• Title/Summary/Keyword: Carbon Migration

Search Result 73, Processing Time 0.251 seconds

Modeling Geologic Storage of Carbon Dioxide: Effects of Low-permeability Layer on Migration of CO2 (이산화탄소 지중저장 모델링: 저투수 이질협재층이 이산화탄소 거동에 미치는 영향)

  • Han, Ahreum;Kim, Taehee;Kwon, Yikyun;Koo, Min-Ho
    • Journal of Soil and Groundwater Environment
    • /
    • v.22 no.3
    • /
    • pp.42-49
    • /
    • 2017
  • TOUGH2 was used to simulate the migration of $CO_2$ injected into a sandy aquifer. A series of numerical simulations was performed to investigate the effects of a low-permeability layer (LPL) embedded in the aquifer on the injection rate and the pressure distribution of $CO_2$. The results show that the size and location of the LPL greatly affected the spread of $CO_2$. The pressure difference between two points in the aquifer, one each below and above the LPL, increased as the size of the LPL increased, showing a critical value at 200 m, above which the size effect was diminished. The location of the LPL with respect to the injection well also affected the migration of $CO_2$. When the injection well was at the center of the LPL, the injection rate of $CO_2$ decreased by 5.0% compared to the case with no LPL. However, when the injection well was at the edge of the LPL, the injection rate was decreased by only 1.6%. The vertical distance between the injection point and the LPL also affected the injection rate. The closer the LPL was to the injection point, the lower the injection rate was, by up to 8.3%. Conclusively, in planning geologic storage of $CO_2$, the optimal location of the injection well should be determined considering the distribution of the LPL in the aquifer.

Seismic Imaging of Ocean-bottom Seismic Data for Finding a Carbon Capture and Storage Site: Two-dimensional Reverse-time Migration of Ocean-bottom Seismic Data Acquired in the Pohang Basin, South Korea (이산화탄소 지중저장 부지 선정을 위한 해저면 탄성파 탐사자료의 영상화: 포항 영일만 해저면 탐사자료의 2차원 역시간 구조보정)

  • Park, Sea-Eun;Li, Xiangyue;Kim, Byoung Yeop;Oh, Ju-Won;Min, Dong-Joo;Kim, Hyoung-Soo
    • Geophysics and Geophysical Exploration
    • /
    • v.24 no.3
    • /
    • pp.78-88
    • /
    • 2021
  • Owing to the abnormal weather conditions due to global warming, carbon capture and storage (CCS) technology has attracted global attention as a countermeasure to reduce CO2 emissions. In the Pohang CCS demonstration project in South Korea, 100 tons of CO2 were successfully injected into the subsurface CO2 storage in early 2017. However, after the 2017 Pohang earthquake, the Pohang CCS demonstration project was suspended due to an increase in social concerns about the safety of the CCS project. In this study, to reconfirm the structural suitability of the CO2 storage site in the Pohang Basin, we employed seismic imaging based on reverse-time migration (RTM) to analyze small-scale ocean-bottom seismic data, which have not been utilized in previous studies. Compared with seismic images using marine streamer data, the continuity of subsurface layers in the RTM image using the ocean-bottom seismic data is improved. Based on the obtained subsurface image, we discuss the structural suitability of the Pohang CO2 storage site.

Diameter Control of Carbon Nanotubes Using Surface Modified Fe Nano-Particle Catalysts with APS (APS로 표면 처리한 Fe 나노 입자 촉매를 이용한 CNT의 직경제어)

  • Lee, Sunwoo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.26 no.6
    • /
    • pp.478-481
    • /
    • 2013
  • Diameter controlled carbon nanotubes (CNTs) were grown using surface modified iron nano-particle catalysts with aminpropyltriethoxysilane (APS). Iron nano-particles were synthesized by thermal decomposition of iron pentacarbonyl-oleic acid complex. Subsequently, APS modification was done using the iron nano-particles synthesized. Agglomeration of the iron nano-particles during the CNT growth process was effectively prevented by the surface modification of nano-particles with the APS. APS plays as a linker material between Fe nano-particles and $SiO_2$ substrate resulting in blocking the migration of nano-particles. APS also formed siliceous material covering the iron nano-particles that prevented the agglomeration of iron nano-particles at the early stages of the CNT growth. Therefore we could obtain the diameter controlled CNTs by blocking agglomeration of the iron nano-particles.

