• Textile Coloration and Finishing
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• v.6 no.1
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• pp.33-43
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• 1994

In the present work, to clarify the mechanism of the neutral salt effect on the alkaline hydrolysis of PET, many salts with different cations like LiCl, NaCl, KCl, CsCl were added to the aqueous alkaline solutions. Then PET was hydrolyzed with aqueous solutions of many salts in alkali metal hydroxides under various conditions. Some conclusions obtained from the experimental results were summarized as follows. The reaction rate of the alkaline hydrolysis of PET was increased by the addition of neutral salts and In k was increased nearly linearly with the square root of ionic strength of reaction medium. This fact suggested that the ionic strength effect by Debye-Huckel and Bronsted theory was exerted on the reaction. The specific salt effect was also observed. The reaction rate was increased with the increase in the electrophilicity of cations of neutral salts, i. e., in the order of $Cs^+$/ < $K^+$/ $a^+$/ $i^$^+$. It was considered that the reaction rate was increased in the order of C $s^+$. < $K^+$. $a^+$. $i^+$. because the lowering effect of the cations on the negative charge of PET surface was increased with the electrophilicity of cations. It was thought that $E_{a}$ was increased because the cations of neutral salts decreased the negative charge of PET surface. It, however, was inferred from the increase in ${\Delta}$S＊ and the decrease in the ${\Delta}$G＊ that the cations of neutral salts associated with PET increased the collision frequency between carbonyl carbon and OH- ion and then accelerated the reaction rate.te.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.37 no.6
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• pp.586-594
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• 2009

This paper is the study on random, sinusoidal and shock vibration responses for the STSAT-3(science and technology satellite-3) proto-model which is the first small size all-composite satellite in Korea. The structure system of the STSAT-3 forms box type structure by joining several hybrid sandwich panels comprised of honeycomb core and carbon fiber reinforced laminated composite skins on both side. Mode shape, stress, displacement and acceleration responses are obtained on both the frequency domain and time domain by means of a commercial FEA software MSC/NASTRAN. From these analysis results, failure, safety factor and design validity are assessed. These results can be successfully applicable as reference data when a new satellite is developed as well as giving out an excellent criteria in satellite vibration treatment design.

• Journal of the Korean Institute of Gas
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• v.13 no.6
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• pp.29-33
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• 2009

In this study, the strength safety of a composite fuel tank which is fabricated by an aluminum liner of Al6061-T6 materials and composite layers of carbon/epoxy-glass/epoxy composites has been analyzed by using a finite element analysis technique. In order to enhance the durability of the composite fuel tank, an autofrettage process was used and compressed natural gas was supplied to the prestressed fuel tank. The FEM computed results on the stress safety of autofrettaged gas tanks were compared with a criterion of design safety of US DOT-CFFC and Korean Standard. The FEM computed results indicated that the stress safety of autofrettaged fuels tanks shows instability at the dome zone and uniform stability at the parallel body, which provide an evaluation data for a strength safety of autofrettaged composite fuel tanks. The computed results show that the stress safety of 9.2 liter composite fuel tanks satisfied the safety criteria of four evaluation items, which are provided by US DOT-CFFC and KS and indicated a safe design.

• Journal of the Korean Society of Fisheries and Ocean Technology
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• v.31 no.3
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• pp.272-278
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• 1995

In this paper to investigate mode I and mode II critical energy release rates, G sub(IC) and G sub(IIC), three prepregs which are domestic products are used. Those are used for the unidirectional composites, but only one is used for the cross-ply laminate composites which is molded [0/90] sub(6s), [0/45] sub(6s) and [0/45/90] sub(6s). The value of G sub(IC) is almost same when modified three calculating methods are applied. The highest value of G sub(IC) at crack initiation is obtained at the [0/90] sub(6s) interlaminar and the lowest one is at the [0/45/90] sub(6s) interlaminar.

• Structural Engineering and Mechanics
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• v.67 no.2
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• pp.207-217
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• 2018

In past years, numerous problems have vexed engineers with regard to buckling, corrosion, bending, and overloading in damaged steel structures. This article sets out to investigate the possible effects of carbon fiber reinforced polymer (CFRP) and steel plates for retrofitting deficient steel square hollow section (SHS) columns. The effects of axial loading, stiffness, axial displacement, the position and shape of deficient region on the length of steel SHS columns, and slenderness ratio are examined through a detailed parametric study. A total of 14 specimens was tested for failure under axial compression in a laboratory and simulated using finite element (FE) analysis based on a numerical approach. The results indicate that the application of CFRP sheets and steel plates also caused a reduction in stress in the damaged region and prevented or retarded local deformation around the deficiency. The findings showed that a deficiency leads to reduced load-carrying capacity of steel SHS columns and the retrofitting method is responsible for the increase in the load-bearing capacity of the steel columns. Finally, this research showed that the CFRP performed better than steel plates in compensating the axial force caused by the cross-section reduction due to the problems associated with the use of steel plates, such as in welding, increased weight, thermal stress around the welding location, and the possibility of creating another deficiency by welding.

