• Coupled systems mechanics
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• v.3 no.4
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• pp.329-344
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• 2014

In this work, quantum molecular dynamics simulations (QMD) are preformed to study the hydrogen molecules in three types of carbon nanostructures, $C_{60}$ fullerene, (5,5) and (9,0) carbon nanotubes and graphene layers. Interactions between hydrogen and the nanostructures is of importance to understand hydrogen storage for the development of hydrogen economy. The QMD method overcomes the difficulties with empirical interatomic potentials to model the interaction among hydrogen and carbon atoms in the confined geometry. In QMD, the interatomic forces are calculated by solving the Schrodinger's equation with the density functional theory (DFT) formulation, and the positions of the atomic nucleus are calculated with the Newton's second law in accordance with the Born-Oppenheimer approximation. It is found that the number of hydrogen atoms that is less than 58 can be stored in the $C_{60}$ fullerene. With larger carbon fullerenes, more hydrogen may be stored. For hydrogen molecules passing though the fullerene, a particular orientation is required to obtain least energy barrier. For carbon nanotubes and graphene, adsorption may adhere hydrogen atoms to carbon atoms. In addition, hydrogen molecules can also be stored inside the nanotubes or between the adjacent layers in graphite, multi-layer graphene.

• Journal of the Korean Society of Industry Convergence
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• v.25 no.6_3
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• pp.1165-1171
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• 2022

In this paper, the results of an experimental study were presented by measuring and comparing the flexural strength and deformation on the carbon fiber sheet strength reinforced concrete beam considering end anchorage effect. For this purpose, total six specimens of 100×100×600mm size were prepared and tested according to the KDS 14 20 20. The specimens were categorized in three cases as reference beams without strengthening, beams carbon fiber strengthened but not anchored and beams carbon fiber strengthened also anchored. Experimental results showed that the end anchorage contributed to increase the flexural strength about 42% greater than that of carbon fiber sheets alone, and the number and width of cracks were relatively increased. The results support a considerable effects of end anchorage for carbon fiber strengthened reinforced concrete beams in enhancing the flexural performance. Further studies are needed in durability and long term behavior of carbon fiber sheet strengthened reinforced concrete beams.

• Advances in environmental research
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• v.12 no.2
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• pp.123-148
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• 2023

The first part of the study involved calculating emission factors from electricity production. The second part of the study aimed to analyze perceptions of the concept of carbon dioxide utilization and was conducted through a questionnaire survey with participants from Almaty and Astana. The results showed that there were no significant improvements in the decrease of carbon dioxide emissions between 2017 and 2020. Almost no change occurred in the rate of carbon dioxide emission throughout the course of the four years. According to the results of the survey, a number of respondents had reservations about the feasibility of using carbon dioxide utilization as a solution to tackle climate change. They felt that this technology would only offer a temporary solution to carbon emissions, without addressing the underlying causes of the problem. Despite these concerns, the participants acknowledged that carbon dioxide utilization had certain advantages in promoting sustainability.

• Polymer(Korea)
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• v.34 no.6
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• pp.511-516
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• 2010

The electrochemical coating of poly(3-octylthiophene) on carbon materials was studied in order to investigate the application possibility of the modified carbon materials in the photoelectronic devices. Commercial carbon paper and carbon fiber were used as substrate electrodes for electrochemical coating. The coating behaviors were analysed with the variation of monomer and electrolyte concentration, applied potential, and cycling number in cyclovoltammetry. The coating rate of poly(3-octylthiophene) formed on the substrate were proportional to the monomer and electrolyte concentration, applied potential, and cycling number with each independent exponent. The structure and morphology of electrochemically polymerized poly(3-octylthiophene) was investigated with scanning electron microscopy and FTIR reflectance measurement.

• The Journal of the Society of Korean Medicine Diagnostics
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• v.19 no.3
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• pp.185-193
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• 2015

Objectives The purpose of this report is to represent decubitus ulcer(pressure sore) improved by carbon arc and oriental medicine. Methods Patients with decubitus ulcer were treated with carbon arc, acupuncture, herbal medicine and simple dressing. Laser was irradiated at ulcer site once a day for 5 hour, using cored carbon number 3000,3002. Simple dressing with wound cleansing was performed to prevent reinfection. Herbal medicine and acupuncture treatment were applied to improve patients' general condition. Ulcer sizes and aspects were carefully checked by one week. Results Sizes of the decubitus ulcer decreased. Stage of ulcer was improved from stage 3 to stage 2. These results show that carbon arc may play a role in treating the decubitus ulcer with oriental medicine.

