• Title/Summary/Keyword: Carbon content

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Thermal characteristics of spent activated carbon generated from air cleaning units in korean nuclear power plants

  • So, Ji-Yang;Cho, Hang-Rae
    • Nuclear Engineering and Technology
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    • v.49 no.4
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    • pp.873-880
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    • 2017
  • To identify the feasibility of disposing of spent activated carbon as a clearance level waste, we performed characterization of radioactive pollution for spent activated carbon through radioisotope analysis; results showed that the C-14 concentrations of about half of the spent activated carbon samples taken from Korean NPPs exceeded the clearance level limit. In this situation, we selected thermal treatment technology to remove C-14 and analyzed the moisture content and thermal characteristics. The results of the moisture content analysis showed that the moisture content of the spent activated carbon is in the range of 1.2-23.9 wt% depending on the operation and storage conditions. The results of TGA indicated that most of the spent activated carbon lost weight in 3 temperature ranges. Through py-GC/MS analysis based on the result of TGA, we found that activated carbon loses weight rapidly with moisture desorption reaching to $100^{\circ}C$ and desorbs various organic and inorganic carbon compounds reaching to $200^{\circ}C$. The result of pyrolysis analysis showed that the experiment of C-14 desorption using thermal treatment technology requires at least 3 steps of heat treatment, including a heat treatment at high temperature over $850^{\circ}C$, in order to reduce the C-14 concentration below the clearance level.

A Study on Impurities Measurement and Physical Properties of Semiconductive Shield at Power Cable (전력케이블에서 반도전 재료층의 불순물 측정 및 물성에 관한 연구)

  • 이경용;양종석;최용성;박대희
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.53 no.9
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    • pp.455-458
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    • 2004
  • In this paper, we investigated impurities content and physical properties showing by changing the content of carbon black that is semiconductive materials for underground power transmission. Specimens were made of sheet form with the three of existing resins and the nine of specimens for measurement. Impurities content of specimens was measured by ICP-AES (Inductively Coupled Plasma Atomic Emission Spectrometer), and density of specimens were measured by density meter And then specific heat (Cp) was measured by DSC (Differential Scanning Calorimetry). A ranges of measurement temperature were from $0^{\circ}[C]$ to $200^{\circ}[C]$, and heating temperature was $4^{\circ}[C/min]$. Impurities content was highly measured according to increasing the content of carbon black from this experimental result, also density was increased according to these properties. Especially impurities content values of the Al and A2 of existing resins were measured more than 4000[ppm]. Specific heat from the DSC results was decreased according to increasing the content of carbon black. Because ionic impurities of carbon black having Fe, Co, Mn, Al and Zn are rapidly passed kinetic energy increasing the number of times breaking during the unit time with the near particles according to increasing vibration of particles by the applied heat energy.

Relative Content Evaluation of Single-walled Carbon Nanotubes using UV-VIS-NIR Absorption Spectroscopy

  • Cha, Ok-Hwan;Jeong, Mun-Seok;Byeon, Clare C.;Jeong, Hyun;Han, Jong-Hun;Choi, Young-Chul;An, Kay-Hyeok;Oh, Kyung-Hui;Kim, Ki-Kang;Lee, Young-Hee
    • Carbon letters
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    • v.10 no.1
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    • pp.9-13
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    • 2009
  • We propose an evaluation method of the relative content of single-walled carbon nanotubes (SWCNT) in SWCNT soot synthesized by arc discharge using UV-VIS-NIR absorption spectroscopy. In this method, we consider the absorbance of semiconducting and metallic SWCNTs together to calculate the relative content of SWCNTs with respect to a highly purified reference. Our method provides the more reliable and realistic evaluation of SWCNT content with respect to the whole carbonaceous content than the previously reported method.

