• Carbon letters
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• v.14 no.4
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• pp.210-217
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• 2013

The synthesis of carbon nanomaterials (CNMs) by a chemical vapor deposition method using three different plant oils as precursors is presented. Because there are four parameters involved in the synthesis of CNM (i.e., the precursor, reaction temperature of the furnace, catalysts, and the carrier gas), each having three variables, it was decided to use the Taguchi optimization method with the 'the larger the better' concept. The best parameter regarding the yield of carbon varied for each type of precursor oil. It was a temperature of $900^{\circ}C$ + Ni as a catalyst for neem oil; $700^{\circ}C$ + Co for karanja oil and $500^{\circ}C$ + Zn as a catalyst for castor oil. The morphology of the nanocarbon produced was also impacted by different parameters. Neem oil and castor oil produced carbon nanotube (CNT) at $900^{\circ}C$; at lower temperatures, sphere-like structures developed. In contrast, karanja oil produced CNTs at all the assessed temperatures. X-ray diffraction and Raman diffraction analyses confirmed that the nanocarbon (both carbon nano beads and CNTs) produced were graphitic in nature.

• Korean Chemical Engineering Research
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• v.50 no.5
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• pp.933-937
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• 2012

In the present study, we evaluate the sensitivity and optimal stripping voltammetry (SV) conditions of copper (Cu), which is one of the main trace heavy metals inducing the environmental contamination, using carbon nanotube (CNT) electrode. In addition, the reaction mechanism of stripping reaction of Cu is investigated. The electrochemical analyses such as squarewave stripping voltammetry (SWSV) and linear scan voltammetry (LSV) are used for the evaluations. As a result of that, the best SWSV conditions like squarewave amplitude of 15 mV, frequency of 60 Hz, deposition potential of -1.0V vs. Ag/AgCl and deposition time of 200s are determined with the measured Cu sensitivity of $1.824{\mu}A/{\mu}M$. As a driving force affecting the stripping reaction of Cu, surface reaction is more dominant one than diffusion. These results are compared with other reference results and it is confirmed that our suggested CNT electrode gives rise to better Cu sensitivity result than other references.

• 한국정보디스플레이학회:학술대회논문집
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• 2006.08a
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• pp.422-425
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• 2006

Recently, studies on orientation of carbon nanotubes (CNTs) dispersed in nematic liquid crystal (LC) and CNTs effects on electro-optic characteristics of the LC device have been performed. In this paper, we summarize interaction nature between CNT and LC, local distortion of the LC director field by motion of CNTs, and effects on electro-optic performances of LC device.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2009.05a
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• pp.260-260
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• 2009

탄소나노튜브 (carbon nanotube, CNT)는 우수한 전기적, 화학적, 기계적 성질과 큰 비표면적인 구조적인 특성에 기인하여 전자방출원 수직 소자에서의 interconnection, 에너지 저장 소자에서의 전극재료 및 고감도센서 등 다양한 분야로의 응용이 예상되고 있다 [1]. 본 연구에서는 이러한 응용을 위한 계면제어 측면제어 측면에서, 고전도성을 확보하기 위하여 금속 기판 위에 수직배향 탄소나노튜브(VCNT)를 직접 성장시키고자 하였다.

• JSTS:Journal of Semiconductor Technology and Science
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• v.14 no.2
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• pp.153-162
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• 2014

We show that carbon nanotube sensors with gold particles on the single-walled carbon nanotube (SWNT) network operate as Schottky barrier transistors, in which transistor action occurs primarily by varying the resistance of Au-SWNT junction rather than the channel conductance modulation. Transistor characteristics are calculated for the statistically simplified geometries, and the sensing mechanisms are analyzed by comparing the simulation results of the MOSFET model and Schottky junction model with the experimental data. We demonstrated that the semiconductor MOSFET effect cannot explain the experimental phenomena such as the very low limit of detection (LOD) and the logarithmic dependence of sensitivity to the DNA concentration. By building an asymmetric concentric-electrode model which consists of serially-connected segments of CNTFETs and Schottky diodes, we found that for a proper explanation of the experimental data, the work function shifts should be ~ 0.1 eV for 100 pM DNA concentration and ~ 0.4 eV for $100{\mu}M$.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2008.06a
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• pp.153-153
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• 2008

