• Applied Chemistry for Engineering
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• v.4 no.2
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• pp.365-372
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• 1993

$CO_2$ methanation was performed over Ni supported on cation-exchanged Y zeolites under atmospheric pressure at $250{\sim}550^{\circ}C$ and $H_2/CO_2$ mole ratio of 4. Adsorption strength between carbon dioxide and nickel was found to be Influenced by the cation exchanged in the zeolite. TPD(Temperature-programmed desorption) results show that the adsorption strength decreases in the order of Ni/NaY>Ni/MaY>Ni/HY. TPSR(Temperature-programmed surface reaction) results indicate that enhanced methanation activity is obtained when the adsorption strength between carbon dioxide and nickel is stroing. As the reduction temperature increases, the methantion activity of the catalyst increase. From this result the larger size nickel particle seems advantageous for $CO_2$ methanation reaction. The maximum activity is obtained when nickel loading is 3.3wt%. Carbon monoxide is produced as a by-product throughout the reaction temperature range, and as the contact time increases, the selectivity to methane increases and the selectivity to carbon monoxide decreases steadily. Thus methane seems to be produced from $CO_2$ via CO as an intermediate species. In the temperature range of $410{\sim}450^{\circ}C$, the methane production rate is found to be dependent on the orders of 3.3~-0.5 and 1.4~3.6 with respect to $CO_2$ and $H_2$ partial pressures, respectively. This clearly shows that $CO_2$ and $H_2$ are competing for adsorption sites and as the reaction temperature increases, it becomes increasingly difficult for $H_2$ to be adsorbed on the catalyst surface.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2022.11a
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• pp.127-128
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• 2022

In order to realize carbon neutrality in the international society, research on supplementary cementitious materials(SCMs) has been actively conducted as a way to reduce carbon dioxide emissions in the cement industry. However, the use of SCMs causes problems of initial hydration delay and strength reduction due to the reduction of tricalcium silicate(C3S) in the cement clinker. Therefore, in this study, the initial hydration and basic characteristics of cement mortar were confirmed by adding a C-S-H based hardening acceleration to blended cement mixed with Portland cement, blast furnace slag, fly ash, and limestone power. As a result of the heat of hydration and compressive strength test, it was confirmed that when hardening acceleration was added, the initial reactivity was high, so the heat of hydration was promoted, and the initial strength was increased. It is considered to be due to C-S-H seeding effect. Therefore, it is judged that the use of C-S-H based hardening acceleration can supplement the problem of initial hydration delay of blended cement in Korea.

• Journal of the Society of Naval Architects of Korea
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• v.61 no.2
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• pp.135-142
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• 2024

There is a lot of concern around the world about air pollution from ships. The majority of air pollution from ships comes from fuel combustion. The combustion process produces various air pollutants such as carbon monoxide (CO), carbon dioxide (CO₂), nitrogen oxides (NOx), sulfur oxides (SOx), and particulate matter (PM), each of which has adverse effects on people and is a major environmental problem. To prevent this, the International Maritime Organization (IMO) has strengthened the regulation of pollutant emissions through the Convention for the Prevention of Marine Pollution. This paper discusses the types of air pollutants emitted by ships, their current status, and the latest technologies to reduce emissions of NOx and SOx.

• Journal of Navigation and Port Research
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• v.48 no.2
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• pp.97-103
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• 2024

As there is growing concern about the environmental impact of greenhouse gas emissions from ships, the International Maritime Organization (IMO) has introduced several regulations targeting reductions in carbon dioxide emissions of 50% by 2050. This study pays particular attention to the carbon intensity indicator (CII) and investigates the impact of slow steaming, one of the short-term measures in the regulation, on containership operations. To this end, a dataset of 8 containerships with various ages and sizes was collected. Based on operation data in 2021, the CII ratings of the containerships were estimated in the business-as-usual scenario for the 2023-2030 period. Then, the speed reductions required to keep the minimum CII rating were calculated for individual containerships. Finally, working day losses resulting from the speed reductions were calculated. The findings in this study were threefold. First, it was found that containerships will undergo degradation in the CII rating every 3 or 4 years without slow steaming. Second, a speed reduction of 2 knots between 2023 and 2030 is required to keep the minimum CII rating. Finally, speed reductions result in the loss of as many as 6 or 7 working days per year.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.35 no.3
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• pp.308-310
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• 2022

Ultrawide bandgap gallium oxide (Ga₂O₃) semiconductors are known to have excellent photocatalytic properties due to their high redox potential. In this study, CO₂ reduction is demonstrated using nanostructured Ga₂O₃ photocatalyst under ultraviolet (254 nm) light source conditions. After the CO₂ reduction, C₂H₄ remained as a by-product in this work. Nanostructured Ga₂O₃ photocatalyst also showed an excellent endurance characteristic. Photogenerated electron-hole pairs boosted the CO₂ reduction to C₂H₄ via nanostructured Ga₂O₃ photocatalyst, which is attributed to the ultrawide and almost direct bandgap characteristics of the gallium oxide semiconductor. The findings in this work could expedite the realization of CO₂ reduction and a simultaneous C₂H₄ production using a low cost and high performance photocatalyst.

