• 제목/요약/키워드: Carbon concentration

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횡성호의 유기물 수지 및 거동 특성 (Organic Matters Budget and Movement Characteristic in Lake Hoengseong)

  • 정승현;박혜경;윤석환
    • 한국물환경학회지
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    • 제28권2호
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    • pp.238-246
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    • 2012
  • Organic matters budget in Lake Hoengseong were monthly investigated from April 2009 to November 2009. The intense rainfall occurred at between July and August and the hydrological factors were highly varied during the rainfall season. By the concentrated rainfall, the elevation, influx and efflux were sharply increased and the turbid water was also flowed into the middle water column in Lake. The inflow of turbid water increased the nutrient concentrations in water body and this appears to stimulate of phytoplankton regard as the primary productivity of influx of organic matter. Monthly average concentration of dissolved organic carbon (DOC) was generally higher than the particulate organic carbon (POC) concentration in Lake, but Temporal and spatial variation of POC concentration was higher than DOC and the maximum POC concentration was recorded in surface water in August, had the highest phytoplankton biomass. Organic carbon concentration in inflow site was rarely changed during the dry season, but the concentration was rapidly increased by the initial intense rainfall. In organic matters budget, the most of the organic matters was inflowed from the inflow site at rainfall season. Especially, the influx of allochthonous organic matters during the intense rainfall was 72.4% in the total influx organic matters.

Pilot-scale modified SBR 공정에서 외부탄소원의 종류에 따른 탈질효율 비교 연구 (A Study on Denitrification Efficiency with External Carbon Sources in Pilot-scale Modified SBR)

  • 서인석;김병군;홍성택;정위득
    • 환경위생공학
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    • 제17권3호
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    • pp.52-59
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    • 2002
  • Pilot-scale PSSBR(Phase Separated Sequencing Batch Reactor) was operated to evaluate requirement of external carbon sources(${\Delta}gCOD/{\Delta}gNO_3^{-}-N$) in denitrification. Methanol and fermented food waste were used as external carbon sources. Methanol and fermented food waste were fed to the anoxic state of first reactor and concentration were 50 and 40 mgCOD/L on the basis of concentration in reactor, respectively. In case that external carbon source was not used, average $NO_3^{-}-N$ concentration in effluent was 22.49 mg/L. When methanol and fermented food waste were fed, average $NO_3^{-}-N$ concentration in effluent were 10.13 mg/L and 6.3 mg/L, respectively and requirement of external carbon sources were 4.04 and 2.5 ${\Delta}gCOD/{\Delta}gNO_3^{-}-N$, respectively. Fermented food waste was better than methanol in denitrification efficiency. Therefore fermented food waste could be one of the excellent external carbon sources for nitrogen removal in biological nutrient removal process.

NITROGEN DOPED DIAMOND LIKE CARBON FILM SYNTHESIZED BY MICROWAVE PLASMA CVD

  • Urao, Ryoichi;Hayatsu, Osamu;Satoh, Toshihiro;Yokota, Hitoshi
    • 한국표면공학회지
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    • 제29권5호
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    • pp.549-555
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    • 1996
  • Diamond Like Carbon film is amorphous film which is considered to consist of three coordinate graphite structure and tetrahedron coordinate diamond structure. Its hardness, thermal conductivity and chemical stability are nearly to one of diamond. It is well known to become semi-conductor by doping of inpurity. In this study Diamond Like Carbon film was synthesized by Microwave Plasma CVD in the gas mixture of hydrogen-methan-nitrogen and doped of nitrogen on the single-crystal silicon or silica glass. The temperature of substrate and nitrogen concentration in the gas mixture had an effect on the bonding state, structural properties and conduction mechanism. The surface morphology was observed by Scanning Electron Microscope. The strucure was analyzed by laser Raman spectrometry. The bonding state was evaluated by electron spectroscopy. Diamond Like Carbon film synthesized was amorphous carbon containing the $sp^2$ and $sp^3$ carbon cluster. The number of $sp^2$ bonding increased as nitrogen concentration increased from 0 to 40 vol% in the feed gas at 1233K substrate temperature and at $7.4\times10^3$ Pa. Increase of nitrogen concentration made Diamond Like Carbon to be amorphous and the doze of nitragen could be controlled by nitrogen concentration of feed gas.

