• Title/Summary/Keyword: Carbon flow

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Effects of chemistry in Mars entry and Earth re-entry

  • Zuppardi, Gennaro
    • Advances in aircraft and spacecraft science
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    • v.5 no.5
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    • pp.581-594
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    • 2018
  • This paper is the follow-on of a previous paper by the author where it was pointed out that the forthcoming, manned exploration missions to Mars, by means of complex geometry spacecraft, involve the study of phenomena like shock wave-boundary layer interaction and shock wave-shock wave interaction also along the entry path in Mars atmosphere. The present paper focuses the chemical effects both in the shock layer and on the surface of a test body along the Mars orbital entry and compares these effects with those along the Earth orbital re-entry. As well known, the Mars atmosphere is almost made up of Carbon dioxide whose dissociation energy is even lower than that of Oxygen. Therefore, although the Mars entry is less energized than the Earth re-entry, one can expect that the effects of chemistry on aerodynamic quantities, both in the shock layer and on a test body surface, are different from those along the Earth re-entry. The study has been carried out computationally by means of a direct simulation Monte Carlo code, simulating the nose of an aero-space-plane and using, as free stream parameters, those along the Mars entry and Earth re-entry trajectories in the altitude interval 60-90 km. At each altitude, three chemical conditions have been considered: 1) gas non reactive and non-catalytic surface, 2) gas reactive and non-catalytic surface, 3) gas reactive and fully-catalytic surface. The results showed that the number of reactions, both in the flow and on the nose surface, is higher for Earth and, correspondingly, also the effects on the aerodynamic quantities.

An experimental study on preparation of precipitated calcium carbonate using Ca component dissolution characteristics and liquid carbonation by the Industrial byproducts (산업부산물의 Ca 성분 용출 특성 및 액상탄산화 반응을 이용한 침강성 탄산칼슘 제조에 관한 실험적 연구)

  • Lim, Yun-Hui;Lee, Ju-Yeol;Shin, Jae-Ran;Choi, Chang-Sik;Hong, Bum-Ui;Kang, Ho Jong;Park, Byung Hyun
    • Journal of the Korean Applied Science and Technology
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    • v.32 no.1
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    • pp.116-126
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    • 2015
  • The present study utilized a shuttle mechanism of wet chemical absorption using MEA. In addition, industrial by-products containing a large amount of inorganic alkali substances were utilized for wet carbonization process. Chemical pretreatment of industrial by-products extracted calcium ions. ICP result of calcium ion was obtained up to 17,900 ppm(17.9%) by acidic substance. And also, In this work, 94% of recovery rate was obtained using wet MEA absorption process from $CO_2$ flow at the ambient condition. Through the liquid carbonation process, a sludge was fixed with rate of 0.175 mg of $CO_2$ per mg of sludge. It was found from XRD results that the structure of final product was composed of a calcite structure which is general structure of $CaCO_3$.

Evaporation Heat Transfer and Pressure Drop of $CO_2$ in a Small diameter Tube (세관내 이산화탄소의 증발 열전달 및 압력강화)

  • Jang, Seong-Il;Choi, Sun-Muk;Kim, Dae-Hui;Park, Ki-Won;Oh, Hoo-Kyu
    • Proceedings of the Korean Society of Marine Engineers Conference
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    • 2005.06a
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    • pp.189-194
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    • 2005
  • The evaporation heat transfer and pressure drop of $CO_2$ in a small diameter tube was investigated experimentally. The experiments were conducted without oil in a closed refrigerant loop which was driven by a magnetic gear pump. The main components of the refrigerant loop are a receiver, a variable-speed pump, a mass flow meter, a pre-heater and evaporator(test section). The test section was made of a horizontal stainless steel tube with the inner diameter of 4.57 mm, and length of 4 m. The experiments were conducted at mass flux of 200 to 700 $kg/m^2s$, saturation temperature of $0^{\circ}C$ to $20^{\circ}C$, and heat flux of 10 to 20 $kW/m^2$ . The test results showed the evaporation heat transfer of $CO_2$ has great effect on more nucleate boiling than convective boiling. The evaporation heat transfer coefficients of $CO_2$ are highly dependent on the vapor quality, heat flux and saturation temperature. The evaporation pressure drop of C02 are highly dependent on the mass flux. In comparison with test results and existing correlations, correlations failed to predict the evaporation heat transfer coefficient and pressure drop of $CO_2$, therefore, it is necessary to develop reliable and accurate predictions determining the evaporation heat transfer coefficient and friction pressure drop of $CO_2$ in a horizontal tube.