Change in Molecular Weight Distribution of Diffusible Species on RTV Silicone Rubber Using Solvent Extraction and Recovery Rate of Hydrophobicity (용매추출에 의한 옥외용 RTV 실리콘고무의 분자량 변화와 발수성 회복속도)

  • Lee, Chang-R.;Kim, Dong-H.;Choi, Yong-C.;Kim, Jong-G.;Homma, H.;Izumi, K.
    • Proceedings of the KIEE Conference
    • /
    • 2001.07c
    • /
    • pp.1337-1339
    • /
    • 2001
  • We have investigated the relation between the molecular weight distribution (MWD) of diffusible species and the recovery rate of hydrophobicity of room-temperature vulcanizing (RTV) silicone rubber (SIR) using solvent extraction at various temperatures. It was observed that the extract had a MWD ranging from a few hundreds g/mol to hundreds of thousands g/mol. By measuring the migration of siloxane to the extracted SIR surface through a thin carbon coating, the aspect of migration of diffusible species was observed as a real time plot, and the time constant of the migration was also calculated. According to the time dependence of IR-absorbance, the time constant was increased with the increase of MW of the extracts.

  • PDF

Research on desorption and stability of benzene, toluene, acetone and n-hexane of activated carbon acquired from domestic market (국내 시판 중인 활성탄을 이용한 벤젠, 톨루엔, 아세톤 및 노말 헥산의 탈착 및 저장성 평가 연구)

  • Lee, Naroo;Yi, Gwangyong
    • Journal of Korean Society of Occupational and Environmental Hygiene
    • /
    • v.24 no.3
    • /
    • pp.353-358
    • /
    • 2014
  • Purpose: This study was conducted to evaluate desorption efficiency and storage stability on activated carbon acquired form domestic market. Materials: Mixture of acetone, benzene, normal hexane and toluene was injected on four types of charcoal 100 mg. After overnight, charcoal was desorbed by carbon disulfide $1m{\ell}$ and analyzed by gas chromatography with flame ionization detector. Results: Desorption efficiency of benzene, normal hexane and toluene in charcoal tubes were 95% ~ 105%. But desorption efficiency of acetone in charcoal tubes was below 75% and different from types of charcoal. The more injected amount of acetone on charcoal showed higher desorption efficiency. Acetone injected on charcoal tubes migrated from front section into back section after 10 days storage at room temperature. Conclusions: Desorption efficiency and storage stability of activated carbon acquired from domestic market was good for benzene, normal hexane and toluene. The activated carbon acquired from domestic market has ability to be used as sampling media.

Study on Diffusion Bonding of Stainless Steel to Mild Steel (연강-스테인리스강의 확산접합에 관한 연구)

  • Kim, S.T.
    • Journal of the Korean Society for Heat Treatment
    • /
    • v.11 no.1
    • /
    • pp.17-26
    • /
    • 1998
  • Cladding of stainless steel on mild steel was prepared by diffusion bonding process. The bond strength increased with an increase of bonding temperature and time. It was also found that the bond strength increased as the surface roughness decreased. After the diffusion bonding of stainless steel-mild steel, the mild steel part near the bonded interface showed higher strength than the base steel due to the migration of chromium and nickel from stainless steel to mild steel. Carbon migration from mild steel gave effect on the formation of chromium carbides at grain boundaries of stainless steel, the fractograpohic features of the imperfectly bonded interface showed rather coarse dimples in the mild steel part and very fine dimples in the stainless steel part.

  • PDF

Seasonal and diel abundance and feeding patterns of Chaoborus flavicans in Sang-Chun reservoir

  • Jeong, Ga-Ram;Park, Sang-Kyu
    • Animal cells and systems
    • /
    • v.14 no.4
    • /
    • pp.297-303
    • /
    • 2010
  • To document the basic ecological aspects of Chaoborus species, which has never been reported in Korea, we attempted to identify the species, to monitor seasonal and vertical dynamics, and to elucidate trophic relations of the species in Sang-Chun reservoir. Using morphological characteristics, we identified the collected samples as C. flavicans. Also, we compared the distribution of C. flavicans, Daphnia rosea and chlorophyll a to observed seasonal dynamics. The increase of C. flavicans was observed 1-2 weeks after the increase of D. rosea. Survey of diel vertica migration patterns in the summer season showed that C. flavicans were in hypolimnion at daytime, but moved to the epilimnion at night. Finally, to determine trophic relationships in Sang-Chun reservoir, additional studies on the food web were undertaken by stable isotope analysis. Chaoborus flavicans I-II instars appear to be filter feeders based on carbon isotope values. Trophic levels of C. flavicans III-IV instars were shown to be higher than other zooplankto based on nitrogen isotope values.

