• Korean Journal of Materials Research
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• v.1 no.2
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• pp.86-92
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• 1991

A potential energy function comprising a two-body potential term which is modified form Morse potential and a three-body potential term which is modified from Axilrod-Teller potential has been developed for small carbon clusters. The structural changes of small carbon clusters $C_2-C_6$ are qualitatively investigated by employing this potential energy function representing the energies of the small carbon cluster isotopes as a function of the three body intensity factor. It is found that the structure of the small carbon cluster changes from open structure to closed one, from complicated structure to simple one, and from three-dimensional structure to two-or-one dimensional one as the degree of the three-body interaction increases.

• Bulletin of the Korean Chemical Society
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• v.23 no.8
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• pp.1163-1165
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• 2002

• Bulletin of the Korean Chemical Society
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• v.23 no.2
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• pp.309-314
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• 2002

The ablation dynamics and cluster formation of $C_n^+$ ions ejected from 355 nm laser ablation of a graphite target in vacuum are investigated using a reflectron time-of-flight (RTOF) mass spectrometer. At low laser fluence, odd-numbered cluster ions with $3{\leq}n{\leq}15$ are predominantly produced. Increasing the laser fluence shifts the maximum size distribution towards small cluster ions, implying the fragmentation of larger clusters within the hot plume. The temporal evolution of $C_n^+$ ions was measured by varying the delay time of the ion extraction pulse with respect to the laser irradiation, providing significant information on the characteristics of the ablated plume. Above a laser fluence of $0.2J/cm^2$ , large cluster ions ($n{\geq}30$) are produced at relatively long delay times, indicating that atoms or small carbon clusters aggregate during plume propagation. The dependence of the intensity of ablated $C_n^+$ ions on delay time after laser irradiation shows that the most probable velocity of each cluster ion decreases with cluster size.

• Bulletin of the Korean Chemical Society
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• v.28 no.11
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• pp.1996-2002
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• 2007

The redox behavior of a [Ni6(μ3-Se)2(μ4-Se)3(Fe(η 5-C5H4P-Ph2)2)3] (= [Ni-Se-dppf], dppf = 1,1-bis(diphenylphosphino) ferrocene) cluster was studied using platinum (Pt) and glassy carbon electrodes (GCE) in nonaqueous media. The cluster showed electrochemical activity at the potential range between +1.6 and ?1.6 V. In the negative region (0 to ?1.6 V), the cluster exhibited two-step reductions. The first step was one-electron reversible, while the second step was a five-electron quasi-reversible process. On the other hand, in the positive region (0 to +1.6 V), the first step involved one-electron quasi-reversible process. The applicability of the cluster was found towards the electrocatalytic reduction of CO2 and was evaluated by experiments using rotating ring disc electrode (RRDE). RRDE experiments demonstrated that two electrons were involved in the electrocatalytic reduction of CO2 to CO at the Se-Ni-dppf-modified electrode.

• Korean Journal of Metals and Materials
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• v.47 no.6
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• pp.331-337
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• 2009

To lower the annealing temperature and the deviation of the mechanical properties of bake hardening steels, high purity steels were investigated. The steels were characterized by treating at low recrystallization temperature. It was confirmed that the strengthening originated from the solid solution of carbon and the ferrite grain refinement by fine MnS precipitates as carbon and sulfur contents increased in high purity steels. However, it was observed that there was no more increase of strength in steels containing over 40 ppm of carbon. It was considered that the excess carbon formed either the carbon cluster or the low temperature unstable carbides which had the negligible effect on the strengthening because they were reported to be highly coherent with the matrix. The carbon cluster and unstable carbides could be transformed to the stable cementite during bake hardening treatment. MnS was not observed in the high purity steel containing 5 ppm S, resulting in very coarse recrystallized grains and good ductility. As sulfur content increased, the recrystallized grain size decreased due to the formation of the fine MnS precipitates.

• Nuclear Engineering and Technology
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• v.56 no.6
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• pp.2071-2078
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• 2024

The precipitation of solutes is a major cause of irradiation hardening and embrittlement limiting the service life of reactor pressure vessel (RPV) steels. Impurities play a significant role in the formation of precipitation in RPV materials. In this study, the effects of carbon on cluster formation and irradiation hardening were investigated in an RPV alloy Fe-1.35Mn-0.75Ni using C and Fe ions irradiation at 290 ℃. Nanoindentation results showed that C ion irradiation led to less hardening below 1.0 dpa, with hardening continuing to increase gradually at higher doses, while it was saturated under Fe ion irradiation. Atom probe tomography revealed a broad size distribution of Ni-Mn clusters under Fe ion irradiation, contrasting a narrower size distribution of small Ni-Mn clusters under C ion irradiation. Further analysis indicated the influence of carbon on the cluster formation, with solute-precipitated defects dominating under C ion irradiation but interstitial clusters dominating under Fe ion irradiation. Simulations suggested that carbon significantly affected solute nucleation, with defect clusters displaying smaller size and higher density as carbon concentration increased. The higher hardening at doses above 1.0 dpa was attributed to a substantial increase in the number density of defect clusters when carbon was present in the matrix.

• Journal of The Korean Astronomical Society
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• v.14 no.1
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• pp.13-17
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• 1981

The observed radial UBV colour variations (both B-V and U-B) of some globular clusters are examined for correlations with radial variations in the integrated spectra. The results show that the presence of a radial colour gradient is correlated with the presence of a gradient of the CN (and possibly the G-band) line strength, in the sense that the CN (and possibly the G-band) is stronger in the centre (where the cluster is redder) and becomes weaker in the outer region of the cluster (where the cluster is bluer). This may suggest that a primordial abundance, possibly nitrogen and carbon gradient was set up in the early stage of cluster formation.

• Journal of the Korea Society of Computer and Information
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• v.28 no.7
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• pp.189-198
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• 2023

The phenomenon of climate change is deteriorating which increased heatwaves, typhoons and heavy snowfalls in recent years. Followed by the 25^th United nations framework convention on climate change(COP25), the world countries have achieved a consensus on achieving carbon neutrality. City plays a crucial role in achieving carbon mitigation as well as economic development. Considering economic and environmental factors, we selected 63 cities in South Korea to analyze carbon emission situation by Elbow method and K-means clustering algorithm. The results reflected that cities in South Korea can be categorized into 6 clusters, which are technology-intensive cities, light-manufacturing intensive cities, central-innovation intensive cities, heavy-manufacturing intensive cities, service-intensive cities, rural and household-intensive cities. Specific suggestions are provided to improve city-level carbon mitigation development.

• Journal of Microbiology and Biotechnology
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• v.7 no.1
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• pp.68-74
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• 1997

One hundred and eighty two lactic acid bacteria, isolated mainly from kimchi, including reference strains were examined for their ability to utilize 95 carbon sources. The test strains were assigned to 5 major, 1 minor and 12 single-membered clusters based on the $S_{SM}$, UPGMA algorithm (at similarity of $80{\%}$). These aggregate clusters were equivalent to the genus Leuconostoc (aggregate cluster M and N), the genus Lactobacillus (aggregate cluster Q and R), and the genera Lactobacillus and Leuconostoc (aggregate cluster O and P) according to the database of the Biolog system. This study demonstrates that rapid identification and classification of isolates originating from kimchi can be achieved on the basis of such carbon source utilization tests.

• Proceedings of the Materials Research Society of Korea Conference
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• 2007.11a
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• pp.113.2-113.2
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• 2007