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수도권 일부 대형상가 지상주차장 및 지하주차장의 공기중 디젤엔진배출 입자상물질의 공기중 농도 비교 (Comparison of Diesel Exhaust Particle Concentration between Large Above-Underground Parking Lots)

  • 김부욱;송동우
    • 한국산업보건학회지
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    • 제23권4호
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    • pp.323-332
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    • 2013
  • Objectives: This study was conducted in order to investigate the diesel exhaust particle(DEP) concentrations in the thirteen parking lots of large shopping complex. Methods: The real-time black carbon(BC) concentration was determined using an Aethalometer, and elemental/organic carbon concentration was determined according to the method of the National Institute for Occupational Safety and Health(NIOSH) 5040. The particle number concentration(NC), lung deposited surface area concentration(LDSA) and geometric mean diameter(GMD) were determined using a DiSCmini aerosol monitor. Results: The average concentration of BC, EC, OC, NC, LDSA and GMD were $19.1{\mu}g/m^3$, $12.6{\mu}g/m^3$, $51.5{\mu}g/m^3$, $94,000particles/cm^{-3}$, $298{\mu}m^2/cm^{-3}$ and 57 nm in all parking lots, respectively, approximately 3-fold higher than those found in the urban outdoor. The average concentration of BC were $21.3{\mu}g/m^3$ in underground parking lots, 3-fold higher than above parking lots. Conclusions: Therefore, the parking lots at the large shopping complex can be considered a potentially dangerous environment with a high concentration of DEP nanoparticles.

코코넛 기반 활성탄 필터의 라돈 제거 효율 (Radon Removal Efficiency of Activated Carbon Filter from Coconut)

  • 안윤진;김기섭;김태환;김상록
    • 대한방사선기술학회지:방사선기술과학
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    • 제46권2호
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    • pp.141-149
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    • 2023
  • The Korea Institute of Radiological and Medical Sciences plans to produce 225Ac, a therapeutic radio-pharmaceutical for precision oncology, such as prostate cancer. Radon, a radioactive gas, is generated by radium, the target material for producing 225Ac. The radon concentration is expected to be about 2000 Bq·m-3. High-concentration radon-generating facilities must meet radioactive isotope emission standards by lowering the radon concentration. However, most existing studies concerning radon removal using activated carbon filters measured radon levels at concentrations lower than 1000 Bq·m-3. This study measured 222Rn removal of coconut-based activated carbon filter under a high radon concentration of about 2000 Bq·m-3. The 222Rn removal efficiency of activated carbon impregnated with triethylenediamine was also measured. As a result, the 222Rn removal amount of the activated carbon filter showed sufficient removal efficiency in a 222Rn concentration environment of about 2000 Bq·m-3. In addition, despite an expectation of low radon reduction efficiency of Triethylenediamine-impregnated activated carbon, it was difficult to confirm a significant difference in the results. Therefore, it is considered that activated carbon can be used as a radioisotope exhaust filter regardless of whether or not Triethylenediamine is impregnated. The results of this study are expected to be used as primary data when building an air purification system for radiation safety management in facilities with radon concentrations of about 2000 Bq·m-3.

진공침탄에 의한 AISI 4115강의 침탄 거동에 미치는 세멘타이트 석출의 영향 (Effect of Cementite Precipitation on Carburizing Behavior of Vacuum Carburized AISI 4115 Steel)

  • 권기훈;박현준;손윤호;이영국;문경일
    • 열처리공학회지
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    • 제36권6호
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    • pp.402-411
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    • 2023
  • In order to examine the effect of cementite precipitated on the steel surface on the carburizing rate, the carburizing process was carried out at various boost times to measure the mass gain and carbon flux, phase analysis and carbon concentration analysis were performed on the surface of the carburized specimen. In the case of the only boost type, the longer the boost time, the more the mass gain by the diffused carbon follows the parabolic law and tends to increase. In particular, as the boost time increased, the depth of cementite precipitation and the average size of cementite on the steel surface increased. At a boost time of 7 min, the fraction of cementite precipitated on the surface is 7.32 vol.%, and the carburizing rate of carbon into the surface (surface-carbon flux) is about 17.4% compared to the calculated value because the area of the chemical (catalyst) where the carburization reaction takes place is reduced. The measured carbon concentration profile of the carburized specimen tended to be generally lower than the carbon concentration calculated by the model without considering precipitated cementite. On the other hand, in the pulse type, the mass gain by the diffused carbon increased according to the boost time following a linear law. At a boost time of 7 min, the fraction of cementite precipitated on the surface was 3.62 vol.%, and the surface-carbon flux decreased by about 4.1% compared to the calculated value. As a result, a model for predicting the actual carbon flux was presented by applying the carburization resistace coefficient derived from the surface cementite fraction as a variable.