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Behavior of Elastic and Plastic Limit Loads of Thinned Elbows Observed During Real-Scale Failure Test Under Combined Load (감육엘보 실증실험에서의 탄성 및 소성 한계하중 거동 고찰)

  • Lee, Sung-Ho;Lee, Jeong-Keun;Park, Chi-Yong
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.34 no.9
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    • pp.1293-1298
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    • 2010
  • In most power plants, wall thinning in carbon-steel pipes due to flow-accelerated corrosion is one of the major aging phenomena, and it reduces the load-carrying capacity of the piping system. Various types of wall-thinning defects were manufactured in real-scale elbows, and monotonic in-plane bending tests were performed under internal pressure to evaluate the failure behavior of the elbows. In this paper, the behavior of elastic and plastic limit leads of locally thinned elbows in a real-scale failure test is presented. The loads determined on the basis of TES (twice elastic slope) were considered to be the limit loads of locally thinned elbows so that the integrity of the thinned elbows could be maintained, even when a small amount of plastic deformation might have occurred.

SiC Contaminations in Polycrystalline-Silicon Wafer Directly Grown from Si Melt for Photovoltaic Applications (실리콘 용탕으로부터 직접 제조된 태양광용 다결정 실리콘의 SiC 오염 연구)

  • Lee, Ye-Neung;Jang, Bo-Yun;Lee, Jin-Seok;Kim, Joon-Soo;Ahn, Young-Soo;Yoon, Woo-Young
    • Journal of Korea Foundry Society
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    • v.33 no.2
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    • pp.69-74
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    • 2013
  • Silicon (Si) wafer was grown by using direct growth from Si melt and contaminations of wafer during the process were investigated. In our process, BN was coated inside of all graphite parts including crucible in system to prevent carbon contamination. In addition, coated BN layer enhance the wettability, which ensures the favorable shape of grown wafer by proper flow of Si melt in casting mold. As a result, polycrystalline silicon wafer with dimension of $156{\times}156$ mm and thickness of $300{\pm}20$ um was successively obtained. There were, however, severe contaminations such as BN and SiC on surface of the as-grown wafer. While BN powders were easily removed by brushing surface, SiC could not be eliminated. As a result of BN analysis, C source for SiC was from binder contained in BN slurry. Therefore, to eliminate those C sources, additional flushing process was carried out before Si was melted. By adding 3-times flushing processes, SiC was not detected on the surface of as-grown Si wafer. Polycrystalline Si wafer directly grown from Si melt in this study can be applied for the cost-effective Si solar cells.

Economic Evaluation of Alternatives for CO2 Reduction of Thermal Power Generation Companies using ROPM: Comparing CCS with RPS Implementation (실물옵션을 활용한 화력발전회사의 CO2 감축대안의 경제성 평가: CCS와 RPS 이행의 비교)

  • Lee, Dong Su;Jeong, Kiho
    • Environmental and Resource Economics Review
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    • v.20 no.1
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    • pp.61-98
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    • 2011
  • This study conducts economic evaluation of alternatives for $CO_2$ reduction of thermal power plants. Two alternatives in reducing $CO_2$ emission are considered for the evaluation under the RPS(Renewable Portfolio Standard) system; one is to perform renewable energy quotas and another is to construct green thermal power plants using CCS(Carbon Capture and Sequestration). As evaluation methods, DCF(Discount Cash Flow) and ROPM(Real Options Pricing Method) are employed. At a discount rate of 7.5% applied to the Electricity Supply and Demand Plan, it is shown that green thermal power generation has economic dominance under both evaluation methods.

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Measurement of Antioxidant Activities and Phenolic and Flavonoid Contents of the Brown Seaweed Sargassum horneri: Comparison of Supercritical CO2 and Various Solvent Extractions

  • Yin, Shipeng;Woo, Hee-Chul;Choi, Jae-Hyung;Park, Yong-Beom;Chun, Byung-Soo
    • Fisheries and Aquatic Sciences
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    • v.18 no.2
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    • pp.123-130
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    • 2015
  • Seaweed Sargassum horneri extracts were obtained using supercritical carbon dioxide ($SC-CO_2$) and different solvents. $SC-CO_2$ was kept at a temperature of $45^{\circ}C$ and pressure of 250 bar. The flow rate of $CO_2$ (27 g/min) was constant during the entire 2-h extraction period, and ethanol was used as a cosolvent. Six different solvents [acetone, hexane, methanol, ethanol, acetone mix methanol (7:3), and hexane mix ethanol (9:1)] were used for extraction and agitated by magnetic stirring (250 rpm) in the dark at $25^{\circ}C$ for 20 h; the ratio of material to solvent was 1:10 (w/v). Antioxidant properties of S. horneri extracted using $SC-CO_2$ with ethanol and different solvents have shown good activity. The highest activity belongs to $SC-CO_2$ with ethanol extracted oil, showing DPPH, ABTS, total phenolic content, and total flavonoid levels of $68.38{\pm}1.21%$, $83.51{\pm}1.25%$, $0.64{\pm}0.02mg/g$, and $5.57{\pm}0.05mg/g$, respectively. The S. horneri extracts showed a significant correlation between the antioxidant activity and phenolic content. Based on these results, the $SC-CO_2$ extract (ethanol) of the seaweed extract from brown seaweed may be a valuable antioxidant source.

