• Korean Chemical Engineering Research
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• 제57권6호
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• pp.826-831
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• 2019

Experimental data of phase equilibrium is reported for caprolactone acrylate in supercritical carbon dioxide. Bubble-point data was measured by synthetic method at temperatures ranging from (313.2 to 393.2) K and pressures up to 55.93 MPa. In this research, the solubility of carbon dioxide for the (carbon dioxide + caprolactone acrylate) system decreases as temperature increases at a constant pressure. The (carbon dioxide + caprolactone acrylate) system exhibits type-I phase behavior. The experimental result for the (carbon dioxide + caprolactone acrylate) system was correlated with Peng-Robinson equation of state using mixing rule. The critical property of caprolactone acrylate was predicted with the Joback and Lyderson method.

• 한국도로학회논문집
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• 제17권2호
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• pp.99-105
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• 2015

PURPOSES: In this study, alkali-activated blast-furnace slag (AABFS) was investigated to determine its capacity to absorb carbon dioxide and to demonstrate the feasibility of its use as an alternative to ordinary Portland cement (OPC). In addition, this study was performed to evaluate the influence of the alkali-activator concentration on the absorption capacity and physicochemical characteristics. METHODS: To determine the characteristics of the AABFS as a function of the activator concentration, blast-furnace slag was activated by using calcium hydroxide at mass ratios ranging from 6 to 24%. The AABFS pastes were used to evaluate the carbon dioxide absorption capacity and rate, while the OPC paste was tested under the same conditions for comparison. The changes in the surface morphology and chemical composition before and after the carbon dioxide absorption were analyzed by using SEM and XRF. RESULTS: At an activator concentration of 24%, the AABFS absorbed approximately 42g of carbon dioxide per mass of paste. Meanwhile, the amount of carbon dioxide absorbed onto the OPC was minimal at the same activator concentration, indicating that the AABFS actively absorbed carbon dioxide as a result of the carbonation reaction on its surface. However, the carbon dioxide absorption capacity and rate decreased as the activator concentration increased, because a high concentration of the activator promoted a hydration reaction and formed a dense internal structure, which was confirmed by SEM analysis. The results of the XRF analyses showed that the CaO ratio increased after the carbon dioxide absorption. CONCLUSIONS : The experimental results confirmed that the AABFS was capable of absorbing large amounts of carbon dioxide, suggesting that it can be used as a dry absorbent for carbon capture and sequestration and as a feasible alternative to OPC. In the formation of AABFS, the activator concentration affected the hydration reaction and changed the surface and internal structure, resulting in changes to the carbon dioxide absorption capacity and rate. Accordingly, the activator ratio should be carefully selected to enhance not only the carbon capture capacity but also the physicochemical characteristics of the geopolymer.

• 한국산업보건학회지
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• 제20권4호
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• pp.236-240
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• 2010

This study demonstrates the use of a chemical containing potassium superoxide (KO2) to convert carbon dioxide (CO$_2$) in air to oxygen (O$_2$). A oxygen generating closed-circuit SCBA (self contained breathing apparatus) removes carbon dioxide by a chemical reaction with potassium dioxide that consumes the carbon dioxide and produces oxygen. Considering the disasters, there is a need to develop strategies to enable the introduction of self-contained self rescuers (SCSR). The potassium superoxide reacts with the wears breath to produce oxygen and absorb carbon dioxide. If the respiration rate of a person is 5 MET (metabolic equivalent), to say 30 L/min, at disaster such as fire, mass of potassium superoxide was evaluated as 33.3 g with yield and safety factor. Four researchers tested on a laboratory treadmill breathing through SCSRs in a closed circuit, it appears useable for 9 minutes.

