• 제목/요약/키워드: Carbon contents

검색결과 1,236건 처리시간 0.031초

Comparative Investigation of the Hydrogen Production of Zinc/carbons Prepared from Non-activated Carbon and Surface-modified Activated Carbon by Treatment with Zinc Salts

  • Oh, Won-Chun
    • 한국세라믹학회지
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    • 제44권11호
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    • pp.607-612
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    • 2007
  • Zn-AC and Zn-H-AC series prepared from non- and surface-modified activated carbon were investigated in terms of their hydrogen production capacity. An increase in the concentration of the zinc salts used with these series was shown to lead to a decrease in the values of the surface textural properties. The existence of zinc complexes on the surface was confirmed from an analysis of XRD data. The SEM micrographs of the two different sample types showed that the transformation of the carbon surface with an acid pre-treatment significantly change the metal contents on the surfaces of the carbon matrix. The EDX spectra indicated that all of the samples were richer in the amount of oxygen and zinc compared to any other elements. The results obtained using the Boehm's titration method showed that the positive introduction of the acidic groups on the carbon surfaces with the acid treatment is correlated with an increase in the amounts of zinc complexes with variation of the acidic groups. In terms of the hydrogen production performance, the volume fractions of the Zn-H-AC series were found to produce higher amounts than the Zn-AC series as a function of the metal contents considering the effects of the acid treatment.

Effects of Tillage and Cultivation Methods on Carbon Accumulation and Formation of Water-stable Aggregates at Different Soil Layer in Rice Paddy

  • Kim, Sukjin;Choi, Jong-Seo;Kang, Shingu;Park, Jeong-Hwa;Hong, Sunha;Kim, Tae-su;Yang, Woonho
    • 한국토양비료학회지
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    • 제50권6호
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    • pp.634-643
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    • 2017
  • No-tillage is an effective practice to save labor input and reduce methane emission from the paddy. Effects of tillage and cultivation methods on carbon accumulation and soil properties were investigated in the treatments of tillage-transplanting (T-T), tillage-wet hill seeding (T-WS), minimum tillage-dry seeding (MT-S) and no-tillage dry seeding (NT-S) of rice. Soil carbon was higher in NT-S and MT-S, compared to T-T and T-WS. In NT-S and MT-S, soil carbon contents were the highest in the top soil (5 cm depth) and decreased with soil depth. In T-T and T-WS, however soil carbon contents showed no significant difference up to soil depth of 15 cm from the top. Carbon content was the highest in the soil particle size under $106{\mu}m$ and decreased as the soil particle size increased. Contents of water-stable aggregates in NT-S and MT-S were higher than those of T-T and T-WS. In NT-S and MT-S, contents of water-stable aggregates were the highest in the top soil and significantly decreased with soil depth while no significant difference up to the soil depth of 15 cm in T-T and T-WS. Available $SiO_2$ contents in the top soil were the highest in NT-S and MT-S while the lowest in T-T and T-WS. It is concluded that minimum or no disturbance of soil in rice cultivation can increase carbon accumulation in the soil, especially in the top layer, and subsequently contribute to the formation of the water-stable soil aggregates.

섬유혼입률 및 섬유길이 변화에 따른 탄소섬유 보강시멘트 복합재료의 역학적 특성과 내충격성 검토 (Mechanical Properties and Impact Resistance Review of Carbon Fiber Reinforced Cement Composites with Different Fiber Contents and Fiber Lengths)

  • 허광희;송기창;박종건;한윤정;임채영
    • 한국구조물진단유지관리공학회 논문집
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    • 제23권4호
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    • pp.86-95
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    • 2019
  • 탄소섬유는 경량이면서 높은 기계적 특성 때문에 우주항공, 선박, 자동차, 토목 및 건축과 같은 산업분야에서 그 어느 때 보다 더 광범위하게 적용되고 있다. 본 연구는 섬유혼입률 및 섬유길이 변화에 따른 탄소섬유 보강시멘트 복합재료( CFRC)의 역학적 특성과 휨 거동을 분석하였으며, 또한 자연 낙하시험에 의한 모르타르 시편에 대한 내충격성을 비교, 검토하였다. 더불어, 탄소섬유(CF)의 혼입률은 0.5%, 1.0%, 2.0% 및 3.0%로 변화를 주었으며, 각각의 섬유길이는 6 mm와 12 mm를 사용 하였다. 실험결과, 플로우 값은 탄소섬유의 뭉침현상으로 인해 유동성 측면에서 매우 불리하였으며, 단위용적질량은 다소 감소하였다. 특히, 압축강도는 탄소섬유 혼입량이 증가함에 따라 감소하는 것으로 나타내었다. 반면 휨 강도는 섬유 길이가 12 mm이고 2% 혼입한 것이 가장 높은 휨 강도를 보였다. 내충격성 시험결과, 보통 모르타르 시편은 완전파괴까지의 낙하횟수가 2~3회 정도 걸리지만 반면 CFRC 시편은 섬유혼입량이 증가함에 따라 다소 차이가 있지만, 섬유길이가 12 mm이고 섬유혼입량 2% 인 경우 충격에 대한 저항성이 가장 높았다.