A Study on the Finite Element Analysis of springback characteristics according to stamping process conditions of UHSS with UTS of 1.2GPa (1.2GPa급 초고강도강판의 공정조건에 따른 스프링백 특성에 관한 유한요소해석 연구)

  • Jang, Hyun-Min;Choi, Kye-Kwang
    • Design & Manufacturing
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    • v.12 no.2
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    • pp.34-39
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    • 2018
  • The biggest topics in the automobile industry are light weightening and fuel efficiency improvement. There's a lot of research going on. It is focused on light weight materials. Light weight material is seen as the best way to reduce fuel consumption and to solve the problem of environmental pollution and resource depletion. For the light weight materials, new materials such as aluminum, magnesium, and carbon-hardening materials can be found. Research on the joining techniques of dual materials, improvement of material properties by improving the method of manufacture of existing materials, and studies on ultra-high strength steel sheets are expected to take up the most weight in lightweight materials. As the strength of the ultra-high strength steel sheets increases during forming, it is difficult to obtain dimensional precision due to the increase in elastic restoring force compared to mild or high strength steel sheets. Spring back is known to be affected by a number of factors due to poor plastic molding, and can be divided into the effects of the material spraying and the process. The study on the plasticitic variables were studied as plasticitic factors that can be controlled by a part company. Tensile testing of ultra-high strength materials was conducted to derive properties for plasticitic analysis and to analyze spring back with two factors controlling the height of the bead and blank holding force by adding tensile force and controlling the flow rate.

Application of SBR Process to Treat Pickling Wastewater including the High Nitrate and Ca+2 (고농도 질산성질소와 Ca+2을 함유한 산세폐수의 효과적인 처리를 위한 SBR 공정의 적용)

  • Kim, Seung-jun;Choi, Yong-su;Bae, Woo-keun
    • Journal of Korean Society on Water Environment
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    • v.22 no.2
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    • pp.215-221
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    • 2006
  • This research presents results from laboratory and pilot-scale experiments to remove high-nitrate in pickling wastewater using the sequencing batch reactor (SBR) as a biological method. During the experimental periods, the influent concentrations of NOx-N and $Ca^{+2}$ were analyzed to be 350-1,600 and 700-800 mg/L, respectively. In order to provide carbon source for denitrification, methanol has been added in proportion to the influent nitrate loading. The mean concentrations of MLSS and MLVSS, the fraction of volatile solids in sludge and the sludge volume index were measured to be 27 g/L, 5 g/L, 18.5% and 7.5, respectively. The solid retention time was kept in the range of 18 to 22 days, specific denitrification rate ($U_{dn}$) was $0.301g{NO_3}^--N/gVSS/day$. The oxidized nitrogen concentration of effluent ranged 2-34 mg/L with an average of 5.2 mg/L, the overall reduction in total nitrogen was more than 99.2%. In order to treat the pickling wastewater including the high concentration of nitrate and $Ca^{+2}$, the continuous flow process is not suitable because the specific gravity of the sludge is considerably increased by $Ca^{+2}$, thus the SBR process is shown to be very effective to treat the pickling wastewater.

Priority Selection of Water Quality Improvement Through Water Quality Data of Tributaries of Nakdong River (낙동강수계 지류 수질자료를 통한 수질개선 우선순위 선정)

  • Shim, Kyuhyun;Shin, Sangmin;Kim, Seongmin;Kim, Youngseok;Kim, Gyeonghoon
    • Journal of Korean Society on Water Environment
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    • v.36 no.5
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    • pp.364-372
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    • 2020
  • The "Master Plan for the Revitalization of Water in the Nakdong River" is designed for the fundamental improvement of water quality in the Nakdong River. The water quality and flow of the Nakdong River system tributaries was monitored in this study. Among the living environmental standard parameters of 195 rivers, BOD (Biochemical oxygen demand), T-P (Total phosphorus) and TOC (Total organic carbon) were assessed to analyze the water quality from 2012 to 2019. We examined the role of TOC. It was found that 12 rivers exceeded the water quality of the second grade (3.0 mg/L BOD standard, 0.1 mg/L T-P standard, 4.0 mg/L TOC standard) based on BOD and T-P concentrations: the Gumi stream, Gisegok stream, Yongha stream, Yongho stream, Changnyeong stream, Gajwa stream, Gwangok stream, Yeongsan stream, Toerae stream, Hwapo stream, Sangnam stream and Hogye stream. These rivers require strategies to improve the quality of the Nakdong River. Based on the ongoing project, it is possible to supplement the "Master Plan for the Revitalization of Water in the Nakdong River" and manage it after verifying it as a component of people's life and therefore used to establish water quality control measures.