• 제목/요약/키워드: Carbon Nano Material

검색결과 372건 처리시간 0.026초

Polyol Process를 통한 PEM Fuel Cell용 Pt/C촉매 제조 (Preparation of Pt/C catalyst for PEM fuel cells using polyol process)

  • 오형석;김한성
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2006년도 추계학술대회
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    • pp.443-446
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    • 2006
  • Carbon-supported Platinum (Pt) is the potential electro-catalyst material for anodic and cathodic reactions in fuel cell. Catalytic activity of the metal strongly depends on the particle shape, size and distribution of the metal in the porous supportive network. Conventional preparation techniques based on wet impregnation and chemical reduction of the metal precursors often do not provide adequate control of particle size and shape. We have proposed a novel route for preparing nano sized Pt colloidal particles in solution by oxidation of ethylene glycol. These Pt nano particles were deposited on large surface area carbon support. The process of nano Pt colloid formation involves the oxidation of solvent ethylene glycol to mainly glycolic acid and the presence of its anion glycolate depends on the solution pH. In the process of colloidal Pt formation glycolate actsas stabilizer for the Pt colloidal particle and prevents the agglomeration of colloidal Pt particles. These mono disperse Pt particles in carbon support are found uniformly distributed in nearly spherical shape and the size distribution was narrow for both supported and unsupported metals. The average diameter of the Pt nano particle was controlled in the range off to 3 nm by optimizing reaction parameters. Transmission electron microscopy, CV and RRDE experiments were used to compliment the results.

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탄소나노튜브 복합소재 전왜 특성과 3D 프린팅을 활용한 로드셀 개발 연구 (A Study on Load Cell Development by means of a Nano-Carbon Piezo-resistive Composite and 3D printing)

  • 강인필;정관영;최백규;김성용;오광원;김병탁;백운경
    • 드라이브 ㆍ 컨트롤
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    • 제17권4호
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    • pp.97-102
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    • 2020
  • This paper presents the basic research for the design and fabrication of a 3D-printed load cell made of NCPC (nano-carbon piezo-resistive composite). We designed a structure that can resonate at a low frequency range of about 5-6 Hz with ANSYS using sensitivity analysis and a response surface method. The design was verified by fabricating the device with a low-quality commercial 3D printer and ABS filament. We conducted a feasibility test for a commercial sensor using 1000 cyclic load tests at 0.3 Hz in a material testing system. A manufacturing process for the 3D printer filament based on the NCPC was also developed using the nano-composite process.

탄소나노튜브 상대전극을 이용한 염료감응형 태양전지 (Carbon nano-tube as the Counter electrode for Dye-sensitized Solar cell)

  • 구보근;이동윤;김현주;이원재;송재성
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2004년도 추계학술대회 논문집 Vol.17
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    • pp.691-694
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    • 2004
  • 염료감응형 태양전지는 다공질 $TiO_2$ 전극막, 광감응형 염료, 전해질, 상대전극으로 구성된, 전기화학적 원리를 응용한 신형태양전지이다. 염료감응형 태양전지의 상대전극으로 주로 Pt가 사용되고 있는데 본 연구에서는 탄소나노튜브를 사용하여 상대전극으로서의 가능성을 조사하였다. 제조된 탄소나노튜브 상대전극은 cyclic voltammetry와 Impedance spectroscopy을 이용하여 전기화학적 특성을 측정하였다. 또한 탄소 나노튜브 상대 전극이 태양전지의 효율 및 그 특성에 미치는 영향을 알아보기 위하여 단위 셀 태양전지를 제조하여 단파장 하에서의 광전특성을 측정하고, 이를 바탕으로 탄소나노튜브의 상대전극으로서의 가능성을 제시하였다.

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Hydrogen Storage Behaviors of Porous Carbons

  • 김병주;안계혁;박수진
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2009년도 추계학술대회 논문집
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    • pp.230-230
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    • 2009
  • In this work, Porous Carbons (PCs) were prepared by using a chemical acid treatment, and the hydrogen storage behaviors of PCs doped by Pt nanoparticles were investigated. The hydrogen storage capacities of the Pt-doped carbons with a platinum content of 0.2 - 1.5 wt.% were evaluated by a volumetric adsorption method at 298K and 10 MPa. The microstructures of samples were examined by XRD and SEM. It was found that the hydrogen storage capacitiesof the PCs dramatically increased, but the amount of hydrogen stored from the samples began to decrease after 0.6 wt.% of Pt content due to the pore blocking. These results indicate that a suitable amount of supported catalysts and layer intervals of carbons had a very important impact on hydrogen storage behaviors.

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Impact of carbon dioxide on the stability of the small-scale structures by trapping the material properties

  • Zhou, Yunlong;Wang, Jian
    • Advances in nano research
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    • 제13권1호
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    • pp.1-12
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    • 2022
  • The existence of active material in the environment causes the small-scale systems to be sensitive to the actual environment. Carbon dioxide is one of the active materials that exists a lot in the air conditions of the living environment. However, in some applications, the carbon dioxide-coated is used to improve the performance of systems against the destructive factors such as the corrosion; nevertheless, in the current research, the stability analysis of a carbon dioxide capture mechanism-coated beam is investigated according to the mathematical simulation of a rectangular composite beam utilizing the modified couple stress theory. The composite mechanism of carbon dioxide trapping is made of a polyacrylonitrile substrate that supports a cross-link polydimethylsiloxane gutter layer as the carbon dioxide mechanism trapping. Three novel types of carbon dioxide trapping mechanism involving methacrylate, poly (ethylene glycol) methyl ether methacrylate, and three pedant methacrylates are considered, which were introduced by Fu et al. (2016). Finally, according to introducing the methodology of carbon dioxide (CO2) trapping, the impact of various effective parameters on the stability of composite beams will be analyzed in detail.