• Applied Chemistry for Engineering
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• v.8 no.4
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• pp.685-693
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• 1997

We have studied the reforming of carbon dioxide with methane over various supported nickel catalysts. The nickel supported on natural zeolite showed the highest activity and the nickel on acidic support showed higher activity and slow deactivation compared to nickel on basic support. The activity of nickel on natural zeolite increased with increasing loading ratio and showed almost constant activity above 10wt.% loading of nickel. The conversion and yield of products were affected by the mole ratio of reactants and the highest yields of CO and $H_2$ were obtained at $CH_4/CO_2=1$. The deactivation of catalyst was caused by deposition of coke which was formed by the decomposition of methane. The shape of coke was shown to be whisker tripe carbon, and it brought out the slow deactivation of catalyst.

• Land and Housing Review
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• v.3 no.4
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• pp.399-406
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• 2012

One-third of total energy and 50% of $CO_2$ emissions arise from construction phase. Because of this global amount of energy consumption and $CO_2$ emission, we must do our best to solve this problem. But our existing ways of meeting this problem has focused on the energy consumption saving of the construction and dwelling stage. On the other hand, we has been treated too lightly for handling the $CO_2$ emissions problem during the maintenance management and the demolition process so far,. In this paper, we quantitatively predicted and evaluated the environmental load in each construction step during all life cycle. And, we developed the environmental load assessment program for each construction step. And we proposed the reliable decision support model for objective and reliable environmental load assessment and reduction. This result must help the development of construction technology and low carbon & green growth.

• Journal of the Korean Solar Energy Society
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• v.30 no.6
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• pp.131-136
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• 2010

The purpose of this study is to provide foundational data for expansion of solar generation in building application, a clean energy, by introducing applicability of solar power generation system on roofs of industrial buildings and computing expected amounts of power and carbon dioxides reduction. As methodologies of this study, after reviewing 120,000 domestic factories to verify the BIPV feasibility for industrial building sthrough theoretical considerations of solar generation system, we calculated BIPV application methods and subsequent expected power generation quantity and carbon dioxide reductions through roof type analysis. we analyzed four cases of expected power generation amounts of solar batteries according to application methods, and when considering that the main type of roofs are slant roofs according to the investigation result about roof forms of domestic industrial complexes, we believe that the module angle of a slant roof around $17^{\circ}$(case3) is most suitable for the application. Finally, we came up with 517,944[TOE] as the corresponding petroleum tonnage based on this computed expected power generation amount and the amount of 1,214,836[$tCO_2$] carbon dioxide reductions by calculating them by energy sources.

• Journal of Electrical Engineering and Technology
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• v.13 no.1
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• pp.114-123
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• 2018

Recently, as one of the countermeasures to reduce carbon dioxide($CO_2$) for global warming problems, operation methods in micro-grid systems replacing diesel generator with renewable energy sources including wind power(WP) and photovoltaic(PV) system have been studied and presented in energetic manners. However, it is reported that some operation problems in micro-grid systems without diesel generator for carbon-free island are being occurred when large scaled WP systems are at start-up. To overcome these problems, this paper proposes an operation strategy in micro-grid systems by adapting control devices such as CVCF(constant voltage constant frequency) ESS(energy storage system) for constant frequency and voltage regulation, load control ESS for balancing demand and supply and SVC(static-var compensator) for reactive power compensation. From the simulation results based on the various operation scenarios, it is confirmed that the proposed operation strategy in micro-grid systems without diesel generators is a useful tool to perform a stable operation in micro-grid systems without diesel generator and also make a contribution to reduce carbon dioxide in micro-grid systems.

• Tunnel and Underground Space
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• v.20 no.5
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• pp.309-317
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• 2010

CCS (Carbon dioxide Capture and Storage) is a means of mitigating the contribution of $CO_2$ to the Greenhouse gas, from large point sources such as power plants and steel companies. CCS is a process whereby $CO_2$ is captured from gases produced by fossil fuel combustion, compressed, transported and injected into deep geologic formations for permanent storage. CCS applied to a conventional power plant can reduce $CO_2$ emissions to the atmosphere by approximately 80~90% compared to a plant without CCS. The IPCC estimates that the economic potential of CCS will be between 10% and 55% of the total carbon mitigation effort by year 2100. In this paper, overseas sites where CCS technology is being applied and technical development trends for CCS are briefly reviewed.