Physical and Mechanical Properties of Concrete Using Waste Activated Carbon (폐활성탄을 혼입한 콘크리트의 물리.역학적 성질)

  • Kang, Hyun-Soo;Sung, Chan-Yong
    • Journal of The Korean Society of Agricultural Engineers
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    • v.51 no.1
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    • pp.21-26
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    • 2009
  • This study was performed to evaluate the physical and mechanical properties of concrete using waste activated carbon. Materials used were ordinary portlant cement, crushed coarse aggregate, natural fine aggregate, waste activated carbon, and superplasticizer. The substitution ratios of waste activated carbon were 0,1,2,3,4,5,6,7,8,9 and 10%. The unit weight was decreased and water absorption ratio was increased with increasing the waste activated carbon content, respectively. When the substitution ratio of waste activated carbon was 3%, compressive strength, flexural strength and dynamic modulus of elastisity were more higher than that of the ordinary portland cement (OPC), and it was decreased with increasing the waste activated carbon content, respectively. The most effective contents of waste activated carbon was 2% in performance and 4% in practical use Accordingly, waste activated carbon can be used for concrete material.

Mechanical Properties of Sintered Steel of Pure Iron Powder and Iron Powder Coated with Phosphorus (순철분말과 인(P)이 피복된 철분말 소결강의 기계적 성질)

  • 정재우
    • Journal of Powder Materials
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    • v.1 no.2
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    • pp.181-189
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    • 1994
  • The compacts of pure and phosphorus-coated iron powder with 0~0.8%C were sintered at $1100^{\circ}C$ for 40 min. in cracked ammonia gas atmosphere. The tensile and impact strengths were measured and the relationship of the results with carbon content, phosphorus, quenching and tempering was investigated. The results obtained can be summarized as follows : (1) The tensile strength of sintered compacts increased slowly with carbon content. Increase in tensile strength by heat treatment was evident especially in the low carbon specimen. The specimen with phosphorus showed higher strength compared to pure iron compacts value. (2) No inflection point of elasticplastic deformation on stress-strain curve was observed in sintered steel. The elastic modulus of sintered steel had the same tendency as tensile strength. But the elongation showed the opposite tendency. (3) The impact absorption energy of sintered steel without addition of phosphorus decreased successively with carbon content and by quenching and tempering. On the contrary, addition of phosphorus resulted in an increase of the impact absorption energy. Quenching and tempering did not affect the impact energy especially in high carbon content. (4) The main fracture source was pore in specimen and the propagation of crack occured mostly along the grain boundaries. But the intragranular fracture was also observed in high carbon, quenched and tempered specimen, and especially in the specimen with phosphorus.

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Modulus Properties and Smoothness Measurement of Semiconducting Materials Using the DMA and SEM (DMA와 SEM을 사용한 반도전층 재료의 탄성특성과 평활도 측정)

  • Yang, Jong-Seok;Lee, Kyoung-Yong;Choi, Yong-Sung;Park, Dae-Hee
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.54 no.10
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    • pp.443-448
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    • 2005
  • To measure modulus, damping properties and smoothness of semiconducting materials in power cable, we have investigated those of semiconducting materials showed by changing the content of carbon black. Then they were produced as sheets after pressing for 20 minutes at 180[$^{\circ}C$] with a pressure of 200[kg/cm$^{2}$]. The content of conductive carbon black was the variable, and their contents were 20, 30 and 40[wt$\%$], respectively. The modulus and tans were measured by DMA 2980. The ranges of measurement temperature were from -50[$^{\circ}C$] to 100[$^{\circ}C$] and measurement frequency was 1[Hz3. The modulus of specimens was increased according to a increment of a carbon black content. And modulus was rapidly decreased at the glass transition temperature. The tans of specimens was decreased according to a increment of a carbon black content. The smoothness was measured by JSM-6400. EEA resin from SEM measurement was best the dispersion of carbon back in base resin.