신선가공조건에 따른 고탄소강 선재 Pearlite 층상구조의 유한요소해석 (FEM analysis of Pearlite Lamella Structure of High Carbon Steel on Drawing Process Conditions)

  • 김현수;배철민;이충열;김병민
    • 대한기계학회논문집A
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    • 제29권2호
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    • pp.325-332
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    • 2005
  • This paper presents a study on defects in pearlite lamella structure of high carbon steel by means of finite-element method(FEM) simulation. High carbon pearlite steel wire is characterized by its nano-sized microstructure feature of alternation ferrite and cementite. FEM simulation was performed based on a suitable FE model describing the boundary conditions and the exact material behavior. Due to the lamella structure in high carbon pearlite steel wire, material plastic behavior was taken into account on deformation of ferrite and cementite. The effects of many important parameters(reduction in area, semi-die angle, lamella spacing, cementite thickness) on wire drawing process can be predicted by DEFORM-2D. It is possible to obtain the important basic data which can be guaranteed in the ductility of high carbon steel wire by using FEM simulation.

Konjac Glucomannan Derived Carbon Aerogels for Multifunctional Applications

  • Lian, Jie;Li, Jiwei;Wang, Liang;Cheng, Ru;Tian, Xiuquan;Li, Xue;Zhou, Jian;Duan, Tao;Zhu, Wenkun
    • Nano
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    • 제13권10호
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    • pp.1850113.1-1850113.11
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    • 2018
  • Environmental and energy issues have always been a hot topic of global research. Oil leakage has caused great damage to the environment, affecting a wide area and it is difficult to clean up. In most cases, carbon-based adsorbents are typically utilized to remove oil spills because of their economic benefits and high adsorbent efficiency. At the same time, its excellent material properties can also be used for the preparation of supercapacitors. In this paper, the carbon aerogels were prepared by the one-step method. The prepared materials endowed a 3D network structure with a huge number of micropores and mesoporous, and the material is light-weight, stable, hydrophobic and has affinity for oil (17.02 g/g) to the KGM carbon aerogel. Through the physicchemical characterization, the KGM carbon aerogel shows specific surface area is $689m^2/g$, high water contact angle ($136.64^{\circ}$) and excellent reusability (more than 15 cycle times). In addition, we also discussed the electrochemical properties of the material and obtained the specific electrical capacity of 139 F/g under the condition of 1 A/g.

탄소나노튜브/$V_2O_5$ 나노선 헤테로 구동소자 특성연구 (Research for MWCNTs/$V_2O_5$ Nanowire Hetero-Junction Actuator Devices)

  • 이강호;이성민;박소정;허정환;김규태;박성준;하정숙
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2005년도 하계학술대회 논문집 Vol.6
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    • pp.83-84
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    • 2005
  • 생명체의 근육을 구성하는 근섬유와 마찬가지로 나노선 구동기는 불규칙적으로 엉켜있는 나노선들의 집합으로 이루어져 있으며, 기존의 강유전체에 기반을 둔 구동기에 비해 낮은 구동전압과 높은 일률을 가진다. 대표적인 나노선인 MWCNTs(Multi-walled Carbon Nanotubs)와 $V_2O_5$ 나노선을 이용한 구동기는 이미 각각 시현된 바 있으나, 이 둘의 이종접합을 통한 구동기는 아직까지 보고되지 않았다. 본 연구에서는 탄소나노튜브와 $V_2O_5$의 이종접합을 통해 필름 형태의 구동기를 구현하여 각각의 나노선 만을 이용했을 때보다 월등한 성능을 보여주는 구동기를 구현하였다. 향후 실용화 가능성을 염두에 두어, 보다 강건하고 최적화된 나노선 sheet의 합성과 구동기의 구조적 향상이 이루어진다면 그동안 알려진 그 어떤 물질보다도 우수한 구동특성을 보여줄 것이라 예상된다.

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W-C-N 확산방지막의 질소량에 따른 특성 연구 (Effect of Nitrogen concentration on Properties of W-C-N Diffusion Barrier)

  • 김수인;김상윤;강길범;이동호;고태준;강지훈;이창우
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2006년도 하계학술대회 논문집 Vol.7
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    • pp.114-115
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    • 2006
  • 반도체 기술이 초고집적화 되어감에 따라 공정에서 선폭이 줄어들고, 박막을 다층으로 제조하는 것이 중요하게 되었다. 이와 같은 제조 공정 하에서는 Si 기판과 금속 박막간의 확산이 커다란 문제로 부각되어 왔다. 특히 Cu는 높은 확산성에 의하여 Si 기판과 접합에서 많은 확산에 의한 문제가 발생하게 되며. 또한 선폭이 줄어듦에 따라 고열이 발생하여 실리콘으로 spiking이 발생하게 된다. 이를 방지하기 위하여 우리는 3개의 화합물로 구성된 Tungsten-Carbon-Nitrogen (W-C-N) 확산방지막을 사용하였다. 실험은 물리적 기상 증착법 (PVD)으로 질소비율을 변화하며 확산방지막을 증착하였고, 이를 여러 온도에서 열처리하여 X-ray Diffraction 분석을 하였다.

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