• 제목/요약/키워드: Carbon Zero

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Efficient Adsorption of Methylene Blue from Aqueous Solution by Sulfuric Acid Activated Watermelone Rind (Citrullus lanatus)

  • Lee, Seo-Yun;Choi, Hee-Jeong
    • 공업화학
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    • 제32권3호
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    • pp.348-356
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    • 2021
  • The lignocellulose-based dried watermelon rind (WR) was modified with sulfuric acid, namely SWR for enhancement of methylene blue (MB) adsorption from the aqueous solution. According to FT-IR analysis, after the modification of WR with sulfuric acid, the functional groups of R-SO3H, COOH and -OH groups was formated or enhanced on the surface of the WR. Moreover, the point of zero charge (pHpzc) was changed from 6.3 to 4.1 after modification, which widened the range for adsorbing of cationic dye MB. The adsorption process of MB onto the SWR was suitable for pseudo-2nd-order and Langmuir model and the maximum adsorption capacity of Langmuir was found to be 334.45 mg/g at pH 7. In adition, the adsorption process occurs through the electrostatic interaction, hydrogen bridge formation, electron donor-acceptor relationship, and 𝜋-𝜋 electron dispersing force between functional groups on the carbon surface with MB molecules. Depending on functional groups available on the SWR surface, the MB adsorption mechanism can occur in combination with various interactions.

합성가스 스파크점화 과급 엔진에서 희박 연소를 통한 열효율 및 배기 개선 (Improvement of Thermal Efficiency and Emission by Lean Combustion in a Boosted Spark-Ignition Engine Fueled with Syngas)

  • 박현욱;이준순;나랑후 잠스랑;오승묵;김창업;이용규;강건용
    • 한국분무공학회지
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    • 제26권1호
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    • pp.40-48
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    • 2021
  • Lean combustion was applied to improve the thermal efficiency and emission in a single-cylinder, spark-ignition engine fueled with syngas. Under naturally aspirated conditions, the lean combustion significantly improved the thermal efficiency compared to the stoichiometric combustion, mainly due to the reduction in heat transfer loss. Intake air boost was applied to compensate the low power output of the lean combustion. The gross indicated power of 24.8 kW was achieved by increasing the intake pressure up to 1.6 bar at excess air ratio of 2.2. The nitrogen oxides showed near zero level, but the carbon monoxide emission was significant.

Effects of Chemical Etching with Sulfuric Acid on Glass Surface

  • Jang, H.K.;Chung, Y.L.;S.W.Whangbo;C.N.Whang;Lee, S.J.
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2000년도 제18회 학술발표회 논문개요집
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    • pp.165-165
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    • 2000
  • Glass slides were chemically etched with sulfuric acid using five different methods. we investigated the effects of the chemical etching conditions on such properties as chemical composition, surface roughness, and the thermal stability of the glass. Sodium and carbon atoms in the surface of the glass are effectively eliminated by chemical etching with sulfuric acid. The glass slides were boiled for 30 min in 95% sulfuric acid and were depth profiled at room temperature with X-ray photoelectron spectroscopy (XPS), the Na ls signal was not detected in the detection limit of XPS. Surface morphology of the glass was very different depending on the concentration of sulfuric acid. The surface of the glass etched with 50% sulfuric acid was rougher than that of glass etched with 95% sulfuric acid. The sodium concentration of the glass boiled for 30 min in 95% sulfuric acid was nearly zero at the glass surface, and the sodium composition changed very little with annealing temperatures up to 35$0^{\circ}C$ in a vacuum environment. However the sulfur concentration at the glass surface due to the sulfuric acid increased with increasing temperature.

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Measurement of greenhouse gas emissions from a dairy cattle barn in Korea

  • Eska Nugrahaeningtyas;So-Hee Jeong;Eliza Novianty;Mohammad Ataallahi;Geun Woo Park;Kyu-Hyun Park
    • Journal of Animal Science and Technology
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    • 제65권2호
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    • pp.459-472
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    • 2023
  • Korea is currently developing country-specific emission factors to support the 2050 zero-carbon campaign. Dairy cattle represent one of the largest livestock industries in Korea, and the industry is estimated to continue increasing because of an increase in milk demand. However, country-specific emission factors for dairy cattle are currently only available for calculating methane (CH4) emissions from enteric fermentation. Two experiments were conducted to evaluate CH4 and nitrous oxide (N2O) fluxes from sawdust-bedded barn in dairy cow and steer, as well as dairy cattle manure composting lots. The greenhouse gas (GHG) fluxes were quantified using the open-chamber method and gas chromatography. CH4 fluxes from steer, dairy cow, and manure compost were 27.88 ± 5.84, 36.12 ± 10.85, and 259.44 ± 61.78 ㎍/head/s, respectively. N2O fluxes from steer, dairy cow, and manure compost were 14.04 ± 1.27, 4.11 ± 1.57, and 3.97 ± 1.08 ㎍/head/s, respectively. The result of this study can be used to construct country-specific data for GHG emissions from manure management. Thus, the application of mitigation strategies can be prioritized based on the GHG profile and targeted source.

