• Journal of the Korea Academia-Industrial cooperation Society
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• v.11 no.11
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• pp.4643-4648
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• 2010

In this study, $CO_2$ absorption properties at high pressure condition that can apply pre-combustion $CO_2$ capture were investigated for physical sorbent such as PEG, DMSO, and Sulfone. The $CO_2$ Solubility, regeneration, and initial absorption rate with temperature and pressure were measured using batch type stirred cell contactor. The PEG showed the highest $CO_2$ solubility and initial absorption rate. It can be found that all the physical sorbents used in this experiments were almost completely regenerated at various temperature and pressure.

• Korean Chemical Engineering Research
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• v.47 no.4
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• pp.410-417
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• 2009

Carbon dioxide was absorbed into GMA solution in a stirred flat cell using mesoporous catalyst Imidazole-CP-MS41, which was synthesized by CP-MCM41 with imidazole. Experiments were carried out at a batch-type absorber with different conditions, varying reaction temperature, concentration of GMA, solvent but maintaining 50 rpm of agitation speed and 2 g of catalyst. Absorption rate of $CO_2$ was used to obtain the kinetics based on the film theory using zwitterion mechanism with 2 elementary reaction and the kinetics were correlated with the solubility parameter of the solvents.

• Spatial Information Research
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• v.20 no.5
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• pp.1-13
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• 2012

This study intends to evaluate the seasonal flow direction of carbon dioxide in Northeast Asia by using GOSAT, the first Greenhouse Observing SATellite, in an attempt to overcome costly, laborious and time consuming ground observation which has been frequently pointed out in existing studies. For this purpose, missing values were supplemented by applying the Kriging interpolation and the overall flow direction of carbon dioxide was determined through anisotoropy semi-variogram. As a result, it was found that the overall spatial distribution of carbon dioxide in Northeast Asia varies depending on the latitude, and that carbon dioxide mainly flows southeast or east in spring, autumn and winter, but northeast or north in summer. Similar to the flow of monsoons in Northeast Asia, these results show that carbon dioxide flows mainly from the west to the east, which proves that carbon dioxide discharged from China is influencing even the Korean Peninsula and Japan. However, as the flow of carbon dioxide varies depending on a variety of factors such as artificial sources, plant respiration, and the absorption and discharge of the ocean, follow-up studies are requested to evaluate such variables and the correlations.

• Journal of Multimedia Information System
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• v.6 no.3
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• pp.155-164
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• 2019

We intended to confirm that microwave attenuation by tree leaves is strongly linked to water content in leaves. We sampled natural broadleaves, including Japanese cinnamon, and investigated their effects on the microwave (3 to 20 GHz) frequency characteristics using a network analyzer. Experiments determined that microwave attenuation by foliage increases as a linear function of frequency per unit weight (gram). As the frequency increases, the spatial resolution increases, but the phase difference (imaginary component) increases. So we solved the dispersion of phase difference by sweeping the frequency and taking the intermediate value. Based on these experimental results, we developed a microwave scanner on 10Ghz to describe foliage moisture as a image and to enable assessments of leaf condition. Photosynthesis is the process whereby plants synthesize oxygen and sugars from carbon dioxide and water, thereby converting light energy into chemical energy. Since water is a major parameter of photosynthesis, the quantity of water accumulated inside a leaf reflects leaf health. The equipment described here and related microwave technologies will help assess the capacity of leaves to absorb atmospheric carbon dioxide.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.22 no.3
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• pp.763-769
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• 2021

In this study, ionic liquids were synthesized to remove carbon dioxide (CO2) on a laboratory scale. The vapor-liquid absorption equilibrium device (VLE) was used to investigate the carbon dioxide absorption capacity. In the regeneration study, the absorption capacity after regeneration was reduced by approximately 7% for all ionic liquids, in which the anion was sulfite-based, showing excellent regeneration. Ethyl sulfite showed the highest absorption capacity of CO2 among the ionic liquids based on the sulfite anion. In particular, the absorption capacity of [beim] ethyl sulfite was 1.1 mol CO2 / mol IL at an absorption equilibrium pressure of 22 bar. In the regeneration study, the absorption capacity after regeneration was reduced by approximately 7% for all ionic liquids, in which the anion was sulfite-based, from which regeneration is outstanding. After the absorption experiment, the viscosity of the sample tended to decrease by approximately 8% compared to that before the absorption experiment. On the other hand, the absorbent was synthesized in the first step. Moreover, the raw material used is also inexpensive and has excellent reproducibility and highly stable absorbent capacity.

• Journal of Chest Surgery
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• v.25 no.12
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• pp.1399-1403
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• 1992

