbon steels. An optimum position of focus and the effect of shielding gas on penetration depth with varying the flow range of 0.5 to 5.1m/min have been combined to investigate the effect of laser power and travel speed on penetration depth and bead width. It is found that the optimum position of focus in 3kW class laser is 0.5 to 1.5mm below the surface of the material. The flow rate of shielding gas affects the penetration depth and He is more effective than Ar. The penetration depth in laser welds of low carbon steels is between two and four times of the bead width. Laser beam welding of butt joints in 2mm thick carbon steel has been carried out to establish a weldability lobe. The lobe indicating acceptable welding conditions is introduced.

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Study on the Manufacture and Characteristics of Pitch-Based Activated Carbon Fibers Using Steam Activation (수증기 유량제어에 따른 피치계 활성탄소섬유 비표면적 특성에 대한 연구)

  • Hae-Reum Shin;Seung-Jun Yeo;Woo-Seung Noh;Man-Tae Kim
    • Journal of the Korean Society of Industry Convergence
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    • v.26 no.6_3
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    • pp.1333-1339
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    • 2023
  • To produce activated carbon fibers, the process is carried out through either physical activation method or chemical activation method. In this study, we present the results regarding the characteristics of activated carbon fibers manufactured under various conditions through the quantitative control of steam. The yield after activation indicates a decreasing trend with the increase in steam quantity and activation time. Additionally, specific surface area characteristics exhibit variations based on activation time and steam flow rate. The SEM analysis results reveal that higher steam flow rates lead to the presence of both mesopores and macropores on the surface of activated carbon fibers (ACF).

Mapping of Carbon Flow Distribution in the Central Metabolic Pathways of Clostridium cellulolyticum: Direct Comparison of Bacterial Metabolism with a Soluble versus an Insoluble Carbon Source

  • DESVAUX, MICKAEL,
    • Journal of Microbiology and Biotechnology
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    • v.14 no.6
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    • pp.1200-1210
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    • 2004
  • Metabolic flux analysis was established by adapting previous stoichiometric model developed during growth with cellulose to cell grown with cellobiose for further direct comparison of the bacterial metabolism. In carbon limitation with cellobiose, a shift from acetate-ethanol fermentation to ethanol-lactate fermentation is observed and the pyruvate overflow is much higher than with cellulose. In nitrogen limitation with cellobiose, the cellodextrin and exopolysaccharide overflows are much higher than on cellulose. In carbon and nitrogen saturation with cellobiose, the cellodextrin, exopolysaccharide, and free amino acids overflows reach the highest levels observed but all remain limited on cellulose. By completely shunting the cellulosome, the use of cellobiose allows to reach much higher carbon consumption rates which, in return, highlights the metabolic limitation of C. cellulolyticum. Therefore, the physical nature of the carbon source has a profound impact on the metabolism of C. cellulolyticum and most probably of other cellulolytic bacteria. For cellulolytic bacteria, the use of soluble carbon substrate must carefully be taken into consideration for the interpretation of results. Direct comparison of metabolic flux analysis from cellobiose and cellulose revealed the importance of cellulosome, phosphoglucomutase and pyruvate-ferredoxin oxidoreductase in the distribution of carbon flow in the central metabolism. In the light of these findings, future directions for improvement of cellulose catabolism by this bacterium are discussed.

A Study on Thermal Characteristic Carbon and other Elements in Suspended Particulates (대기 입자상물질중 탄소(C)등의 열적특성에 관한 조사연구)