• Journal of Radiation Industry
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• v.6 no.1
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• pp.55-59
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• 2012

Polyacrylonitrile (PAN)-based carbon fibers have been widely used due to their unique chemical, electrical, and mechanical properties. Electron beam irradiation has been extensively employed as means of altering properties of polymeric materials. Electron beam irradiation can induce chemical reactions in materials without any catalyst. Electron beam irradiation may be useful in accelerating the thermal compression stabilization of PAN nanofibers. To investigate the irradiation effect on PAN fibers, PAN nanofibers were irradiated by electron beam at 1,000~5,000 kGy. Irradiated and non-irradiated PAN nanofibers were heated at 180 and $220^{\circ}C$ without applying pressure for 15 min. Then 1 metric ton has been applied for 5 min. SEM images have been found that the fiber kept its morphological behavior after the hot pressing up to electron beam irradiated 1,000 kGy. DSC thermograms showed that the peak temperatures of the exothermic reactions were found to decrease with increasing electron beam irradiation doses and temperature. FT-IR spectra have been found to decrease $C{\equiv}N$ stretch band with increasing the electron beam irradiation dose. These results indicate that the modification of PAN via reactions such as cyclization is significantly enhanced by electron beam irradiation and thermal compression technique.

• Journal of Aerospace System Engineering
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• v.13 no.5
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• pp.94-101
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• 2019

The dynamic characteristics of the composite reflector panels are numerically and experimentally investigated. A dynamics model of the panel is analytically developed based on a deployment mechanism of the antenna. The deployment is passively activated using elastic energy of a spring with two rotational degrees of freedom. Using the flexible multi-body dynamic analysis ADAMS, dynamic behavior of the panels such as velocities, deformations, as well as reaction forces during the deployment, are investigated in the gravity and zero-gravity cases. The reflector panel is manufactured using carbon fiber reinforced plastics (CFRPs) and its deployment characteristics are experimentally observed using a zero-gravity deployment test. The impact response and vibration problems that occur during deployment of the antenna panel have been identified and reliably deployed using dampers.

• Journal of the Korean Society of Propulsion Engineers
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• v.17 no.2
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• pp.31-38
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• 2013

This research analyzed the acoustic emission signals collected from the pin loading tests and investigated the effect of hygrothermal exposure on the fracture behavior of the pin-jointed carbon fiber/epoxy composites. The composite specimens include: the Base specimen that has not been exposed to any environments, the RT specimen that has been immersed in room temperature water, and the HT specimen that has been immersed in high temperature water. According to the pin loading test, the RT and the HT specimens showed 2.2% and 13% decreases in the bearing strength compared to the Base specimen, respectively. The analysis of the acoustic emission signals showed different fracture acceleration points for three types of the specimens. Furthermore, for the RT and the HT specimens, the event from the matrix crack signals in the composites decreased. This shows the effect of the hygrothermal conditions on the acoustic emission signals. Additionally, upon investigating the fracture behaviors of the pin-jointed composites, the exposing specimens to hygrothermal environments decreases the interfacial characteristics of the composites.

• Structural Engineering and Mechanics
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• v.55 no.6
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• pp.1139-1155
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• 2015

In this study, a new retrofitting method for improving the seismic performance of reinforced concrete column was presented, in which prestressed steel strips were utilized as retrofitting stuff to confine the reinforced concrete column transversely. In order to figure out the seismic performance of concrete column specimen retrofitted by such prestressed steel strips methods, a series of quasi-static tests of five retrofitted specimens and two unconfined column specimen which acted as control specimens were conducted. Based on the test results, the seismic performance including the failure modes, hysteresis performance, ductility performance, energy dissipation and stiffness degradation of all these specimens were fully investigated and analyzed. And furthermore the influences of some key parameters such as the axial force ratios, shear span ratios and steel strips spacing on seismic performance of those retrofitted reinforced concrete column specimens were also studied. It was shown that the prestressed steel strips provided large transverse confining effect on reinforced concrete column specimens, which resulted in improving the shearing bearing capacity, ductility performance, deformation capacity and energy dissipation performance of retrofitted specimens effectively. In comparison to the specimen which was retrofitted by the carbon fiber reinforced plastics (CFRP) strips method, the seismic performance of the specimens retrofitted by the prestressed steel strips was a bit better, and with much less cost both in material and labor. From this research results, it can be concluded that this new retrofitting method is really useful and has significant advantages both in saving money and time over some other retrofitting methods.

• Korean Journal of Soil Science and Fertilizer
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• v.44 no.6
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• pp.1286-1294
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• 2011

This paper reviews the future directions and perspectives on the soil environmental researches in the 21 century. Previously, the principal emphasis of soil environmental researches had put on the enhancement of food and fiber productions. Beside the basic function of soil, however, the societal needs on soil resources in the 21st century have demands for several environmental and social challenges, occurring regionally or globally. Typical global issues with which soil science should deal include food security with increasing agronomic production to meet the exploding world population growth, adaptation and mitigation of climate change, increase of the carbon sequestration, supply of the biomass and bioenergy, securing the water resource and quality, protection of environmental pollution, enhancing the biodiversity and ecosystem health, and developing the sustainable farming/cropping system that improve the use efficiency of water and agricultural resources. These challenges can be solved through the sustainable crop production intensification (SCPI) or plant welfare concept in which soil plays a key role in solving the abovementioned global issues. Through implementation of either concept, soil science can fulfill the goal of the modern agriculture which is the sustainable production of crops while maintaining or enhancing the ecosystem function, quality and health. Therefore, directions of the future soil environmental researches should lie on valuing soil as an ecosystem services, translating research across both temporal and spatial scales, sharing and using data already available for other purposes, incorporating existing and new technologies from other disciplines, collaborating across discipline, and translating soil research into information for stakeholders and end users. Through the outcomes of these approaches, soil can enhance the productivity from the same confined land, increase profitability, conserve natural resource, reduce the negative impact on environment, enhance human nutrition and health, and enhance natural capital and the flow of ecosystem services. Soil is the central dogma, final frontier and new engine for the era of sustainability development in the $21^{st}$ century and thus soil environmental researches should be carried according to this main theme.