• Title/Summary/Keyword: Carbon film

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Simulation Model for Dissolution of Liquid $CO_2$ Discharged at Intermediate Depth of Ocean (중층심해에 분사된 액체 이산화탄소 용해 예측모델 개발)

  • 김남진;김종보
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.15 no.9
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    • pp.718-726
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    • 2003
  • Carbon dioxide ocean disposal is one of the promising options to reduce carbon dioxide concentration in the atmosphere because the ocean has vast capacity for carbon dioxide sequestration. However, the dissolution rate of liquid carbon dioxide in seawater must be known in advance in order to estimate the amount of carbon dioxide sequestration in the ocean. Therefore, in the present study, calculations of the solubility, the surface concentration and the dissolution behavior of carbon dioxide when liquid carbon dioxide is released at 1,000m and 1,500m in depth are peformed. The results show that the droplet is completely dissolved below 500 m in depth if the carbon dioxide droplet is released both at 1,000m in depth with the initial droplet diameter of 0.011m or less and at 1,500m in depth with the diameter of 0.016 or less. Also, the surface concentration of carbon dioxide droplet with the hydrate film is about 50% of carbon dioxide solubility at 1,500 m in depth and about 60% of carbon dioxide solubility at 1,000 m in depth.

Effect of High Concentration Carbon Dioxide and Pre-Cooling Treated with Solid Carbon Dioxide on the Storability of Radish Sprout in MA Storage (고체 이산화탄소를 이용한 고농도 이산화탄소와 예냉 처리가 싹채소의 저장성에 미치는 영향)

  • Kang, Ho-Min;Choi, In-Lee;Kim, Il-Seop;Park, Keun-Woo
    • Journal of Bio-Environment Control
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    • v.18 no.3
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    • pp.285-290
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    • 2009
  • The solid carbon dioxide used for prolongation shelf life of radish sprout that was just 7days. The developed equipment for treated carbon dioxide consisted of solid carbon dioxide evaporated part and high carbon dioxide and low temperature treated part that can hold products. The inner temperature of equipment decreased temperature to below $5^{\circ}C$ from room temperature for 10minutes and carbon dioxide concentration increased to 80%. The radish sprouts treated 4 different conditions that was nontreated condition (control), solid carbon dioxide put into package (CO2-1), solid carbon dioxide treated before storage using the developed equipment (CO2-2), solid carbon dioxide treated before storage and during storage, and sprout packaged with solid carbon dioxide (CO2-3). These radish sprout packaged with $25{\mu}m$ ceramic film stored at $8^{\circ}C$. The high carbon dioxide treatment did not affect the fresh weight loss. The carbon dioxide and oxygen content in package changed 40% and 10%, respectively in CO2-1 and CO2-2 at 1day after treatments. But carbon dioxide content of all treatments was decreased to 5% and stabilized. The high carbon dioxide showed the effect of reduction ethylene production, but did not affect to visual quality and offodor.

Relations Between Dispersion of CNTs and Electrical Conductivity in the Hydrophobic CNT/PVDF Composite Film (소수성 CNT/PVDF 복합막에서 CNT의 분산과 전도성의 관계)

  • Lee, Sunwoo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.28 no.7
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    • pp.462-466
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    • 2015
  • In this paper, we investigated the relations between dispersion of CNTs (carbon nanotubes) and electrical conductivity in the CNT/PVDF (polyvinylidene fluoride) composite film. By adding hydrophobic CNTs as filler into the PVDF matrix, we fabricated hydrophobic and electrically conducting polymer coating film. Dispersion of CNTs in the CNT/PVDF composite film plays a significant role in terms of electrical conductivity and wetting property. Spray coating method was used to form the CNT/PVDF composite films by injecting the dispersed CNTs in the PVDF solution with different weight ratios from 0.7 wt% to 7 wt%. We investigated the electrical properties and contact angles of the CNT/PVDF composite films with the CNT concentration. Finally we discussed the conducting mechanism and feasibility of the CNT/PVDF composite film for the conducting polymer films.

Monitoring of Low-velocity Impact Damage Initiation of Gr/Ep Panel Using Piezoelectric Thin Film sensor (압전필름센서를 이용한 복합재 평판의 저속충격 손상개시 모니터링)

  • 이관호;박찬익;김인걸;이영신
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2001.10a
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    • pp.174-178
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    • 2001
  • The piezoelectric thin film sensor can be used to interpret variations in structural and material properties, e.g. for structural integrity monitoring and assessment. To illustrate one of this potential benefit, PVDF film sensors are used for monitoring impact damage initiation in Gr/Ep composite panel. Both PVDF film sensors and strain gages are surface mounted to the Gr/Ep specimens. A series of impact test at various impact energy by changing impact mass and height is performed on the instrumented drop weight impact tester. The sensor responses are carefully examined to predict the onset of impact damage such as matrix cracking, delamination, and fiber breakage, etc. Test results show that the particular waveforms of sensor signals implying the damage initiation and development are detected above the damage initiation impact energy. As expected, the PVDF film sensor is found to be more sensitive to impact damage initiation event than the strain gage.

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Assesment of Biodegradability of Poly-$\beta$- Hydroxyvbutyrate by Pot-Test (Pot-Test에 의한 Poly-$\beta$-Hydroxybutyrate의 생분해성 평가)

  • 손대주;김희구
    • Journal of Environmental Science International
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    • v.6 no.4
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    • pp.379-384
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    • 1997
  • The biodegradable characteristics of poly-$\beta$-hydroxybutyrate(PHB) film by fun맥 and soil burial are Investigated. As the results of the American Standards for Testing and Materials(ASTM) method, the you of Aspergillus niger was apparent on the PHB containing plate. This suggests that PHB was utilized as the sole carbon source by Aspergillus niger and ASTM method may have applications as measuring means of biome gradability of polyhydroxyalkanoic acid(PHA). PHB film was studied by monitoring the time-dependant changes in weight loss of PHB film under 30% and relative humidity 80 % during pot-test. As the results of pot-test, PHB film was decomposed about 87 % in 30 days by soul microorganisms. PHB film was more slowly degraded than PHB/HV film.

