• Title/Summary/Keyword: Carbon dioxide treatment

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Adsorption Characteristics of Methane and Carbon Dioxide in Zeolite with Flexible Framework (유연한 구조체를 가지는 제올라이트에서 메탄과 이산화탄소의 흡착 특성)

  • Yang Gon Seo
    • Clean Technology
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    • v.30 no.3
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    • pp.248-257
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    • 2024
  • Carbon dioxide is an undesired component of biogas and landfill gas. As a result, it needs to be removed from these mixtures in order to increase their heating value and reduce corrosion during treatment. Zeolites are a class of microporous materials that can be used as adsorbents for the separation of carbon dioxide from gas mixtures. In this work, the pure gas adsorption isotherms of methane and carbon dioxide and the selectivity of their mixture onto LTA-4A, FAU-13X and FAU-NaY adsorbents at temperatures of 273, 298 and 323 K and pressures up to 30 bars were calculated by the Monte Carlo method. Also, the influence of a flexible framework in a set of zeolites on the separation of methane and carbon dioxide was studied. Carbon dioxide adsorption onto the zeolites used in this work was more favorable than methane adsorption. The FAU-13X adsorbent had the highest adsorption capacity among the studied adsorbents. However, the selectivity of carbon dioxide over methane for LTA-4A was the highest. The adsorption capacities of a rigid framework were higher than those of a flexible framework. The influence of the framework flexibility in FAU on adsorption capacity was small. In contrast, its influence on selectivity seemed to be much larger.

Production of Acetate from Carbon Dioxide in Bioelectrochemical Systems Based on Autotrophic Mixed Culture

  • Su, Min;Jiang, Yong;Li, Daping
    • Journal of Microbiology and Biotechnology
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    • v.23 no.8
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    • pp.1140-1146
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    • 2013
  • Bioelectrochemical systems (BESs) have been suggested as a new technology for wastewater treatment while accomplishing energy and chemical generation. This study describes the performance of BESs based on mixed culture that are capable of reducing carbon dioxide to acetate. The cathode potential was a critical factor that affected the performance of the BESs. The rate of acetate production increased as the electrode potential became more negative, from 0.38 mM $d^{-1}$ (-900 mV vs. Ag/AgCl) to 2.35 mM $d^{-1}$ (-1,100 mV), while the electron recovery efficiency of carbon dioxide reduction to acetate increased from 53.6% to 89.5%. The microbial population was dominated by relatives of Acetobacterium woodii when a methanogenic inhibitor was added to the BESs initially.

The activation of PPAR-α and Wnt/β-catenin by Paeonia lactiflora root supercritical carbon dioxide extract

  • Kim, Bora
    • Journal of the Korean Applied Science and Technology
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    • v.36 no.4
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    • pp.1136-1142
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    • 2019
  • The root of Paeonia lactiflora has been used in Chinese medicine. We conducted to check the comparative qualities of ethanol solvent extraction (PLE) and supercritical carbon dioxide extraction (PLS) of P. lactiflora root. PLE had higher antioxidant and polyphenol contents than PLS. But, PLS were significantly increased peroxisome proliferator-activated receptor (PPAR)-α. In addition, PLS inhibited the adipocyte differentiation of 3T3-L1 cells. When treated with the extract at a concentration of 100 ㎍/mL, the Wnt/β-catenin pathway reporter luciferase activity of HEK 293-TOP cells increased approximately by 3-folds compared to that of the untreated control group. These results indicate that P. lactiflora supercritical carbon dioxide extract may serve as a cosmeceutical for improving skin barrier function and the treatment of obesity.