벤투리 효과를 활용한 도심형 건물용 하이브리드 풍력 및 태양광 발전 시스템 기초타당성 예비연구 (Preliminary Feasibility Study on Wind and Solar Hybrid Power Systems based on Venturi Effects for Buildings)

  • 김수현;김윤수;박수민;안지현;이상훈
    • 신재생에너지
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    • 제19권1호
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    • pp.22-30
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    • 2023
  • Recently, the use of renewable energy has been increasing to achieve carbon neutrality. The concept of a zero-energy building is also attracting attention. In this study, a preliminary study was conducted to analyze the feasibility of a hybrid wind and solar power generation system between buildings that utilize the building wind generated by the Venturi effect. For this purpose, the wind speed and sunshine hours were monitored in the area where the building wind blows by the Venturi effect, and the power generation depending on system types, areas, and season was estimated. Consequently, the wind power generation system showed a larger amount of power per area than solar power. The wind power systems can generate larger power if wind power blades are installed along the height of the building. As a preliminary study, this study verified the feasibility of the system utilizing building wind and suggested follow-up studies.

탄소중립 항만 구현을 위한 지능형 제로에너지 건물 관리시스템 (Implementation of Intelligent Zero-Energy Building Management System For Carbon Neutral Port)

  • 이진규;강동재;정형진;김인수
    • 한국정보처리학회:학술대회논문집
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    • 한국정보처리학회 2022년도 추계학술발표대회
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    • pp.1038-1040
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    • 2022
  • 지속적인 지구 평균 기온 상승으로 인해 우리나라를 포함한 전 세계적으로 탄소중립을 위한 혁신이 이루어지고 있다. 본 연구는 해양수산부 '해양수산분야 2050 탄소중립 로드맵'의 기준에 따라 에너지 자립률을 극대화하고 효율을 최적화시킨 제로에너지 탄소중립 건축물을 제시한다. 태양광 발전 시스템에서, 패널의 태양 일주추적 기능을 통해 에너지 발전률을 극대화하고, 패널 하향정렬 및 딥러닝 모델을 통해 유지 보수를 용이하게 하여 성능 저하를 예방한다. 폐열을 이용한 열 회수/바이패스 환기 시스템을 통해 에너지 효율을 최적화하고, 온/습도에 가중치를 부여하여 모호했던 환기 시스템 결정 기준을 에너지 효율화에 맞게 최적화해 제시한다. 탄소중립 BEMS 기능이 내재된 앱 개발로 위의 건축물 시스템을 제어·관리한다. 본 연구를 통해 제로 에너지 건축물으로서 항만 건물의 가능성을 제고하고, 탄소중립 항만의 구현을 기대한다.

청정수소 생산 방식 도입에 따른 LCA 기반 탄소중립 기여도 평가 (An Evaluation of Net-zero Contribution by Introducing Clean Hydrogen Production Using Life Cycle Assessment)

  • 장소정;정대웅;김정열;황용우;안희경
    • 한국수소및신에너지학회논문집
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    • 제35권2호
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    • pp.175-184
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    • 2024
  • This study focuses on investigating the importance of managing greenhouse gas emissions from global energy consumption, specifically examining domestic targets for clean hydrogen production. Using life cycle assessment, we evaluated reductions in global warming potential and assessed the carbon neutrality contribution of the domestic hydrogen sector. Transitioning from brown or grey hydrogen to blue or green hydrogen can significantly reduce emissions, potentially lowering CO2 equivalent levels by 2030 and 2050. These research findings underscore the effectiveness of clean hydrogen as an energy management strategy and offer valuable insights for technology development.