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Improvement of Adhesion Strength of DLC Films on Nitrided Layer Prepared by Linear Ion Source

  • Shin, Chang-Seouk;Kim, Wang-Ryeol;Park, Min-Seok;Jung, Uoo-Chang;Chung, Won-Sub
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.177-179
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    • 2011
  • The purpose of this study is to enhance an adhesion between substrate and Diamond-like Carbon (DLC) film. DLC has many outstanding properties such as low friction, high wear resistance and corrosion resistance. However, it is difficult to achieve enough adhesion because of weak bonding between DLC film and the substrate. For improvement adhesion, a layer between DLC film and the substrate was prepared by dual post plasma. DLC film was deposited on nitrided layer by linear ion source. The composed compound layer between substrate and DLC film was investigated by Glow Discharge Spectrometer (GDS) and Scanning Electron Microscope (SEM). The synthesized bonding structure of DLC film was analyzed using a micro raman spectrometer. Mechanical properties were measured by nano-indentation. In order to clarify the mechanism for improvement in adhesive strength, it was observed by scratch test.

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Oxidation of BON and Si-DLC Thin Films deposited by Plasma Enhanced CVD method (Plasma Enhanced CVD 법으로 증착한 BON박막과 Si-DLC 박막의 산화)

  • Kim, Chan-U;Hong, Ri-Seok;Lee, Dong-Bok
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2007.04a
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    • pp.73-73
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    • 2007
  • Amorphous BON and Si-DLC thin films were synthesized by the RF plasma enhanced CVD method, and their oxidation behavior was studied up to $500^{\circ}C$ in air. The oxidation of both films was accompanied by evaporation of volatile species. The oxidation of BON film was preceded by nitrogen escape from the film, and oxygen penetration into the film. The oxidation of Si-DLC film was preceded by carbon escape probably as CO or $CO_2$from the film, and oxygen penetration into the film. The inwardly transported oxygen simply stayed in the oxidized BON and Si-DLC thin films.

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Improved Adhesion of DLC Films by using a Nitriding Layer on AISI H13 Substrate

  • Park, Min-Seok;Kim, Dae-Young;Shin, Chang-Seouk;Kim, Wang Ryeol
    • Journal of the Korean institute of surface engineering
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    • v.54 no.6
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    • pp.307-314
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    • 2021
  • Diamond-like carbon (DLC) is difficult to achieve sufficient adhesion because of weak bonding between DLC film and the substrate. The purpose of this study is to improve the adhesion between substrate and DLC film. DLC film was deposited on AISI H13 using linear ion source. To improve adhesion, the substrate was treated by dual post plasma nitriding. In order to define the mechanism of the improvement in adhesive strength, the gradient layer between substrate and DLC film was analyzed by Glow Discharge Spectrometer (GDS) and Scanning Electron Microscope (SEM). The microstructure of the DLC film was analyzed using a micro Raman spectrometer. Mechanical properties were measured by nano-indentation, micro vickers hardness tester and tribology tester. The characteristic of adhesion was observed by scratch test. The adhesion of the DLC film was enhanced by active screen plasma nitriding layer.

SUPERLUBRICITY IN CARBON FILMS

  • Erdemir, Ali
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2002.10b
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    • pp.163-164
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    • 2002
  • This paper describes a new carbon film that afford superlubricity (i.e, friction coefficients of 0.001- 0.005) and superlow wear rates (i.e., $10^{-11}-10^{-10}mm^3/N.m$) to sliding metallic and ceramic surfaces, when tested in inert test environments. The wear life of these films are more than 1000 km even under very high contact pressures (i.e., 1-3 GPa) and at a wide range of sliding velocities (i.e., 0.1 to 2 m/s). They are produced in a plasma enhanced chemical vapor deposition system at room temperature using highly hydrogenated gas discharge plasmas. Extensive research has shown that films grown in highly hydrogenated gas discharge plasmas (i.e., hydrogen-to-carbon ratio of 6 and above) provide superlow friction and wear coefficients. In full paper, specific conditions under which superlubricity can be achieved in carbon films will be discussed.and a mechanistic model will be proposed to explain the superlubricity of new carbon films.

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Synthesis of well-aligned thin multiwalled carbon nanotubes on the silicon substrate and their field emission properties

  • Yuan, Huajun;Shin, Dong-Hoon;Kim, Bawl;Lee, Cheol-Jin
    • Carbon letters
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    • v.12 no.4
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    • pp.218-222
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    • 2011
  • Well-aligned multi-walled carbon nanotubes (MWCNTs) were successfully synthesized by catalytic chemical vapor deposition using a hydrogen sulfide ($H_2S$) additive onto Al/Fe thin film deposited on Si wafers. Transmission electron microscopy images indicated that the as-grown carbon products were thin MWCNTs with small outer diameters of less than 10 nm. $H_2S$ plays a key role in synthesizing thin MWCNTs with a large inside hollow core. The well-aligned thin MWCNTs showed a low turn-on voltage of about 1.1 V/${\mu}m$ at a current density of 0.1 ${\mu}A/cm^2$ and a high emission current of about 1.0 mA/$cm^2$ at a bias field of 2.3 V/${\mu}m$. We suggest a possible growth mechanism for the well-aligned thin MWCNTs with a large inside hollow core.