The Analysis of the Low Carbon Green Growth Education Contents in the Fisheries and Marine High School Textbooks (저탄소 녹색성장 교육 관련 수산·해운계 고등학교 교과서 분석)

  • Hwang, Jae-Ho;Park, Jong-Un
    • Journal of Fisheries and Marine Sciences Education
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    • v.24 no.3
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    • pp.395-405
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    • 2012
  • This study was investigated 35 government-authorized and officially approved textbooks for the Fisheries and marine high school which were published by the 2007 Revised Curriculum at 2009 for analyzing the objective and content domains concerning school the low carbon green growth education. Prior to the grounds of analyzing for the objective and content domains were presented, the factors of the grounds were made based on the low carbon green growth standards for the nation. According to the analysis, the findings which were as follows; 18(51.4%) in 35 textbooks and 666(6.4%) in 10,406 pages were related the low carbon green growth education in the course of the Fisheries and marine high school education. There were 37 participation domains, 27 information and knowledge domains, 9 value and attitude domains and 6 skill domains in the objective domains. The content domains were consisted of 33 green growth, 23 climate change, 10 energy conservation, 6 low carbon and 6 international cooperation.

Effects of Oxygen Annealing of MgO Thin Films on the Phase Formation and the Electrical Properties of PZT/MgO/Si Structure

  • Song, Han-Wook;No, Kwang-Soo
    • The Korean Journal of Ceramics
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    • v.6 no.1
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    • pp.68-73
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    • 2000
  • The effects of oxygen annealing on the carbon content in MgO thin films were investigated, MgO thin films were deposited on Si(100) substrate at different temperatures of 400 to $700^{\circ}C$ and different deposition rates of 3.4 to 11.6$\AA$/min. Using rf magnetron sputtering method. Carbon content change on the surface of MgO thin films with the oxygen annealing at different temperatures was investigated using various method. The carbon content decreased as the annealing temperature increased. $Pb(Zr_{0.53}Ti_{0.47})O_3$(PZT) thin films were deposited on the MgO/Si(100) substrates. The effects of carbon content on the phase formation and the electrical properties of PZT thin films were also investigated.

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The Effect of Engine Oil Degradation and Piston Top Ring Groove Temperature on Carbon Deposit Formation Part II - The Deposit Formation Characteristics of Diesel Engine (엔진 오일 열화와 피스톤 톱링 그루브 온도가 카본 디포짓 형성에 미치는 영향 Part II-디젤 엔진의 디포짓 형성 특성)

  • 김중수;민병순;오대윤;최재권
    • Tribology and Lubricants
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    • v.14 no.4
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    • pp.108-113
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    • 1998
  • In order to investigate the characteristics of top ring groove deposit formation in diesel engine, engine test and simulation test were performed. From component analysis of used oils sampled from actual running engines, soot content in engine oil was selected as a main parameter for evaluating oil degradation. Deposit formation is highly related to soot content in lubricating oils. And high soot content oil accelerates deposit formation even in low temperature region below 26$0^{\circ}C$. In low temperature region below 26$0^{\circ}C$, deposit formation rate is mainly affected by top ring groove temperature. However, in high temperature region above 26$0^{\circ}C$, deposit formation rate is affected by soot content as well as top ring groove temperature. Therefore, soot content as well as top ring groove temperature should be kept a certain level in order to prevent troubles due to carbon deposit formation.

Ductile-to-Brittle Transition Behavior of Two Austenitic Fe-18Cr-10Mn Alloys with the Combined Addition of Nitrogen and Carbon (질소와 탄소가 복합 첨가된 두 오스테나이트계 Fe-18Cr-10Mn 합금의 연성-취성 천이 거동)

  • Lee, S.Y.;Kim, B.Y.;Hwang, B.
    • Journal of the Korean Society for Heat Treatment
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    • v.28 no.1
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    • pp.1-6
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    • 2015
  • The ductile-to-brittle transition behavior of two austenitic Fe-18Cr-10Mn alloys with the combined addition of nitrogen and carbon was investigated in this study. The alloys exhibited a ductile-to-brittle transition behavior because of unusual brittle fracture at low temperatures unlike conventional austenitic alloys. The alloy with higher carbon content had higher yield and tensile strengths than that with lower carbon content due to the solid solution strengthening effect resulting from carbon addition. However, the increase in carbon content promoted the occurrence of intergranular fracture, and thus deteriorated the impact toughness. In order to develop successfully the austenitic Fe-18Cr-10Mn alloys with the excellent combination of strength and toughness in the future, therefore, more systematic studies are required to find the appropriate amount and ratio of nitrogen and carbon.