  • 황경철
    • Journal of Environmental Health Sciences
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    • v.16 no.2
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    • pp.31-39
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    • 1990
  • An analytical method for particulate carbon and other elements by using elemental analyzer was investigated. Carbon, hydrogen, and nitrogen was determined as CO$_{2}$, H$_{2}$, and N$_{2}$, respectively. Organic was determined after scparation from elemental carbon(Cae) by volatilization and thermal decomposition in a heated helium flow. With organic materials examined in this reprot, more than 90% of carbon was detected as above 600$^{\circ}$C. But it is considered that a few percents of some compounds were charred above 550$^{\circ}$C. A small amount of Cae was oxidized in the inert atmosphere above 850$^{\circ}$C, but the reason was not explained clearly. Based on the thermal chracteristics of Cao it was found that the optimum temperature of heating in the helium flow of an elemental analyzer for Cao analysis is 630$^{\circ}$C. Carbon in a sample after removing Cao was assumed as Cae and the gramatom ratio of hydrogen to carbon in the sample was 0.4 and less. Rescovery of nitrogen derived from some ammonium salts and nitrates was 100% by two-step measurement with elemental analyzer. By the analytical method investigated in this report, carbon and other elements in suspended particulates(S.P) collected at an urban area in Seoul were measured. There was a good correlation between total nitrogen in SP measured by elemental analyzer and nitrogen estimated form ammonium ions and nitrate ions in SP. The nitrogen from these ions accounts for 80% of the total nitrogen. It is further suggested that the residue(20%) of the total nitrogen is attributed to the other nitrogeneous compounds.

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Development and Evaluation of Impregnated Carbon Systems Against Iodine Vapours

  • Srivastava, Avanish Kumar;Saxena, Amit;Singh, Beer;Srivas, Suresh Kumar
    • Carbon letters
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    • v.8 no.4
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    • pp.274-279
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    • 2007
  • In order to understand the breakthrough behaviour of iodine vapours on impregnated carbon systems, an active carbon, 80 CTC grade, $12{\times}30$ BSS particle size and $1104\;m^2/g$ surface area, was impregnated with metal salts such Cu, Cr, Ag, Mo and Zn, and an organic compound Triethylene diamine (TEDA) to prepare different carbon systems such as whetlerite, whetlerite/TEDA, whetlerite/KI/KOH and ASZMT. The prepared adsorbents along with active carbon were characterized for surface area and pore volume by $N_2$ adsorption at liquid nitrogen temperature. These carbon systems were compared for their CT (concentration X time) values at 12.73 to 53.05 cm/sec space velocities and 2 to 5 cm carbon column bed heights. The carbon column of 5.0 cm bed height and 1.0 cm diameter was found to be providing protection against iodine vapours up to 5.5 h at 3.712 mg/L iodine vapour concentration and 12.73 cm/sec space velocity. The study clearly indicated the adsorption capacities of carbon systems to be directly proportional to their surface area values. Dead layer with all the prepared carbon systems was found to be less than 2.0 cm indicating it to be minimum bed height to have protection against $I_2$ vapours. Effect of carbon bed height and flow rate was also studied. The active carbon showed maximum protection at all bed heights and flow rates in comparison to all other impregnated carbon systems, showing that only physical adsorption is responsible for the removal of iodine vapours.

Discussions on Carbon Account in Harvested Wood Products and Effects on Korean Carbon Emissions under the UNFCCC (기후변화협약 하에서 목제품 탄소계정 논의 동향 및 국내 탄소배출량에 미치는 영향 분석)

  • Choi, Soo Im;Bae, Jae Soo;Jung, Byung Heon
    • Journal of Korean Society of Forest Science
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    • v.95 no.4
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    • pp.405-414
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    • 2006
  • Korea is expected to be included in the countries of compulsory reduction of greenhouse gas emissions from the 2nd commitment period (2013~2017). For the negotiations in the future, this study was designed to review the tendency of discussions about carbon account in harvested wood products (HWP), which is currently underway around the globe and approach-specific characteristics, and analyze effects on carbon emissions in our country. As a result, most importantly, except the current IPC default approach there is no big difference among the 3 approaches of carbon account in HWP, which were newly suggested on the basis importers because all the HWP circulated at home are accounted for by carbon-stock changes. Under production approach, those HWP produced at home only are evaluated according to carbon-stock changes with the exception of imported HWP. Atmospheric-flow approach is favorable to net wood exporters, because the spot where ultimate decomposition and combustion arising out of the use of HWP occur is regarded as the place of carbon emission. Meanwhile, the estimation of korean carbon-stock change in HWP showed that as of 2004, stock-change approach was 1.567 Tg C, with production approach being 0.581 Tg C and atmospheric-flow approach being -1.425 Tg C, which means stock-change approach is most favorable to Korea as a net wood importer, while atmospheric-flow approach is the least favorable one, in terms of carbon emissions reduction in Korea.