활성탄에 의한 Tartrazine의 흡착 특성 (Adsorption Charateristics of Tartrazine by Activated Carbon)

  • 윤성욱;이종집
    • 한국물환경학회지
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    • 제25권4호
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    • pp.568-572
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    • 2009
  • The adsorption characteristics of tartrazine by granular activated carbon were experimentaly investigated in the batch adsorber and the packed column. The adsorptivity of activated carbon for tartrazine was largely improved by pH control, and 98 percent of initial concentration could be removed at pH 3. It was estabilished that the adsorption equilibrium of tartrazine on granular activated carbon was sucessfully fitted by Freundlich isotherm equation in the concentration range from 50 mg/L to 1,000 mg/L. The characteristics of breakthrough curve of activated carbon packed column, which depend on the design variables such as initial concentration, bed height, and flow rate, were studied.

Influence of the Thickness and Doping Concentration in p- and n-Type Poly-Si Layers on the Efficiency of a Solar Cell Based on a Carbon Fiber

  • Yoon, Min-Seok;Shim, Young Bo;Han, Young-Geun
    • Journal of the Optical Society of Korea
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    • 제19권2호
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    • pp.199-205
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    • 2015
  • We investigated the effects of the thickness and doping concentration in p- and n-type poly-Si layers on the performance of a solar cell based on a carbon fiber in order to improve the energy conversion efficiency of the cell. The short-circuit current density and open-circuit voltage of the carbon fiber-based solar cell were significantly influenced by the thickness and doping concentration in the p- and n-type poly-Si layers. The solar cell efficiency was successfully enhanced to ~10.5%.

활성탄 흡착에 의한 Amaranth의 제거 (Removal of Amaranth by Activated Carbon Adsorption)

  • 이종집;윤성욱
    • 한국안전학회지
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    • 제24권4호
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    • pp.34-39
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    • 2009
  • The adsorption characteristics of amatanth by granular activated carbon were experimently investigated in the batch adsorber and the packed column. The adsorptivity of activated carbon for amaranth were largely improved by pH control, and 94 percent of initial concentration(100mg/L) could be removed at pH 9. It was estabilished that the adsorption equilibrium of amaranth on granular activated carbon was sucessfully fitted by Freundlich isotherm equation in the concentration range from 1mg/L to 100mg/L. The characteristics of breakthrough curve of activated carbon packed column, which depend on the design variables such as initial concentration, bed height, and flow rate, were studied.

7Li-NMR and Thermal Analysis for Lithium Inserted into Artificial Carbon Material

  • 오원춘
    • Bulletin of the Korean Chemical Society
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    • 제22권4호
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    • pp.367-371
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    • 2001
  • Lithium inserted into artificial carbon has been synthesized as a function of the Li concentration. The characteristics of these prepared compounds were determined from the studies using X-ray diffraction(XRD), solid nuclear magnetic resonance (NM R) spectrophotometric and differential scanning calorimeter(DSC) analysis. X-ray diffraction showed that lower stage intercalation compounds were formed with increasing Li concentration. In the case of the AG3, most compounds formed were of the stage 1 structure. Pure stage 1 structural defects of artificial graphite were not observed. 7Li-NMR data showed that bands are shifted toward higher frequencies with increasing lithium concentration; this is because non-occupied electron shells of Li increased in charge carrier density. Line widths of the Li inserted carbon compounds decreased slowly because of nonhomogeneous local magnetic order and the random electron spin direction for located Li between graphene layers. The enthalpy and entropy changes of the compounds can be obtained from the differential scanning calorimetric analysis results. From these results, it was found that exothermic and endothermic reactions of lithium inserted into artificial carbon are related to the thermal stability of lithium between artificial carbon graphene layers.