• Title/Summary/Keyword: Carbon doping

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Carbon Nanotube Effects on Physical Properties of Liquid Crystal and Electro-Optic Characteristics of Twisted Nematic Liquid Crystal Cell (카본나노튜브가 액정의 물성과 Twisted Nematic 액정 셀의 전기광학 특성에 미치는 영향)

  • Jeon, S.Y.;Jeong, S.J.;Jeong, S.H.;Shin, S.H.;An, K.H.;Lee, S.E.;Lee, S.H.;Lee, Y.H.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.04a
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    • pp.41-42
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    • 2006
  • Carbon nanotubes (CNTs) effects on physical properties of the liquid crystal and twisted nematic (TN) liquid crystal (LC) cells have been investigated. The minute doping of CNTs reduces rotational viscosity of the LC, and thus switching time of the TN cells is improved, especially in grey scale response time. In addition, the dielectric anisotropy and birefringence are not affected by such a small amount of CNT-doping and thus voltage-dependent transmittance remains the same.

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Review on Functionalization of Laser-Induced Graphene

  • Jin Woo An;Hee Jae Kim;Seoung-Ki Lee
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.36 no.3
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    • pp.203-213
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    • 2023
  • Owing to carbon materials' diverse functionalization and versatility, the design and synthesis of carbon-based three-dimensional porous structures have become important foundational research topics across various fields. Among the various methods for producing porous carbon structures, laser-induced graphene (LIG) has garnered attention because of its large surface area, controllable structure, excellent electrical conductivity, scalability, and eco-friendly synthesis process. In addition, recent research results have reported more novel functionalities by advancing further from the unique characteristics of LIG through functionalization or compounding of LIG, making it an attractive material for various applications in electronic devices, sensing, catalysis, and energy storage. This review aims to update the research trends in LIG and its functionalization, providing insights to inspire more interesting studies on functional LIG to expand its potential applications ultimately. Starting with the synthesis method and material characteristics of LIG, we introduce the functionalization of LIG, which is classified into surface modification, heteroatom doping, and hybridization based on the interaction mechanism. Finally, we summarize and discuss the prospects of LIG and its functionalization.

Vertically Aligned Carbon Film Synthesized from Magnetically Oriented Polyacetylene using Morphology Retaining Carbonization

  • Goh, Munju;Choi, Yong Mun
    • Carbon letters
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    • v.13 no.4
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    • pp.226-229
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    • 2012
  • Polyacetylene (PA) films with vertically aligned fibril morphology were synthesized in homeotropic nematic liquid crystal (N-LC) solvent by using a magnetic field of 5 Tesla as an external perturbation. Scanning electron microscope (SEM) photographs indicated that the lengths of fibrils from the substrate were $5-35{\mu}m$, depending on polymerization time. Carbonization was carried out using iodine-doped PA film and a morphology-retaining carbonization method. From the SEM results, we confirmed that the vertical morphology of the PA remains unchanged even after carbonization at $800^{\circ}C$. The weight loss of the films due to carbonization at $800^{\circ}C$ is about 20% of the weight of the film before iodine doping. It is expected that vertically aligned carbon might be a precursor for preparing vertical graphite materials, which materials could be useful for electrochemical energy storage and cell electrodes.

Microstructural, mechanical, and electrochemical analysis of carbon doped AISI carbon steels

  • Muhammad Ishtiaq;Aqil Inam;Saurabh Tiwari;Jae Bok Seol
    • Applied Microscopy
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    • v.52
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    • pp.10.1-10.15
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    • 2022
  • The effect of carbon doping contents on the microstructure, hardness, and corrosion properties of heat-treated AISI steel grades of plain carbon steel was investigated in this study. Various microstructures including coarse ferrite-pearlite, fine ferrite-pearlite, martensite, and bainite were developed by different heat treatments i.e. annealing, normalizing, quenching, and austempering, respectively. The developed microstructures, micro-hardness, and corrosion properties were investigated by a light optical microscope, scanning electron microscope, electromechanical (Vickers Hardness tester), and electrochemical (Gamry Potentiostat) equipment, respectively. The highest corrosion rates were observed in bainitic microstructures (2.68-12.12 mpy), whereas the lowest were found in the fine ferritic-pearlitic microstructures (1.57-6.36 mpy). A direct correlation has been observed between carbon concentration and corrosion rate, i.e. carbon content resulted in an increase in corrosion rate (2.37 mpy for AISI 1020 to 9.67 mpy for AISI 1050 in annealed condition).

