• Title/Summary/Keyword: Carbon cage

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Development of Palladium, Gold and Gold-Palladium Containing Metal-Carbon Nanoreactors: Hydrogen Adsorption

  • Mayani, Vishal J.;Mayani, Suranjana V.;Kim, Sang Wook
    • Bulletin of the Korean Chemical Society
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    • v.35 no.5
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    • pp.1312-1316
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    • 2014
  • Metal-carbon nanoreactors (MCNRs) were prepared from a pristine carbon cage (CC) using a simple and efficient template method with nano silica ball (NSB), pyrolysis fuel oil (PFO) and transition metals, such as palladium and gold. Metal nanoparticles were embedded in approximately 25 and 170 nm sized, highly ordered carbon cages. The newly developed Pd, Au and Au-Pd doped carbon nanoreactors were characterized by microanalysis, $N_2$ adsorption-desorption isotherm, powder X-ray diffraction (XRD), thermo-gravimetric analysis (TGA), scanning electron microscopy coupled with energy dispersive spectroscopy (SEM-EDS), transmission electron microscopy and inductively coupled plasma (ICP) analysis. The ordered MCNRs have exhibited dynamic hydrogen adsorption capability compared to the carbon cage.

Dynamic behavior of a submersible fish cage rigged with a circular floating and a sinking collar (상하가 원형 파이프로 구성된 부침식 가두리의 동적 거동 해석)

  • Lee, Chun-Woo;Lee, Ji-Hoon;Choe, Moo-Youl;Lee, Gun-Ho
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.46 no.1
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    • pp.20-31
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    • 2010
  • In this research, the submersible fish cage was designed to avoid structural and biological damage during harsh sea conditions. The submersible cage system consists of netting, mooring ropes, a floating collar, floats, sinkers and anchors. Whole elements of the cage were modeled on the mass-spring model. The computer simulations were carried out to investigate the dynamic behavior of the cage and to calculate mooring line tension subjected to tidal currents and waves. As expected, the tension values in the mooring line of the submerged position are 36% less compared to that of the surface cage under the same loading conditions. As the wave was used in combination with the current velocity of 1m/s, the average tensile load for the submerged cage showed 85% of the value for the floating cage. The simulation results provide an improved understanding of the behaviors of the structure and valuable information on the optimized design of the cage system exposed to open ocean environmental factors.

Chemical Fluxes at the Sediment-Water Interface Below Marine Fish Cages on the Coastal Waters off Tong-Young, South Coast of Korea (남해안 통영지역 가두리양식장 해수-퇴적물 경계면에서의 chemical fluxes)

  • Shim, Jeong-Hee;Kang, Young-Chul;Choi, Jin-Woo
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.2 no.2
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    • pp.151-159
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    • 1997
  • Benthic respiration and chemical fluxes were measured at the sediment-water interface underlying the marine fish cages floating on the open coastal waters off Tong-Young, the South Coast of Korea. The effects of cage farming on coastal benthic environment and on mass balance of organic carbon in the benthic boundary layer under the marine fish cages are addressed. In a growing season of caged fishes of June, 1995, benthic chambers and sediment traps were deployed on the sediment-water interfaces of the two sites chosen for this study: 1) Cage Site, directly underlying the fish cages of the farm at 18 m water depth, and 2) Control Site, about 100 m away from the farm at 32 m water depth. Benthic respiration rates and chemical fluxes were calculated from the evolution of dissolved oxygen and chemicals in the chamber water, and mass balance of organic carbon in the benthic boundary layer was constructed based on the vertical flux of particulate organic matter (POM) and chemical fluxes out of the sediment. High organic dumping (6400 mg C $m^{-2}d^{-1}$) and high benthic respiration (230 mmol $O_2\;m^{-2}d^{-1}$) were observed at the Cage Site. Equivalent to 40% of vertical flux of organic carbon into the Cage Site seemed to be decomposed concurrently and released back to overlying waters (2400 mg C $m^{-2}d^{-1}$). Consequently, up to 4000 mg C $m^{-2}d^{-1}$ of organic carbon could be buried into the farm sediment (equivalent to 60% of organic carbon flux into the Cage Site). At the Control Site, relatively less input of organic carbon (4000 mg C $m^{-2}d^{-1}$) and low benthic respiration rate (75 mmol $O_2\;m^{-2}d^{-1}$) were observed despite short distance away from the cages. The influence of cage farming on benthic chemical fluxes might be restricted and concentrated in the sea bottom just below the fish cages in spite of massive organic dumping and high current regime around the fish cage farm.