The Activation of PPAR-α and Wnt/β-catenin by Luffa cylindrica Supercritical Carbon Dioxide Extract

  • Kim, Bora
    • Natural Product Sciences
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    • v.25 no.4
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    • pp.341-347
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    • 2019
  • Luffa cylindrica (LC) is a very fast-growing climber and its fruit have been considered as agricultural wastes. We conducted to check the comparative qualities of ethanol solvent extraction (LCE) and supercritical carbon dioxide extraction (LCS) of L. cylindrica fruit and seed. LCS had higher antioxidant and polyphenol contents than LCE. LCS were significantly increased peroxisome proliferator-activated receptor (PPAR)-a and involucrin expression as epidermal differentiation marker in 3D skin equivalent model. LCS also showed antimicrobial activity against Staphylococcus aureus, a causative bacteria in atopic dermatitis. In addition, LCS inhibited the adipocyte differentiation of 3T3-L1 cells. When treated with the extract at a concentration of 100 ㎍/mL, the Wnt/β-catenin pathway reporter luciferase activity of HEK 293-TOP cells was increased approximately by 2-folds compared to that of the untreated control group. These results indicate that L. cylindrica supercritical carbon dioxide extract may serve as a cosmeceutical for improving skin barrier function and the treatment of obesity.

Analysis of the Optimal Thickness and the Heat Transmission for the Triple Glazing System with Vacuum and Carbon Dioxide Gaps (진공 및 이산화탄소 삼중유리 시스템의 최적 두께 및 열관류율 분석)

  • Baek, Sang-Hoon
    • Land and Housing Review
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    • v.11 no.3
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    • pp.61-68
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    • 2020
  • Advanced glazing systems with excellent heat transmission values (Ug-Value) have been developed to reduce the energy consumption and the greenhouse gas emission. This study proposes a triple glazing system consisting of gaps with a vacuum and a carbon dioxide gas layer which is one of greenhouse gases. As a fundamental stage, this study is focused on calculating the optimal glazing thickness and the Ug-Value via a computer simulation, Therm & Window package. As the results, it was presented that the optimal thickness of the proposed triple glazing system is 22.2 mm, and the Ug-Value is 0.273 W/㎡·K. If this glazing system is to be applied to buildings, it could not only reduce building energy consumption but could also contribute to the treatment of carbon dioxide gas which is one of greenhouse gases.

Particle Separation and Flotation Efficiency by Dissolved Carbon Dioxide Flotation Process (용존이산화탄소부상(DCF) 공정의 입자분리 특성과 부상효율)

  • Kwak, Dong-Heui;Kim, Seong-Jin;Jung, Heung-Jo;Park, Yang-Kyun;Yoo, Young-Hoon;Lee, Young-Dong
    • Journal of Korean Society of Water and Wastewater
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    • v.25 no.4
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    • pp.471-478
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    • 2011
  • A series of laboratory experiments carried out to investigate the particle separation efficiency and flotation characteristics using $CO_2$ bubbles. The primary objective of this study was to find out the feasibility of $CO_2$ bubbles as an applicable unit of flotation process in tap-water and wastewater treatment plant. The fundamental measurements were conducted to characterize the $CO_2$ bubble from the physical viewpoint in water including bubble size distribution and rising velocity under various operational conditions. In addition, the removal efficiency of solid was experimented using the lab scale plant applied $CO_2$ bubbles, namely the dissolved carbon dioxide flotation (DCF) process. The DCF process using carbon dioxide bubble, which is an advantage as the decrease and the reuse of Green-House gas, can be a promising technology as an water treatment process. On the other hand, the further research to decrease the bubble size distribution of $CO_2$ is required to enhance the particle separation efficiency.

Post Treatment Application of Jaungo after a Combined Therapy of Carbon Dioxide Laser and Trichloroacetic Acid in a Case of Vulvar Syringoma

  • Kim, En Hyung;Kim, Wonnam
    • Journal of Pharmacopuncture
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    • v.22 no.3
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    • pp.200-203
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    • 2019
  • Syringoma is a benign eccrine sweat gland tumor that predominantly appears in females during puberty with multiple smooth papules measuring 1-2 mm in diameter. Common locations are on lower eyelids and cheeks. Vulvar syringoma is quite a rare, occurring condition with only a few cases reported. Here, we are reporting a case of 31-year-old female with vulvar syringoma associated with pruritus. The lesion was treated with carbon dioxide (CO2) laser ablation and 50% trichloroacetic acid (TCA) chemical peeling. Jaungo was used for wound care after laser abrasion. The combination treatment was effective for removing syringoma lesions. Post laser management with fusidic acid cream and jaungo cream was sufficient to prevent infection and promote wound healing.