• Carbon letters
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• v.4 no.3
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• pp.126-132
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• 2003

Granular Activated Carbon (GAC) has been proven to be an excellent material for many industrial applications. A systematic study has been carried out of the kinetics of physical as well as chemical activation of phenolic resin chars. Physical activation was carried out using $CO_2$ and chemical activation using KOH as activating agent. There are number of factors which influence the rate of activation. The activation temperature and residence time at HTT varied in the range $550{\sim}1000^{\circ}C$ and $\frac{1}{2}{\sim}8$ hrs respectively. Kinetic studies show that the rate of chemical activation is 10 times faster than physical activation even at much lower temperature. Above study show that the chemical activation process is suitable to prepare granular activated carbon with very high surface area i.e.$ 2895\;m^2/g$ in short duration of time i.e. 1 to 2 hrs at lower temperature i.e. $750^{\circ}C$ from phenolic resins.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2008.04c
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• pp.22-26
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• 2008

In this paper, we developed a hybrid simulation model of carbon laser ablation under the Ar plasmas consisted of fluid and particle methods. Three kinds of carbon particles, which are carbon atom, ion and electron emitted by laser ablation, are considered in the computation. In the present simulation, we adopt capacitively coupled plasma with asymmetrical electrodes. As a result, in Ar plasmas, carbon ion motions were suppressed by a strong electric field and were captured in Ar plasmas. Therefore, a low number density of carbon ions were deposited upon substrate. In addition, the plume motions in Ar gas atmosphere was also discussed.

• Interaction and multiscale mechanics
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• v.2 no.2
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• pp.209-222
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• 2009

This article describes recent work on mechanics of carbon nanotubes, one of the most fundamental and amazing man-made nanostructures. The noteworthy point is that "nano"-scale mechanics of carbon nanotubes can be well described by the continuum elastic theories for "macro"-scale thin shells. This provides an efficient means to elucidate mechanical deformation effects of carbon nanotubes on their physical and chemical properties, which is significant to develop new-generation nanomaterials based on nanotubes and their composites. Potential applications of the mechanical deformation of nanotubes in nano-electronics and nano-biology are also commented. In addition, theoretical investigations regarding external pressure buckling is carried out here and we have numerically confirmed that larger N (the number of layers) and a smaller D (the innermost diameter) make "corrugation modes" with a larger mode-index k be energetically favored.

• Journal of Powder Materials
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• v.24 no.4
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• pp.298-301
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• 2017

In the present work, we use multiwall carbon nanotubes (MWCNT) as the starting material for the fabrication of sintered carbon steel. A comparison is made with conventionally sintered carbon steel, where graphite is used as the starting material. Milling is performed using a horizontal mill sintered in a vacuum furnace. We analyze the grain size, number of pores, X-ray diffraction patterns, and microstructure. Changes in the physical properties are determined by using the Archimedes method and Vickers hardness measurements. The result shows that the use of MWCNTs instead of graphite significantly reduces the size and volume of the pores as well as the grain size after sintering. The addition of $Y_2O_3$.to the Fe-MWCNT samples further inhibits the growth of grains.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.22 no.6
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• pp.532-536
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• 2009

In this study, the capacity change of supercapacitor was investigated by surface treatments of carbon nanotubes as electrode materials with various methods, such as ball-milling, $KMnO_4$ and $H_2SO_4/HNO_3$ acid mixture. Surface treatments generated a number of defects on the surface of carbon nanotubes by attacking on $\pi$ bond in graphene layer, at which carboxyl groups were introduced. These hydrophilic groups could enhance the capacity by increasing the wettability of carbon nanotube surfaces. However, a drawback of the surface treatment was the decrease of conductivity by the loss of conduction path in graphene layer due to the defect formation. The surface treatment condition should be therefore optimized between hydrophilicity increase and conductivity decrease.