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Anterior Cervical Interbody Fusion with the Carbon Composite Osta-Pek Frame Cage in Degenerative Cervical Diseases

  • Han, Kwang-Wook;Kim, Joon-Soo;Kim, Kyu-Hong;Cho, Yong-Woon;Lee, In-Chang;Bae, Sang-Do
    • Journal of Korean Neurosurgical Society
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    • v.37 no.6
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    • pp.422-426
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    • 2005
  • Objective: Different types of interbody fusion cages are available for use in the surgical treatment of degenerative cervical diseases. The purpose of this study is to assess the technical feasibility, clinical efficacy and radiological results of intervertebral fusion with a carbon composite Osta-Pek frame cage (Co-Ligne AG, Switzerland) following anterior cervical discectomy. Methods: 41 patients (25males and 16females) with minimum 6months follow-up were included in the study. Disc height, cervical lordotic angle, segmental angle, and fusion rate were assessed by lateral radiographs. In this retrospective analysis, clinical outcome was assessed as evaluated according to Odom's criteria. Results: Fifty-four cages were implanted in 30 single-level, 9 two-level, and 2 three-level procedures. The mean disc height, cervical lordosis angle, segmental angle were $4.2{\pm}1.8mm,\;23.5{\pm}7.2^{\circ},\;2.3{\pm}3.3^{\circ}$ pre-operatively and $5.3{\pm}2.1mm,\;24.2{\pm}8.3^{\circ},\;3.8{\pm}3.5^{\circ}$ at 6months after the surgery. Six months after surgery, there was radiographic evidence of fusion in 92.7% (38/41) of the patients. According to Odom's criteria, 37 of 41 (90.2%) patients experienced good to excellent functional recovery. Conclusion: These clinical and radiological results suggest that the carbon composite Osta-Pek frame cages are safe and effective alternative to autologous bone graft after anterior cervical discectomy for treatment of degenerative cervical disease.

Finite Element Analysis of Instrumented Posterior Lumbar Interbody Fusion Cages for Reducing Stress Shielding Effects: Comparison of the CFRP cage and Titanium cage (요추유합술에서 응력방패 현상 감소를 위한 케이지의 유한요소해석 : CFRP 케이지와 티타늄 케이지 비교 연구)

  • Kang, Kyung-Tak;Chun, Heoung-Jae;Kim, Ho-Joong;Yeom, Jin-S.;Park, Kyoung-Mi;Hwang, In-Han;Lee, Kwang-Ill
    • Composites Research
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    • v.25 no.4
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    • pp.98-104
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    • 2012
  • In recent years, degenerative spinal instability has been effectively treated with a cage. However, little attention is focused on the stiffness of the cage. Recent advances in the medical implant industry have resulted in the use of medical carbon fiber reinforced polymer (CFRP) cages. The biomechanical advantages of using different cage material in terms of stability and stresses in bone graft are not fully understood. A previously validated three-dimensional, nonlinear finite element model of an intact L2-L5 segment was modified to simulate posterior interbody fusion cages made of CFRP and titanium at the L4-L5 disc with pedicle screw, to investigate the effect of cage stiffness on the biomechanics of the fused segment in the lumbar region. From the results, it could be found that the use of a CFRP cage would not only reduce stress shielding, but it might also have led to increased bony fusion.

Finite Element Analysis of Carbon Fiber Reinforced Plastic Frame for Multi-legged Subsea Robot (다관절 복합이동 해저로봇을 위한 탄소섬유 복합소재 프레임의 구조 해석)

  • Yoo, Seong-Yeol;Jun, Bong-Huan;Shim, Hyungwon;Lee, Pan-Mook
    • Journal of Ocean Engineering and Technology
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    • v.27 no.6
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    • pp.65-72
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    • 2013
  • This paper describes a finite element analysis (FEA) of the body frame of a subsea robot, Crabster200 (CR200). CR200 has six legs for mobility instead of screw type propellers, which distinguishes it from previous underwater robots such as remotely operated vehicles (ROVs) and autonomous underwater vehicles (AUVs). Another distinguishing characteristic is the body frame, which is made of carbon fiber reinforced plastic (CFRP). This body frame is designed as a rib cage structure in order to disperse the applied external loads and reduce the weight. The frame should be strong enough to support many devices for exploration and operation underwater. For a reasonable FEA, we carried out specimen tests. Using the obtained material properties, we performed a modal analysis and FEA for CR200 with a ready posture. Finally, this paper presents the FEA results for the CFRP body frame and the compares the characteristics of CFRP with conventional material, aluminum.

Long-Term Follow-Up Radiologic and Clinical Evaluation of Cylindrical Cage for Anterior Interbody Fusion in Degenerative Cervical Disc Disease