Performance of Carbon Cathode and Anode Electrodes Functionalized by N and O Doping Treatments for Charge-discharge of Vanadium Redox Flow Battery (탄소전극의 질소 및 산소 도핑에 따른 바나듐 레독스-흐름전지 양극 및 음극에서의 촉매화학적 특성 연구)

  • Lim, Hyebin;Kim, Jiyeon;Yi, Jung S.;Lee, Doohwan
    • Clean Technology
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    • v.23 no.3
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    • pp.308-313
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    • 2017
  • In this study, we investigated the electrocatalytic effects of the N and O co-doping of Graphite Felt (GF) electrode for the vanadium redox flow battery (VRFB) at the cathode and the anode reaction, respectively. The electrodes were prepared by chemical vapor deposition (CVD) with $NH_3-O_2$ at 773 K, and its effects were compared with an electrode prepared by an O doping treatment. The surface morphology and chemical composition of the electrodes were characterized by scanning electron microscopy (SEM) and photoelectron spectroscopy (XPS). The electrocatalytic properties of these electrodes were characterized in a VRFB single cell comparing the efficiencies and performance of the electrodes at the cathode, anode, and single cell level. The results exhibited about 2% higher voltage and energy efficiencies on the N-O-GF than the O-GF electrode. It was found that the N and O co-doping was particularly effective in the enhancement of the reduction-oxidation reaction at the anode.

Ion charge in captivity in a nanotube-doped liquid-crystal cell (?)

  • Lee, Wei;Chen, Hui-Yu
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.1609-1612
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    • 2006
  • Transient currents were measured in nematic liquid-crystal cells with and without doping of multiwalled carbon nanotubes. Comparative results suggest that the field-screening effect induced by the adsorbed charge is substantially suppressed by the carbon-nanotube dopant, leading to a reduction of the driving voltage and improved performance of display properties.

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Carbon Molecular Sieve Membranes Dispersed with Nano Particles

  • H.Suda;Ha, K.raya
    • Proceedings of the Membrane Society of Korea Conference
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    • 2004.05a
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    • pp.183-186
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    • 2004
  • Nano particles-containing CMS membranes were prepared by pyrolysis of polyimides dispersed uniformly with precursors and their gas separation performances were examined, to elucidate the permeation mechanism and to further improve the gas separation performance. Consequently, it was suggested that the separation performance could be controlled by doping nano-particles in the CMS membranes, and that optimization of various factors, such as the size, content, and dispersion state of the nano particles would contribute for further improvement of the gas separation performance.

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Photocatalytic Degradation of Rhodamine B Using Carbon-Doped Carbon Nitride under Visible Light

  • Wang, Zhong-Li;Zhang, Zai-Teng;Oh, Won-Chun
    • Korean Journal of Materials Research
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    • v.30 no.6
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    • pp.279-284
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    • 2020
  • In this work, a carbon-doped carbon nitride photocatalyst is successfully synthesized through a simple centrifugal spinning method after heat treatment. The morphology and properties of the prepared photo catalyst are characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), UV-vis spectrophotometer (UV-vis), and specific surface area. The results show that the band gap of the prepared sample, g-CN-10 is 2.1 eV, is significantly lower than that of pure carbon nitride, 2.7 eV. As the amount of cotton candy increased, the absorption capacity of the prepared catalyst for visible light is significantly enhanced. In addition, the degradation efficiency of Rhodamine B (RhB) by sample g-CN-10 is 98.8 % over 2 h, which is twice that value of pure carbon nitride. The enhancement of photocatalytic ability is attributed to the increase of specific surface area after the carbon doping modifies carbon nitride. A possible photocatalytic degradation mechanism of carbon-doped carbon nitride is also suggested.