Biodegradation of Ethylene in an Activated Carbon Biofilter

  • Kim, Jong-O;Chung, Il-Hyun
    • Journal of Korean Society for Atmospheric Environment
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    • v.18 no.E2
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    • pp.79-84
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    • 2002
  • The objective of this study was to investigate the biodegradation of ethylene in an activated carbon biofilter inoculated with immobilized microbial consortium. The biofilter performance was monitored in terms of ethylene removal efficiency and carbon dioxide production. The biofilter was capable of achieving ethylene removal efficiency as much as 100% at a residence time of 14 min and an inlet concentration of 290 ppm. Under the same conditions, carbon dioxide with a concentration of up to 546 ppm was produced. Its was found that carbon dioxide was produced at a rate of 87 mg day$\^$-1/, which corresponded to a volume of 0.05 L day$\^$-1/. During operation with an inlet ethylene of 290 ppm, the maximum elimination capacity of the biofilter was 34 g of C$_2$H$_4$m$\^$-3/ day$\^$-1/. The biofilter could provide an attractive treatment technology for removing ethylene, an extremely volatile and slowly adsorbed compound.

A study on the corrosion control of tap water by lime and carbon dioxide (소석회와 이산화탄소를 이용한 수돗물 부식성 제어에 관한 연구)

  • Cheong, Won-Suk;Kim, Jin-Keun;Park, Duk-Joon;Kim, Sun-Wook;Jeong, Sang-Gi
    • Journal of Korean Society of Water and Wastewater
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    • v.25 no.2
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    • pp.193-199
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    • 2011
  • A method to improve internal corrosion control efficiency by adding lime and carbon dioxide, which, in turn increases the Langelier Index (LI) for filtered water at a conventional drinking water treatment plant (WTP) was investigated. The SJ WTP (Q=100,000 $m^{3}$/d) has been operating an internal corrosion control system since 2006. The system has achieved stable operation through technical development and trial and error over a period of several years. As a result of the operation, the LI of treated water has increased up to 29% by adjusting pH of filtered water to 7.8 with the addition of lime and carbon dioxide. Coupon tests in the distribution system indicated that the corrosion rate has been delayed by 24% when the internal corrosion method was implemented. The increase of LI by lime and carbon dioxide has been proven to be a practical method for controlling corrosion.

Carbon Dioxide Sequestration of Enzyme Covalently Immobilized on Porous Membrane (공유결합으로 다공성 막에 고정화된 효소에 의한 이산화탄소 포집)

  • Park, Jin-Won
    • KSBB Journal
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    • v.28 no.4
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    • pp.225-229
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    • 2013
  • Bovine Carbonic anhydrase (BCA) was immobilized on a submicro-porous membrane through covalent immobilization. The immobilization was conducted on the porous membrane surface with the treatment of polyethyleneimine, glutaraldehyde, and the anhydrase, in sequence. The immobilization was confirmed using X-ray photon spectrometer. The pH values of carbon-dioxide saturated solution with buffer were monitored with respect to time to calculate the catalytic activities of hydration of carbon-dioxide for free and immobilized CA. The catalytic rate constant values for free CA, immobilized CA on polystyrene nanoparticles, and immobilized CA on a porous cellulose acetate membrane were 0.79, 0.67, and 0.56 $s^{-1}$, respectively. Reusability was studied up to 10 cycles of $CO_2$ sequestration. The activity for the CA immobilized on the membrane was kept to 95% after 10 cycles, and comparable to the CA on the nanoparticles. The stabilities for heat and storage were also investigated for the three cases. The results suggested that the CA immobilized the membrane had the least loss rate of the activity compared to the others. From this study, the porous membrane was feasible as a carrier for the CA immobilization in hydration and sequestration of carbon-dioxide.