Analysis of online food purchasing behavior: a study of Sri Lankan consumers

  • Piyumi Wijesinghe;Shashika D. Rathnayaka;Niranga Bandara;Jung Min Heo;Dinesh D. Jayasena
    • 농업과학연구
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    • 제50권4호
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    • pp.927-940
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    • 2023
  • Online shopping has been undergoing significant developments in the South Asian region in the last decade. Using a representative sample of Sri Lankan consumers, this study explored online food purchasing behavior in Sri Lanka, a developing nation and island in South Asia. Data were collected from 562 respondents from all nine provinces in Sri Lanka using an online survey. Consumer attitudes were evaluated using factor analysis, and factor scores were added as explanatory variables to the final model. An ordered logistic regression model was used to examine the impact of consumer demographics, economic variables, and consumer attitudes on online food purchases. Online food purchasing intensity was categorized into four groups that suited ordinal rankings: zero for never, low for rarely, medium for occasionally, and high for regularly. Results indicated that age, income, education, and living in urban areas affect the online food purchasing behavior of Sri Lankan consumers. In addition, trust, convenience, and attitudes toward price were powerful drivers of online food purchasing. The findings have a number of significant managerial ramifications for creating strategies to promote online food purchases in developing South Asian nations like Sri Lanka. Moreover, promoting online shopping could be a potential solution for traffic congestion, ultimately helping to mitigate the negative externalities associated with it, such as carbon emissions and air pollution.

Effect of Glutamine, Glutamic Acid and Nucleotides on the Turnover of Carbon (δ13C) in Organs of Weaned Piglets

  • Amorim, Alessandro Borges;Berto, Dirlei Antonio;Saleh, Mayra Anton Dib;Telles, Filipe Garcia;Denadai, Juliana Celia;Sartori, Maria Marcia Pereira;Luiggi, Fabiana Golin;Santos, Luan Sousa;Ducatti, Carlos
    • Asian-Australasian Journal of Animal Sciences
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    • 제29권8호
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    • pp.1152-1158
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    • 2016
  • Morphological and physiological alterations occur in the digestive system of weanling piglets, compromising the performance in subsequent phases. This experiment aimed at verifying the influence of glutamine, glutamate and nucleotides on the carbon turnover in the pancreas and liver of piglets weaned at 21 days of age. Four diets were evaluated: glutamine, glutamic acid or nucleotides-free diet (CD); containing 1% glutamine (GD); containing 1% glutamic acid (GAD) and containing 1% nucleotides (ND). One hundred and twenty-three piglets were utilized with three pigs slaughtered at day zero (weaning day) and three at each one of the experimental days (1, 2, 4, 5, 7, 9, 13, 20, 27, and 49 post-weaning), in order to collect organ samples, which were analyzed for the ${\delta}^{13}C$ isotopic composition and compared by means of time. No differences were found (p>0.05) among treatments for the turnover of the $^{13}C$ in the pancreas ($T_{50%}$ = 13.91, 14.37, 11.07, and 9.34 days; $T_{95%}$ = 46.22, 47.73, 36.79, and 31.04 days for CD, GD, GAD, and ND, respectively). In the liver, the ND presented accelerated values of carbon turnover ($T_{50%}=7.36$ and $T_{95%}=24.47days$) in relation to the values obtained for the GD ($T_{50%}=10.15$ and $T_{95%}=33.74days$). However, the values obtained for the CD ($T_{50%}=9.12$ and $T_{95%}=30.31days$) and GAD ($T_{50%}=7.83$ and $T_{95%}=26.03days$) had no differences (p>0.05) among other diets. The technique of $^{13}C$ isotopic dilution demonstrated trophic action of nucleotides in the liver.

충전층에서 탄소에 고정시킨 Tyrosinase의 반응속도에 관한 연구 (Kinetic Behavior of Immobilized Tyrosinase on Carbon in a Simulated Packed-Bed Reactor)

  • 신선경;김교근
    • 분석과학
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    • 제10권1호
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    • pp.66-74
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    • 1997
  • 지름 2.54cm, 길이 10cm인 유리관에 tyrosinase(EC. 1.14.18.1)를 입자의 크기 $550{\mu}m$인 탄소에 고정시켜 충진하고, 페놀과 산소를 기질로 사용하여 tyrosinase의 반응 특성을 조사하기 위해 axial dispersion 모델을 제안하였다. 본 논문에서 페놀의 농도는 55.5mM로 고정시키고 산소(2.7ppm, 5.4ppm, 그리고 9.5ppm)와 유속 (1~3mL/s)을 변화시키면서 탄소에 고정된 tyrosinase의 반응을 관찰하였다. 또한, Damkolher수를 계산하고 분산 특성과 식으로부터 효소반응 속도 및 분산의 영향을 예측하기 위해 수치적 해석을 하였다. 연구 결과 물질저항은 주로 외부 전달과 내부확산이었으며, 제안된 모델에서 Biot수는 64.25였다. 페놀은 1.0mL/s 정도의 느린 속도에서 산소의 농도가 높을수록 높은 전환율을 나타내었다. 한편, axial dispersion 모델과 plug flow 모델의 비교에서는 모두 같은 전환율을 나타내어 axial dispersion 모델이 반응속도와 무관함을 알 수 있었다.

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