• Journal of the Korean Society for Marine Environment & Energy
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• 제15권2호
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• pp.67-75
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• 2012

Carbon-dioxide capture and storage (CCS) process is consisted by capturing carbon-dioxide from large point source such as power plant and steel works, transporting and sequestrating captured $CO_2$ in a stable geological structure. During CCS process, it is inevitable of introducing impurities from combustion, capture and purification process into $CO_2$ stream. Impurities such as $SO_2$, $H_2O$, CO, $N_2$, Ar, $O_2$, $H_2$, can influence on process efficiency, capital expenditure, operation expense of CCS process. In this study, experimental apparatus is built to simulate the behavior of $CO_2$ transport under various impurity composition and process pressure condition. With this apparatus, $N_2$ impurity effect on $CO_2$ mixture transportation was experimentally evaluated. The result showed that as $N_2$ ratio increased pressure drop per mass flow and specific volume of $CO_2-N_2$ mixture also increased. In 120 and 100 bar condition the mixture was in single phase supercritical condition, and as $N_2$ ratio increased gradient of specific volume change and pressure drop per mass flow did not change largely compared to low pressure condition. In 70 bar condition the mixture phase changed from single phase liquid to single phase vapor through liquid-vapor two phase region, and it showed that the gradient of specific volume change and pressure drop per mass flow varied in each phase.

• Journal of the Korean Society for Marine Environment & Energy
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• 제16권1호
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• pp.9-16
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• 2013

An experiment was conducted to evaluate the biochemical adverse effect of increased carbon dioxide in seawater on marine polychaete, Perinereis aibuhitensis. We measured the available energy reserves, Ea (total carbohydrate, protein, and lipid content) and the energy consumption, Ec (electron transport activity) of Perinereis aibuhitensis exposed for 7-d to a range of $CO_2$ concentration such as 0.39 (control =390 ppmv), 3.03 (=3,030 ppmv), 10.3 (=10,300 ppmv), and 30.1 (=30,100 ppmv) $CO_2$ mM, respectively. The cellular energy allocation (CEA) methodology was used to assess the adverse effects of toxic stress on the energy budget of the test organisms. The results of a decrease in CEA effect of increased carbon dioxide in seawater from all individual in Ea and Ec. Increase of carbon dioxide reduced pH in seawater, significantly. The chemical changes in sea- water caused by increasing $pCO_2$ might cause stresses to test organisms and changes in the cellular energy allocations. Results of this study can be used to understand the possible influence of $CO_2$ concentration increased by the leakage from sub-sea bed storage sites as well as fossil fuel combustion on marine organisms.

• 한국전산유체공학회:학술대회논문집
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• 한국전산유체공학회 2009년 춘계학술대회논문집
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• pp.196-201
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• 2009

Global warming issues due to the $CO_2$(Carbon Dioxide) become increasing since the Industrial Revolution. After the Kyoto protocol at 1997, nations which have the prearranged quota drives their national project for the reduction of $CO_2$. Korean Government start to the related big projects in the view of three concepts which have consist of the $CO_2$ exhaust reduction on land, $CO_2$ capture and $CO_2$ storage. Furthermore, the storage method putting into depleted region underground is accepted by the London Convention while the ocean diluted method discharging the liquid $CO_2$ into the deep ocean using the long pipe which is towed by the surface vessel is underway for the research steps which means that there are many potentials for the R&Ds that need for the breakthrough. In this paper, the role and example of the Computational Fluid Dynamics for the feasibility study of the $CO_2$ ocean sequestration is mentioned.

• Proceedings of the KAIS Fall Conference
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• 한국산학기술학회 2010년도 추계학술발표논문집 1부
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• pp.491-494
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• 2010

지구온난화의 주범인 온실가스 중 이산화탄소 농도 증가에 따라 현재 전 세계적으로 사회적, 환경적, 경제적으로 피해가 나타나고 있다. 그래서 CCS연구를 적용하여 이산화탄소를 포집하는 연구가 활발하게 진행 되고 있으나 분리, 수송, 저장 등의 추가적인 비용이 발생하는 문제점을 가지고 있다. 본 논문은 생체촉매효소를 이용하여 이산화탄소를 포집하는 연구를 하였다. 반응온도, pH, 이산화탄소 농도 등의 변수를 이용한 생체촉매효소의 활성평가, 반응속도, 광물화의 특성에 관하여 연구하였다.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• 제28권12호
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• pp.489-494
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• 2016

There have been many cases when an air curtain installed in the apartment could not remove the gases well, such as carbon dioxide and particles like as smoke, oils, and vapors generated during cooking to disperse pollutants into the room. This study used a numerical analysis to show how the pollutant-removing performance of the range hood is changed when the air curtain is installed front of the kitchen table. The result of this study was that when the air amount supplied by an air curtain through the slot was about 50% of the exhaust amount, the capturing efficiency of the range hood for pollutants increased 90% more than without an air curtain. Even when the amount of supplied air was small, the capturing efficiency improved markedly with the use of an upward air curtain. In case that the air flow rate of the slot was greater than 60%, the capturing efficiency decreased.