The evaluation of the effectivess of ongoing cardiopulmonary resucitation efforts is dependent on the commonly used methods, such as the presence of femoral or carotid artery pulsations, arterial blood gas determinations, peripheral arterial pressure and intracardiac pressure monitoring. But recent studies suggest that end-tidal carbon dioxide tension serves as a non-invasive measurement of pulmonary blood flow and therefore cardiac output under constant ventilation. A prospective clinical study was done to determine whether end-tidal carbon dioxide monitoring in open heart surgery under cardiopulmonary bypass could be used as a prognostic indicator of bypass weaning. We monitored end-tidal PCO2 values continuously during cardiopulmonary bypass in 30 patients. "Ohmeda 5210 CO-2 monitor" under infrared absorption method were incorperated into the ventilator circuit by means of a side point adaptor between endotracheal tube and ventilator tubing. 18 patients[Group I ] were res-ucitated from partial bypass followed by aorta cross clamp off and 12 patients[Group II ] from aorta cross clamp off followed by partial bypass. But there was no difference between two groups[p>0.05]. The value of end-tidal carbon dioxide tension during ventricular fibrillation or nearly arrest state was 6.6$\pm$2.9 mmHg, and at the time of spontaneous beating was 19.3$\pm$5.6 mmHg[Mean$\pm$Standard deviation], In conclusion end-tidal carbon dioxide tension monitoring provides clinically useful, continous, noninvasive and supplementary prognostic indicator during cardiopulmonary bypass weaning procedures.rocedures.

• Clean Technology
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• v.18 no.2
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• pp.221-225
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• 2012

In this study, simulation works for a carbon dioxide capture process using solvent absorption method have been performed for decrease of regeneration energy in applying phase transition of liquid solvent. When carbon dioxide is dissolved in 30 wt% MEA solvent, liquid mixture divided into two phase according to mole loading of dissolved carbon dioxide. Using this phenomenon, we can decrease regeneration energy about 61% than primary absorber column-stripper column process.

• Korean Chemical Engineering Research
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• v.50 no.1
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• pp.128-134
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• 2012

The pilot scale experiments can handle the flue gas up to 1,000 $Nm^3/hr$ for separation of carbon dioxide included in real flue gas at coal-fired power plant. The operational characteristics was analyzed with the main experimental variables such as flue gas flow rate, absorbent circulation rate using chemical absorbents mono-ethanolamine( MEA) and 2-amino-2-methyl-1-propanol(AMP). The more flue gas flow rate decreased in 100 $m^3/hr$ in the MEA 20 wt% experiments, the more carbon dioxide removal efficiency was increased 6.7% on average. Carbon dioxide removal efficiency was increased approximately 2.8% according to raise of the 1,000 kg/hr absorbent circulation rate. It also was more than 90% at $110^{\circ}C$ of re-boiler temperature. Carbon dioxide removal efficiency of the MEA was higher than that of the AMP. In the MEA(20 wt%) experiment, carbon dioxide removal efficiency(85.5%) was 10% higher than result(75.5%) of ASPEN plus simulation.

• Applied Chemistry for Engineering
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• v.23 no.6
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• pp.624-629
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• 2012

To capture and recover carbon dioxide ($CO_2$), we impregnated honeycomb made of ceramic paper with $K_2CO_3$ and its absorption characteristics of $CO_2$ were investigated. The absorption amount of $CO_2$ on the honeycomb absorbent impregnated with $K_2CO_3$ was 13.8 wt% at a constant temperature ($70^{\circ}C$) and relative humidity (66%) condition. Because the absorption amount of $CO_2$ achieved almost the same loading ratio of $K_2CO_3$ (17.6 wt%), the absorption reaction of $CO_2$ by $K_2CO_3$ on the honeycomb absorbent seems to be going smoothly. In addition, $CO_2$ absorption breakthrough characteristics of the honeycomb absorbent were analyzed at the temperature range of $50{\sim}80^{\circ}C$, and the water vapor was fed to an absorption column before the feeding of $CO_2$ or simultaneously with $CO_2$. As a result, the absorption capacity of $CO_2$ was more enhanced using the water vapor supplying before $CO_2$ than that of simultaneous supplying. It was confirmed by temperature programmed desorption analysis that the $KHCO_3$ produced by the absorption reaction of $K_2CO_3$ and $CO_2$ is regenerated by the desorption of $CO_2$ at a temperature of about $128^{\circ}C$.

• Bulletin of the Korean Chemical Society
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• v.33 no.7
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• pp.2325-2332
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• 2012

A series $[C_3Omim]$[X] of imidazolium cation-based ILs, with ether functional group on the alkyl side-chain have been synthesized and structure of the materials were confirmed by various techniques like $^1H$, $^{13}C$ NMR spectroscopy, MS-ESI, FTIR spectroscopy and EA. More specifically, the influence of changing the anion with same cation is carried out. The absorption capacity of $CO_2$ for ILs were evaluated at 30 and $50^{\circ}C$ at ambient pressure (0-1.6 bar). Ether functionalized ILs shows significantly high absorption capacity for $CO_2$. In general, the $CO_2$ absorption capacity of ILs increased with a rise in pressure and decreased when temperature was raised. The obtained results showed that absorption capacity reached about 0.9 mol $CO_2$ per mol of IL at $30^{\circ}C$. The most probable mechanism of interaction of $CO_2$ with ILs were investigated using FTIR spectroscopy, $^{13}C$ NMR spectroscopy and result shows that the absorption of $CO_2$ in ether functionalized ILs is a chemical process. The $CO_2$ absorption results and detailed study indicates the predominance of 1:1 mechanism, where the $CO_2$ reacts with one IL to form a carbamic acid. The $CO_2$ absorption capacity of ILs for different anions follows the trend: $BF_4$ < DCA < $PF_6$ < TfO < $Tf_2N$. Moreover, the as-synthesized ILs is selective, thermally stable, long life operational and can be recycled at a temperature of $70^{\circ}C$ or under vacuum and can be used repeatedly.