  • Kim, Su-Hyeong;Chun, Hyoung-Joon;Yi, Hyeon-Joong;Bak, Koang-Hum;Kim, Dong-Won;Lee, Yoon-Kyoung
    • Journal of Korean Neurosurgical Society
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    • v.52 no.2
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    • pp.107-113
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    • 2012
  • Objective : Various procedures have been introduced for anterior interbody fusion in degenerative cervical disc disease including plate systems with autologous iliac bone, carbon cages, and cylindrical cages. However, except for plate systems, the long-term results of other methods have not been established. In the present study, we evaluated radiologic findings for cylindrical cervical cages over long-term follow up periods. Methods : During 4 year period, radiologic findings of 138 patients who underwent anterior cervical fusion with cylindrical cage were evaluated at 6, 12, 24, and 36 postoperative months using plain radiographs. We investigated subsidence, osteophyte formation (anterior and posterior margin), cage direction change, kyphotic angle, and bone fusion on each radiograph. Results : Among the 138 patients, a minimum of 36 month follow-up was achieved in 99 patients (mean follow-up : 38.61 months) with 115 levels. Mean disc height was 7.32 mm for preoperative evaluations, 9.00 for immediate postoperative evaluations, and 4.87 more than 36 months after surgery. Osteophytes were observed in 107 levels (93%) of the anterior portion and 48 levels (41%) of the posterior margin. The mean kyphotic angle was $9.87^{\circ}$ in 35 levels showing cage directional change. There were several significant findings : 1) related subsidence [T-score (p=0.039) and anterior osteophyte (p=0.009)], 2) accompanying posterior osteophyte and outcome (p=0.05). Conclusion : Cage subsidence and osteophyte formation were radiologically observed in most cases. Low T-scores may have led to subsidence and kyphosis during bone fusion although severe neurologic aggravation was not found, and therefore cylindrical cages should be used in selected cases.

An Evaluation of the Environmental Effects of Marine Cage Fish Farms: I. Estimation of Impact Region and Organic Carbon Cycling in Sediment Using Sediment Oxygen Consumption Rates and Macrozoobenthos (해상 어류가두리양식장의 환경영향평가: I. 퇴적물 산소소모율 및 저서동물을 이용한 유기물 오염영향권 추정 및 유기탄소 순환)

  • 이재성;정래홍;김기현;권정노;이원찬;이필용;구준호;최우정
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.9 no.1
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    • pp.30-39
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    • 2004
  • In order to understand the environmental impact of marine cage fish farms, we measured the vertical fluxes of particulate to the sediment, the distribution of organic carbon in core samples, sediment oxygen consumption rate (SOD), and macrobenthos with increasing distance from a fish cage in Miruk island located in Tongyong. The experiment was performed in August 2003. Measured values gradually decreased with distance, indicating that the organic matter in the sediment derived from the fish farm. The dominant macrobenthos species were Tharyx mulifilis, Lumbrineris longifolia, Sigambra tentaculata, and Capitella capitata, occupying 88% of the total population. Capirella capirata, an opportunistic polychaete species, were especially abundant between 0 to 5 m radius range. The estimated impact regions of organic matter enrichment based on sediment consilmption rates and compositions of macrobenthos were in good agreement. Most organic matter derived from the fish farm was deposited within a 10 m radius and then dispersed horizontally to nearby (at least 50 m) surface sediment. The vertical organic carbon fluxes to the sediment at the fish farm were higher by a factor of two than those outside the area. The remineralization organic carbon in the upper sediment layer was estimated to be 50% (1.07 g C m$^{-2}$ day$^{-1}$ ) at the fish farm. In contrast, outside the area, 30% (0.30 g C m$^{-2}$ day$^{-1}$ ) of organic carbon was recycled and the remaining 70% was deposited to the deep sediment layer.

A DFT Study on CO2 Interaction with a BN Nano-Cage

  • Baei, Mohammad T.;Peyghan, Ali Ahmadi;Bagheri, Zargham
    • Bulletin of the Korean Chemical Society
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    • v.33 no.10
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    • pp.3338-3342
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    • 2012
  • Covalent functionalization of a $B_{12}N_{12}$ nano-cage with $CO_2$ molecule has been investigated using density functional theory in terms of energetic, geometric, and electronic property analyses. Results show that besides two physisorption configurations, $CO_2$ preferably tends to perform [2+2] addition on B-N bonds of the cluster which are shared between six-membered and four-membered rings, releasing energy of 14.99 kcal/mol for adsorption of the first $CO_2$ and of 15.45 kcal/mol for the second one (per each molecule). On the basis of calculated density of states, we have found that the electronic properties of the physisorbed $B_{12}N_{12}$ by $CO_2$ have not changed, while slight changes have been predicted in the functionalized cases. Present results might be helpful to provide an effective way to modify the $B_{12}N_{12}$ properties for further purifications and applications.

Thermal and Geometrical Effect on the Motor Performance of Composite Squirrel Cage Rotor (복합재료 농형 회전자의 열적, 기하학적 특성이 모터 성능에 미치는 효과)

  • 장승환;이대길
    • Composites Research
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    • v.14 no.3
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    • pp.77-89
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    • 2001
  • Since the critical whirling vibration frequency of high speed built-in type motor spindle systems is dependent on the rotor mass of the built-in motor and the spindle specific bending modulus, the rotor and the shaft were designed using magnetic powder containing epoxy and high modulus carbon fiber epoxy composite, respectively. In order to increase the amount of the magnetic flux of the composite squirrel cage rotor of an AC induction motor, a steel core was inserted into the composite rotor. From the magnetic analysis, the optimal configurations of steel core and conductor bars for the dynamic characteristics of the rotor system were determined and proposed. The temperature dependence of composite squirrel cage rotor materials was investigated by various experiments such as TMA, DMA and VSM.

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