Practical application of single-walled carbon nanotubes (SWCNTs) qualified as a promising material has been limited by either poor dispersion or their insolubility in aqueous or organic media due to formation of bundling by relatively high surface energy. Thus, major attention to overcome this issue has been paid at surface modification of CNTs by functionalization, but this introduces defects to the sidewall of CNTs, consequently perturbing the inherent electronic and optical properties. Therefore, using surfactants is a general approach to disperse SWCNTs with lower damages by which bundled nanotubes could be dispersed up to the level of individuals or small bundles. Here, we have investigated various surfactants for their efficiency in dissolving purified SWCNTs produced by arc discharge in deionized water. To compare the surfactants respectively, we have determined the least amount of each surfactant to suspend the nanotubes under optimized experimental conditions(CNT amount, sonication power, and centrifugation speed, etc.) set on the basis of the most common surfactant (sodium dodecyl sulfate, SDS) and discussed the qualitative and quantitative characterization of SWCNT dispersions by UV-Vis absorption spectroscopy. Quantitative aspect about nanotube dispersion was that in particular N-methyl-2-pyrrolidone (NMP) and sodium dodecylbenzene sulfonate (NaDDBS) were found to be effective in dispersing individual tubes.

• 한국정보디스플레이학회:학술대회논문집
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• 2007.08a
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• pp.277-280
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• 2007

Field emission-back light unit (FE-BLU) was fabricated using carbon nanotube (CNT) emitter. Local dimming and local brightening techniques were achieved, which results in very high contrast ratio. In addition, the motion blur phenomenon, one of the serious problems of liquid crystal display (LCD) with cold cathode fluorescent lamp (CCFL)-BLU, was removed from LCD-TV by using FE-BLU.

• Coupled systems mechanics
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• v.10 no.1
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• pp.39-60
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• 2021

The present paper is concerned with the study of nonlinear ultrasonic waves in a magneto thermo (MT) elastic armchair single-walled carbon nanotube (ASWCNT) resting on polymer matrix. The analytical formulation is developed based on Eringen's nonlocal elasticity theory to account small scale effect. After developing the formal solution of the mathematical model consisting of partial differential equations, the frequency equations have been analyzed numerically by using the nonlinear foundations supported by Winkler-Pasternak model. The solution is obtained by ultrasonic wave dispersion relations. Parametric work is carried out to scrutinize the influence of the non local scaling, magneto-mechanical loadings, foundation parameters, various boundary condition and length on the dimensionless frequency of nanotube. It is noticed that the boundary conditions, nonlocal parameter, and tube geometrical parameters have significant effects on dimensionless frequency of nano tubes. The results presented in this study can provide mechanism for the study and design of the nano devices like component of nano oscillators, micro wave absorbing, nano-electron technology and nano-electro- magneto-mechanical systems (NEMMS) that make use of the wave propagation properties of armchair single-walled carbon nanotubes embedded on polymer matrix.

• Advances in nano research
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• v.16 no.3
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• pp.251-263
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• 2024

This article investigates the free vibration behavior of carbon nanotube reinforced composite (CNTRC) beams embedded using variational analytical methods and artificial neural networks (ANN). The material properties of layered functionally graded CNTRC (FG-CNTRC) beams are estimated using nonlocal parameters modified power-law with different types of CNT distributions through the thickness direction of the beam. Adopting Eringen's nonlocal elasticity theory to capture the small size effects, the nonlocal governing equations are derived and solved using the analytical method. And also, the problem was analyzed using the ANN method. The architecture of the proposed ANN model is 3-9-1. In the experiments, we used 112 different data to predict the natural frequency using ANN. Based on the nonlocal differential constitutive relations of Eringen, the equations of motion as well as the boundary conditions of the beam are derived using Hamilton's principle. The classical beam theory is used to formulate a governing equation for predicting the free vibration of laminated CNTRC beams. According to the experimental results, the prediction ability of the ANN model is very good and the natural frequency can be predicted in ANN without attempting any experiments.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.36 no.6
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• pp.603-608
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• 2023

Carbon black with high purity and excellent conductivity is used as a conductive filler in the semiconductive compound for EHV (Extra High Voltage) power cables of 345 kV or higher. When carbon black and CNT (carbon nanotube) are applied together as a conductive filler of a semiconductive compound, stable electrical properties of the semiconductive compound can be maintained even though the amount of conductive filler is significantly reduced. In EHV power cables, since the semi-conductive layer is close to the conductor, stable electrical characteristics are required even under high-temperature conditions caused by heat generated from the conductor. In this study, the theoretical principle that a semiconductive compound applied with carbon black and CNT can maintain excellent electrical properties even under high-temperature conditions was studied. Basically, the conductive fillers dispersed in the matrix form an electrical network. The base polymer and the matrix of the composite, expands by heat under high temperature conditions. Because of this, the electrical network connected by the conductive fillers is weakened. In particular, since the conductive filler has high thermal conductivity, the semiconductive compound causes more thermal expansion. Therefore, the effect of CNT as a conductive filler on the thermal conductivity, thermal expansion coefficient, and volume resistivity of the semiconductive compound was studied. From this result, thermal expansion and composition of the electrical network under high temperature conditions are explained.