Control of Galvanic Corrosion Between A516Gr.55 Steel and AA7075T6 Depending on NaCl Concentration and Solution Temperature

  • Hur, S.Y.;Jeon, J.M.;Kim, K.T.;Kim, Y.S.
    • Corrosion Science and Technology
    • /
    • v.19 no.6
    • /
    • pp.281-287
    • /
    • 2020
  • Chloride ion is one of the most important corrosive agents in atmospheric corrosion, especially in marine environments. It has high adsorption rate and increases the conductivity of electrolytes. Since chloride ions affect the protective properties and the surface composition of the corrosion product, they increase the corrosion rate. A low level of chloride ions leads to uniform corrosion, whereas a high level of chloride ions may induce localized corrosion. However, higher solution temperatures tend to increase the corrosion rate by enhancing the migration of oxygen in the solution. This work focused on the effect of NaCl concentration and temperature on galvanic corrosion between A516Gr.55 carbon steel and AA7075T6 aluminum alloys. When AA7075T6 aluminum alloy was galvanically coupled to A516Gr.55 carbon steel, AA7075T6 was severely corroded regardless of NaCl concentration and solution temperature, unlike the corrosion properties of single specimen. The combined effect of surface treatment involving carbon steel and aluminum alloy on corrosion behavior was also discussed.

Hybrid PtCo Alloy Nanocatalysts Encapsulated by Porous Carbon Layers for Oxygen Reduction Reactions (다공성 탄소층이 코팅된 하이브리드 표면 구조를 갖는 산소 환원 반응용 PtCo 합금 나노 촉매)

  • Jang, Jeonghee;Sharma, Monika;Sung, Hukwang;Kim, Sunpyo;Jung, Namgee
    • Korean Journal of Materials Research
    • /
    • v.28 no.11
    • /
    • pp.646-652
    • /
    • 2018
  • During a long-term operation of polymer electrolyte membrane fuel cells(PEMFCs), the fuel cell performance may degrade due to severe agglomeration and dissolution of metal nanoparticles in the cathode. To enhance the electrochemical durability of metal catalysts and to prevent the particle agglomeration in PEMFC operation, this paper proposes a hybrid catalyst structure composed of PtCo alloy nanoparticles encapsulated by porous carbon layers. In the hybrid catalyst structure, the dissolution and migration of PtCo nanoparticles can be effectively prevented by protective carbon shells. In addition, $O_2$ can properly penetrate the porous carbon layers and react on the active Pt surface, which ensures high catalytic activity for the oxygen reduction reaction. Although the hybrid catalyst has a much smaller active surface area due to the carbon encapsulation compared to a commercial Pt catalyst without a carbon layer, it has a much higher specific activity and significantly improved durability than the Pt catalyst. Therefore, it is expected that the designed hybrid catalyst concept will provide an interesting strategy for development of high-performance fuel cell catalysts.

Analysis of Carbon Migration with Post Weld Heat Treatment in Dissimilar Metal Weld. (이종금속 피복용접부의 후열처리에 따른 탄소이동 해석)

  • Kim, Byeong-Cheol;Ann, Hui-Seong;Kim, Seon-Jin;Song, Jin-Tae
    • Korean Journal of Materials Research
    • /
    • v.1 no.1
    • /
    • pp.29-36
    • /
    • 1991
  • Pressurized Water Reactor (PWR) pressure vessels are made of forged low alloy steel plates internally clad with an austenitic stainless steel by welding to improve anti-corrosion properties. They display a characteristic behavior of dissimilar metal weld interface during post weld heat treatment (PWHT) and service at high temperature and pressure. In this Study, Metallugical structure of weld interface of SA 508 Class 3 forged steel clad with 309L, Austenitic stainless steel after PWHT was investigated. To estimate the width of the carburized/decarburized bands quantitatively, a model for carbon diffusion was proposed and a theoretical equation was derived.

  • PDF