A Study on the Flow-Accelerated Corrosion Characteristics of Galvanically Coupled Dissimilar Metals. (이종금속 연결에 따른 침부식(FAC) 특성에 관한 연구)

  • Kim, Jung-Gu
    • Proceedings of the KIEE Conference
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    • 2000.11a
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    • pp.269-272
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    • 2000
  • The flow accelerated galvanic corrosion characteristics of a carbon steel coupled to stainless steel were investigated in deaerated alkaline-chloride solutions as a function of flow velocities(0, 0.2, 0.4 and 0.6 m/s), pH(8, 9, and 10) and temperature(25, 50 and $75^{\circ}C$). The electrochemical properties of specimens were investigated by potentiodynamic test and galvanic corrosion test using RCE(Rotating Cylinder Electrode). Carbon steel did not show passive behavior in the alkaline-chloride solution. The galvanic current density increases with increasing flow velocity and temperature, but decreased with increasing pH. Flow velocity had a small effect on the galvanic current density at $25^{\circ}C$, whereas the flow velocity increased galvanic current density significantly at $50^{\circ}C$ and $75^{\circ}C$. This might be due to the increased solubility of magnetite at the higher temperature.

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Image Analysis and DC Conductivity Measurement for the Evaluation of Carbon Nanotube Distribution in Cement Matrix

  • Nam, I.W.;Lee, H.K.
    • International Journal of Concrete Structures and Materials
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    • v.9 no.4
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    • pp.427-438
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    • 2015
  • The present work proposes a new image analysis method for the evaluation of the multi-walled carbon nanotube (MWNT) distribution in a cement matrix. In this method, white cement was used instead of ordinary Portland cement with MWNT in an effort to differentiate MWNT from the cement matrix. In addition, MWNT-embedded cement composites were fabricated under different flows of fresh composite mixtures, incorporating a constant MWNT content (0.6 wt%) to verify correlation between the MWNT distribution and flow. The image analysis demonstrated that the MWNT distribution was significantly enhanced in the composites fabricated under a low flow condition, and DC conductivity results revealed the dramatic increase in the conductivity of the composites fabricated under the same condition, which supported the image analysis results. The composites were also prepared under the low flow condition (114 mm < flow < 126 mm), incorporating various MWNT contents. The image analysis of the composites revealed an increase in the planar occupation ratio of MWNT, and DC conductivity results exhibited dramatic increase in the conductivity (percolation phenomena) as the MWNT content increased. The image analysis and DC conductivity results indicated that fabrication of the composites under the low flow condition was an effective way to enhance the MWNT distribution.

CFD Simulation of Pd-Ag Membrane Process for $CO_2$ Separation (이산화탄소 분리를 위한 Pd-Ag 분리막 공정의 CFD 모사)

  • Oh, Min;Park, Junyong;Noh, Seunghyo;Hong, Seong Uk
    • Applied Chemistry for Engineering
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    • v.20 no.1
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    • pp.104-108
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    • 2009
  • In this study, for the flow of carbon dioxide/hydrogen mixture through a tubular type Pd-Ag membrane, hydrogen partial pressure, velocity profile, and concentration profile were simulated as a function of inlet flow rate using computational fluid dynamics (CFD) technique. The simulation results indicated that the mole fraction of carbon dioxide increased slowly in the longitudinal direction as the flow rate increased. In addition, the effects of inlet flow rate and the length of membrane on hydrogen recovery were investigated. At lower flow rate and for longer membrane, the hydrogen recovery was larger.