흰쥐에서의 일산화탄소(一酸化炭素) 중독(中毒)이 뇌(腦)에너지 대사(代謝) 관련물질(關聯物質) 함량변화(含量變化)에 미치는 영향 (Effect of Carbon Monoxide Intoxication on the Change in Contents of Cerebral Energy Metabolites of Rats)

  • 윤재순;최신규
    • 약학회지
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    • 제33권3호
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    • pp.149-155
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    • 1989
  • To predict the influence of carbon monoxide poisonining on cerebral energy metabolism, rats were exposed to 5000 ppm environment for 30 minutes. Carboxyhemoglobin (HBCO) saturation rate in this condition was 72% equally in male and female rats. Cerebral cortex in the rats showed lower level of ATP, glucose, creatine phosphate and higher level of lactate, pyruvate by anaerobic glycolysis. As for the levels of ATP, creatine phsphate and glucose, the cerebral cortex contents of them were larger in female rats of estrus than in male rats, whereas there was no difference between sexes in the levels of pyruvate and lactate. According to time passage from CO intoxication, the mode of changes in cerebral energy metabolite contents was similar in both sexes.

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Effects of mixed contents of carbon nanoreinforcements on the impact resistance of epoxy-based nanocomposites

  • Ayatollahi, M.R.;Naeemi, A.R.;Alishahi, E.
    • Structural Engineering and Mechanics
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    • 제56권2호
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    • pp.157-167
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    • 2015
  • The impact behavior of epoxy-based nanocomposites reinforced with carbon nano tube (CNT), carbon nano fiber (CNF) and mixed contents of these nanoparticles was investigated using Izod impact test. The results showed that while the impact strength of nanocomposites containing 1 wt% of CNT and 1 wt% of CNF increased 19% and 13% respectively, addition of mixed contents of these nanofillers (0.5-0.5 wt%) demonstrated higher improvement (21%) in the impact resistance. The trend of the results is explained on the basis of different fracture mechanisms of nanocomposites. Furthermore, the fracture surface of specimens and the dispersion state of nanoenhancers have been studied using scanning electron microscopy (SEM) photographs.

중기공 탄소의 탄화온도에 따른 이산화탄소 흡착 거동 (Effect of Carbonization Temperature on Carbon Dioxide Adsorption Behaviors of mesoporous carbon)

  • 장동일;박수진
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2011년도 춘계학술대회 초록집
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    • pp.221.1-221.1
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    • 2011
  • In this study, we prepared the nitrogen-containing carbon spheres with mesopore processed by a facile polymerization-induced colloid aggregation method including carbonization in order to investigate the characterization and the effect on their carbon dioxide adsorption behaviors. The carbonization temperature was varied in the range of $600^{\circ}C$ to $900^{\circ}C$. The nitrogen contents of the mesoporous carbon sphere were characterized using XPS. The carbon dioxide adsorption capacities of the prepared mesoporous carbon sphere were determined by the amounts of carbon dioxide adsorptions at 298 K and 1.0 atm. The results showed that the prepared mesoporous carbons were highly effective for the carbon dioxide adsorption due to the increasing the affinity of the basic functionalities of adsorbent surface to acidic carbon dioxide. Maximum adsorption capacities of carbon dioxide at $25^{\circ}C$ were achieved up to 106 mg/g.