• KIEAE Journal
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• 제14권2호
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• pp.87-98
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• 2014

This study is to identify quantitatively the function of carbon dioxide emissions reduction due to temperature and energy reduction according to direct carbon dioxide storage, shade provision, and evaportanspiration of urban park. According to the result of study, landscape tree indicated high carbon dioxide storage effect compare to bush, in which broadleaf tree indicated higher storage function than coniferous tree. It is believed to be the storage of carbon dioxide can be increased by increasing the composition rate of forest plants in the urban park. According to the direct estimation result of carbon dioxide storage in terms of example area, storage of carbon dioxide is estimated to be "seoul a zone" $476,818.8kg{\cdot}CO_2/m^2yr$, "anyang b zone" $186,435.7{\cdot}CO_2/m^2yr$, "daejeon c zone" $262,826{\cdot}CO_2/m^2yr$, "kwangju d zone" $231,657.8{\cdot}CO_2/m^2yr$. The carbon dioxide storage per unit area estimated to be "seoul a zone" $3.4{\cdot}CO_2/m^2yr$, "anyang b zone" $5.0{\cdot}CO_2/m^2yr$, "daejeon c zone" $2.6{\cdot}CO_2/m^2yr$, "kwangju d zone" $5.6{\cdot}CO_2/m^2yr$. The result of indirect carbon dioxide reduction effect estimated to be "seoul a zone" $291,603.4{\cdot}CO_2/m^2yr$, "anyang b zone" $165,462.4{\cdot}CO_2/m^2yr$, "daejeon c zone" $141,719.2{\cdot}CO_2/m^2yr$, "kwangju d zone" $154,803.4{\cdot}CO_2/m^2yr$. Carbon dioxide reduction potential amount through the urban park was increased to 1.6 times to 1.8 times when calculated to the indirect effect.

• KIEAE Journal
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• 제8권4호
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• pp.19-27
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• 2008

The carbon dioxide is brought from the energy consumption and regarded as a criteria material to estimate the Global Warming Potential. Building shares about 30% in national energy consumption and affects to environment as much as the energy consumption. But there is not enough data to forecast the amount of the carbon dioxide during the maintenance stage. Various factors are related with the energy consumption and carbon dioxide emission such as the physical area, the building exterior area, the maintenance type and location. Among these factors, the building carbon-dioxide emission can be estimated by the overall building characteristics such as the maintenance area, the number of household, the heating type, etc., The physical amount such as the thickness of the insulation and window infiltration could explained the limited scope and might not be use to estimate the total carbon-dioxide emission energy because the each value could not include or represent the overall building. In this paper, it provided the estimation model of the carbon-dioxide emission, explained by the overall building characteristics. These factors are shown as the maintenance area, no. of household, the heating type, the volume of the building, the ratio of the window to wall area etc., For providing the estimation model of th carbon-dioxide emission, it conducted the corelation analysis to filter the variables and suggested the estimation model with the power model and multiple regression model. Most of the model have a good statistics and fitted in the curve line.

• 멤브레인
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• 제16권3호
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• pp.204-212
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• 2006

이산화탄소에 대한 가소화 안정성 및 이산화탄소/질소의 분리특성이 탁월한 폴리이서술폰(PES)중공사 분리막에 의한 이산화탄소 분리특성을 수치해석으로 알아보고자 하였다. 공정변수에 따른 이산화탄소 분리 거동을 예측하기 위하여 공급 기체와 투과기체가 같은 방향으로 흐르는 병류 흐름에 대한 분리막 공정 지배 방정식을 5차 Runge-Kutta-Verner 방법을 사용하여 Compaq Visual Fortran 6.6 소프트웨어를 이용 공정모사 프로그램을 개발하였다. 개발된 프로그램을 사용하여 수치해석을 수행한 결과, 이산화탄소 투과특성에 영향을 주는 가장 중요한 인자로서 공급 이산화탄소 분압, 투과측과 분리막 내부의 압력비 그리고 공급 기체가 분리막 내부에 머무르는 체류 시간임을 알 수 있었다.

• 한국지반환경공학회 논문집
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• 제24권6호
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• pp.5-11
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• 2023

석탄 및 석유와 같은 전통적인 화석 연료는 연소 시 발생하는 열을 통해 에너지를 공급한다. 이러한 과정에서 대기 중에 이산화탄소를 배출하고 지구 온난화를 유발한다. 이산화탄소 저감을 위해 많은 연구들이 수행되고 있다. 이러한 방안 중 하나로, 이산화탄소 지중 저장 기술이 관심을 받고 있다. 이산화탄소 지중 저장은 플랜트 등에서 발생하는 이산화탄소를 포집하여 덮개암 하부 포화지반층에 이산화탄소를 주입하여 저장하는 방법을 일컫는다. 하지만, 제한된 공간에 더 많은 양의 이산화탄소 저장을 위해서는 저장 효율의 향상이 필요하다. 따라서, 본 연구에서는 계면활성제를 활용하여 이산화탄소 지중 저장의 효율을 향상하고자 한다. 또한, 지중저장소의 위치에 따라 압력 및 온도가 상이하기 때문에 이산화탄소는 기체, 액체 및 초임계 상태로 존재가능하다. 따라서, 이산화탄소 상태에 따른 저장 효율 특성을 평가하였다. 그 결과, 주입속도 및 계면활성제의 활용은 저장 효율의 향상을 기대할 수 있고, 그 효과는 기체, 액체 및 초임계 상태 이산화탄소에 발휘되는 것을 확인하였다.