• Journal of Energy Engineering
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• 제13권3호
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• pp.219-227
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• 2004

World have been encouraged to develop technologies that contribute to CO$_2$ emission reduction for many years. Those technologies can be categorized into capture, storage or sequestration, utilization, etc. There have been lots of efforts, in Korea, to develop the technology as well. In this paper, the impact factors of the technologies, especially in CDRS (Carbon Dioxide Reduction & Sequestration Center), were selected and were weighed by SMM (Storing Models Method) and AHP (Analytic Hierarchy Process) in order to evaluate the four representative areas of the technologies.

• Journal of Korean Society of Environmental Engineers
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• 제37권11호
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• pp.597-606
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• 2015

This work investigates the carbonation of KOH-dissolved methanol and ethanol solution systems carried out for $CO_2$ fixation. Potassium methyl carbonate (PMC) and potassium ethyl carbonate (PEC) were synthesized during the reaction in each solution as the solid powder, and they were characterized in detail. The amount of $CO_2$ chemically absorbed to produce the PMC and PEC precipitates were calculated to be 97.90% and 99.58% of their theoretical values, respectively. In addition, a substantial amount of $CO_2$ was physically absorbed in the solution during the carbonation. PMC precipitates were consisted of the pure PMC and $KHCO_3$ with the weight ratio of 5:5, respectively. PEC precipitates were also mixture of the pure PEC and $KHCO_3$ with the weight ratio of 8:2, respectively. When these two precipitates were dissolved in excess water, methanol and ethanol were regenerated remaining solid $KHCO_3$ in the solutions. Therefore, the process has the potential to be one of the efficient options of CCS and CCU technologies.

• Korean Chemical Engineering Research
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• 제56권3호
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• pp.335-342
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• 2018

Various technologies to cope with the energy and environmental issues related to the chemical and electric power industry are in development and demonstration stage. Especially, the absorption process of carbon dioxide ($CO_2$) using amine solution is a key technology of the $CO_2$ capture and storage (CCS). In this study, we identify the major risk factors and suggest strategies for safety improvement by analyzing and assessing commercial the amine-based $CO_2$ separation process. HAZOP method was used to assess the risk for the process. We provide facilities and operational strategies to mitigate or eliminate major risk factors by assessing the relative ranks of identified risk factors using a risk matrix.

• International Journal of Highway Engineering
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• 제15권2호
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• pp.95-103
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• 2013

PURPOSES : To investigate the fundamental characteristics of blast-furnace slag mortar that was hardened with activating chemicals to capture and sequester carbon dioxide. METHODS : Various mix proportions were considered to find an appropriate stregnth development in regards with various dosages of activating chemicals, calcium hydroxides and sodium silicates, and curing conditions, air-dried, wet and underwater conditions. Flow characteristics was investigated and setting time of the mortar was measured. At different ages of 3, 7 and 28days, strength development was investigated for all the mix variables. At each age, samples were analyzed with XRD. RESULTS : The measured flow values showed the mortar lost its flowability as the activating chemicals amount increased in the scale of mole concentration. The setting time of the mortar was relatively shorter than OPC mortar but the initial curing condition was important, such as temperature. The amount of activating chemicals was found not to be critical in the sense of setting time. The strength increased with the increased amount of chemicals. The XRD analysis results showed that portlandite peaks reduced and clacite increased as the age increased. This may mean the $Ca(OH)_2$ keeps absorbing $CO_2$ in the air during curing period. CONCLUSIONS : The carbon capturing and sequestering activated blast-furnace slag mortar showed successful strength gain to be used for road system materials and its carbon absorbing property was verified though XRD analysis.

• Clean Technology
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• 제21권2호
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• pp.124-129
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• 2015

The constant-volume method was used to determine the solubility of CO₂ in various physical absorbents such as DMPEG (dimethyl ether of polyethylene glycol), DEC (diethyl carbonate), DMC (dimethyl carbonate), and TAT (triacetin) in the total pressure range from 5 to 30 bar. The Peng-Robinson equation of state has been used to describe the equilibrium behavior of these mixtures. It was found that the solubility of absorbents was in the of DMPEG250 > TAT > DEC > DMC at the same temperature. Futhermore, the solubiity of blended absorbent of DMPEG250 and DEC is higher than that of DMPEG 250 alone. Therefore, blended absorbent of DMPEG250 and DEC is expected to be an effective and low cost absorbent for physical absorption in precombustion CO₂ capture.