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금속유기골격체(Metal-organic Framework)의 함량에 따른 다공성 활성탄소 복합재료 기반 슈퍼커패시터의 전기화학적 거동 분석 (Characterization of electrochemical behaviour for supercapacitor based on porous activated carbon composite with various contents of metal-organic framework(MOF))

  • 정현택;김용렬
    • 한국응용과학기술학회지
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    • 제37권5호
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    • pp.1200-1207
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    • 2020
  • 본 연구에서는 다공성 활성탄소와 금속유기골격체 복합재료 기반의 전극 재료와 "이온젤" 이라고 불리는 고분자 고체 전해질을 이용하여 슈퍼커패시터를 제작 하였으며, 금속유기골격체의 함량에 따른 전기화학적 거동을 관찰하여 보았다. 슈퍼커패시터의 전기화학적 특성은 순환전압전류법(CV), 전기화학적 임피던스 분광법(EIS) 및 전정류 충·방전법(GCD)으로 분석하였으며, 그 결과로, 다공성 활성탄소 대비 금속유기골격체를 0.5 wt% 첨가 하였을 때 가장 높은 전기용량값을 확인 할 수 있었으며, 0.5 wt% 이상의 금속유기골격체의 함유량은 전기화학적 특성 감소에 영향을 주는 것으로 사료되며, 이러한 결과를 바탕으로 제조된 다공성 활성탄소/금속유기골격체 복합재료 기반의 슈퍼커패시터는 다양한 분야에 활용이 가능할 것으로 판단된다.

열중량분석기를 적용한 탄소섬유/에폭시 복합재의 구성재 함유율 측정 기법 (Measurement Method for Constituent Contents of Carbon Fiber/Epoxy Composites Using Thermogravimetric Analyzer)

  • 장정근;차재호;이보미;윤성호
    • Composites Research
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    • 제33권6호
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    • pp.341-345
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    • 2020
  • 열중량분석기를 적용하여 탄소섬유/에폭시 복합재의 구성재 함유량을 평가하기 위한 측정기법을 제시하였다. 시험에 사용된 시료는 탄소섬유/에폭시 토우 프리프레그로 제작된 스트랜드 시편에서 채취하였으며 시간에 따른 시료의 무게 변화를 실시간으로 측정하였다. 또한 전자현미경을 이용하여 수지 제거 여부와 탄소섬유의 열손상 상태를 관찰하였다. 연구결과에 따르면 열중량분석기를 적용하면 기존의 머플로를 적용한 경우에 비해 소량의 시료에 대해서도 시험이 가능하며, 설정 온도와 노출 시간을 제어함으로써 구성재의 함유량을 효율적이고 정량적으로 평가할 수 있음을 알 수 있었다.

Epoxidation of Simple Alkenes with O2 and Isobutyraldehyde Catalyzed by Ni Catalysts Deposited on Nanoporous Carbon

  • Lim, So-Young;Kang, Min;Kim, Ji-Man;Lee, Ik-Mo
    • Bulletin of the Korean Chemical Society
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    • 제26권6호
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    • pp.887-891
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    • 2005
  • Novel nickel catalyst deposited on nanoporous carbon was found to be an efficient catalyst for the epoxidation of simple alkenes with $O_2$ and isobutyraldehyde under mild conditions. Alkenes exhibited different reactivities towards Ni-catalyst and epoxidation with stilbene proceeds stereospecifically. This may be rationalized with the mechanism involving coordinated acylperoxy radical intermediate. Nickel contents depend on the preparative methods and the KNI-3 catalyst, which was synthesized by wet impregnation of $Ni(NO_3)_2$ into nanoporous carbon, shows the highest activity. The activity of the catalyst is well correlated with contents of nickel. Recycled catalysts suffer considerable loss of activity due to leaching of catalytic active species, nickel.

How does Voluntary Carbon Disclosure (VCD) Induce Changes in Carbon Performance? With the Role of Management Capability

  • Kim, Seonae;Kim, Jong Dae
    • 한국환경과학회지
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    • 제30권10호
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    • pp.863-877
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    • 2021
  • While there a growing interest in Voluntary Carbon Disclosure (VCD), comparatively little is discussed whether the improved quality of voluntary carbon disclosure can lead to subsequent changes in a company's carbon reduction performance. Drawing on companies under the Korean Emission Trading Scheme (ETS) with the contents analysis of their sustainable reports, the present research seeks to address the existing knowledge gaps in the current literature on environmental disclosure. Findings empirically show that an increase in the voluntary carbon disclosure score is positively transformed into changes in carbon performance and further develop that the effect of voluntary carbon disclosure on carbon performance varies depending on changes in management capability with the moderation effect.