• KIEAE Journal
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• 제7권4호
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• pp.113-118
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• 2007

From the construction material the cement and the concrete which will reach to 90% are used to construction. But the cement occurrence (from the whole industry 4.4% of carbon dioxide exhaust quantity) makes the carbon dioxide of manufacture hour and anti- the recognition which is an environment industry. The cement absorbs the carbon dioxide during life period of the life time. It calls carbonation. In this study in order to evaluate the carbon dioxide absorption of the cement test produced the mortar specimens which it follows in the W/C. And carbonatable material of mortar specimens (calcium hydroxide) the quantitly it measured, reference study it led and absorption of carbon dioxide quantity it produced. Finally two result comparisons leads and it is a fundamental study which does the test evaluation possibility and a propriety investigation of carbon dioxide absorption quantity in objective.

• 한국수소및신에너지학회논문집
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• 제21권1호
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• pp.72-79
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• 2010

This paper is studying the selective separation of methane and carbon dioxide which are the main ingredients of biogas. Adsorption performance of molecular sieve 13x for carbon dioxide seems to be reasonable. In this experiments carbon dioxide contains about 3~5 ppm of methane and it is impossible to obtain high purity carbon dioxide. Applying the low temperature technique, it is possible to separate methane and carbon dioxide from bio gas. PRO II simulation shows results a small change of liquefaction temperatures and no difference with the used thermodynamic models. Applying low temperature technique, It is possible to separate carbon dioxide and methane from biogas.

• 한국화재소방학회:학술대회논문집
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• 한국화재소방학회 2009년도 춘계학술논문발표회 논문집
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• pp.358-364
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• 2009

본 연구에서는 우리나라 주요 침엽수종인 소나무(Pinus densiflora)와 활엽수종인 굴참나무(Quercus variabilis)의 낙엽에 대해 FTIR(Fourier Transform Infrared) 분광계를 이용하여 배출 연소가스 종류 및 농도를 측정하였다. 실험결과 소나무와 굴참나무 낙엽에서 Carbon monoxide, Carbon dioxide, Acetic acid, Butyl acetate, Ethylene, Methane, Methanol, Nitrogen dioxide, Ammonia, Hydrogen Fluoride, Sulfur dioxide, Hydrogen bromide 등 13개 연소가스가 검출되었고 굴참나무 낙엽에서는 Nitrogen monoxide가 추가로 검출되었다. 방출된 연소가스의 전체 농도는 소나무 낙엽이 굴참나무 낙엽에 비해 4.5배 많이 검출되었다. 특히, 시간가중평균가스농도(TWA : Time-weighted average, ppm) 기준을 초과하는 연소가스는 Carbon monoxide, Carbon dioxide, Butyl acetate가 검출되었고 단시간노출기준(STEL : Short Term Exposure Limit, ppm) 기준을 초과하는 연소가스는 Carbon monoxide, Carbon dioxide로 소나무 및 굴참나무 모두에서 나타났다. 이에 산불에서의 낙엽층 지표화 연소시 전체 가스 방출량의 99% 이상을 차지하고 있는 Carbon monoxide, Carbon dioxide의 건강 위험성이 높은 것으로 나타났다. 하지만, 검출된 다른 건강 위험성 가스의 경우에도 연소물질의 양이 증가할수록 연소가스의 농도가 높아져 건강안정성에 해가 있을 것으로 판단되며 또한 검출된 연소가스 중 나무의 주요구성 원소가 아닌 Bromide, Fluoride 화합물에 대해서는 토양으로부터의 오염 또는 분석과정에서의 노이즈로 인한 검출 등에 대한 보다 면밀한 검토가 필요할 것으로 판단된다.