• Title/Summary/Keyword: Carbon Equivalent

Search Result 359, Processing Time 0.03 seconds

The Effect of Micro-Pore Configuration on the Flow and Thermal Fields of Supercritical CO2

  • Choi, Hang-Seok;Park, Hoon-Chae;Choi, Yeon-Seok
    • Environmental Engineering Research
    • /
    • v.17 no.2
    • /
    • pp.83-88
    • /
    • 2012
  • Currently, the technology of $CO_2$ capture and storage (CCS) has become the main issue for climate change and global warming. Among CCS technologies, the prediction of $CO_2$ behavior underground is very critical for $CO_2$ storage design, especially for its safety. Hence, the purpose of this paper is to model and simulate $CO_2$ flow and its heat transfer characteristics in a storage site, for more accurate evaluation of the safety for $CO_2$ storage process. In the present study, as part of the storage design, a micro pore-scale model was developed to mimic real porous structure, and computational fluid dynamics was applied to calculate the $CO_2$ flow and thermal fields in the micro pore-scale porous structure. Three different configurations of 3-dimensional (3D) micro-pore structures were developed, and compared. In particular, the technique of assigning random pore size in 3D porous media was considered. For the computation, physical conditions such as temperature and pressure were set up, equivalent to the underground condition at which the $CO_2$ fluid was injected. From the results, the characteristics of the flow and thermal fields of $CO_2$ were scrutinized, and the influence of the configuration of the micro-pore structure on the flow and scalar transport was investigated.

Fabrication and Characteristic of C-doped Base AlGaAs/GaAs HBT using Carbontetrachloride $CCI_4$ ($CCI_4$ 를 사용하여 베이스를 탄소도핑한 AlGaAs/GaAs HBT의 제작 및 특성)

  • 손정환;김동욱;홍성철;권영세
    • Journal of the Korean Institute of Telematics and Electronics A
    • /
    • v.30A no.12
    • /
    • pp.51-59
    • /
    • 1993
  • A 4${\times}10^{19}cm^{3}$ carbon-doped base AlGaAs/GaAs HBY was grown using carbontetracholoride(CCl$_4$) by atmospheric pressure MOCVD. Abruptness of emitter-base junction was characterized by SIMS(secondary ion mass spectorscopy) and the doping concentration of base layer was confirmed by DXRD(double crystal X-ray diffractometry). Mesa-type HBTs were fabricated using wet etching and lift-off technique. The base sheet resistance of R$_{sheet}$=550${\Omega}$/square was measured using TLM(transmission line model) method. The fabricated transistor achieved a collector-base junction breakdown voltage of BV$_{CBO}$=25V and a critical collector current density of J$_{O}$=40kA/cm$^2$ at V$_{CE}$=2V. The 50$\times$100$\mu$$^2$ emitter transistor showed a common emitter DC current gain of h$_{FE}$=30 at a collector current density of JS1CT=5kA/cm$^2$ and a base current ideality factor of ηS1EBT=1.4. The high frequency characterization of 5$\times$50$\mu$m$^2$ emitter transistor was carried out by on-wafer S-parameter measurement at 0.1~18.1GHz. Current gain cutoff frequency of f$_{T}$=27GHz and maximum oscillation frequency of f$_{max}$=16GHz were obtained from the measured Sparameter and device parameters of small-signal lumped-element equivalent network were extracted using Libra software. The fabricated HBT was proved to be useful to high speed and power spplications.

  • PDF

Improving Quality of Eco-Mortar Incorporating Blast Furnace Slag and Recycled Aggregate Depending on Replacement Gypsum and Cement (고로슬래그 미분말과 순환잔골재를 사용하는 친환경 모르타르에 탈황석고 및 시멘트에 의한 품질향상)

  • Baek, Byung Hoon;Han, Cheon-Goo
    • Journal of the Korea Institute of Building Construction
    • /
    • v.15 no.2
    • /
    • pp.193-199
    • /
    • 2015
  • As a solution of both environmental issue of reducing carbon dioxide emission and sustainable issue of exhausting natural resources, in concrete industry, many research on recycling various by-products or industrial wastes as the concrete materials has been conducted. The aim of this research is feasibility analysis of additional reaction with ordinary Portland cement and flue gas desulfurization gypsum based on the blast furnace slag and recycled fine aggregate based mortar to achieve the normal strength range. Consequently, in the case of mortar replaced 10% FGD and 30% OPC for BS, 80% of plain OPC mortar's compressive strength was achieved. Furthermore, when the water-to-binder ratio is decreased to keep the practically similar level of flow, it is expected to be achieve the equivalent compressive strength to plain OPC mortar.

The Effect of Hole Size on the Failure Strength and Fracture Toughness in Polymer Matrix Composite Plates (Plastic기 복합재료의 파손강도 및 파괴인성에 미치는 원공크기의 영향)

  • Kim, Jeong-Gyu;Kim, Do-Sik
    • Korean Journal of Materials Research
    • /
    • v.3 no.2
    • /
    • pp.197-204
    • /
    • 1993
  • Abstract The effects of the hole size and the specimen width on the fracture behavior of several fabric composite plates are experimentally investigated in tension. Tests are performed on plain woven glass/ epoxy, plain woven carbon/epoxy and satin woven glass/polyester specimens with a circular hole. It is shown in this paper that the characteristic length according to the point stress criterion depends on the hole size and the specimen width. An excellent agreement is found between the experimental results and the analytical predictions of the modified failure criterion. The notched strength increase with an increase in the damage ratio, which is explained by a stress relaxation due to the formation of damage zone. When the unstable fracture occurred, the critical crack length equivalent for the damage zone is about twice the characteristic length. The critical energy release rate $G_c$ is independent of hole size for the same specimen width. The variation of $G_c$ according to the material system, fiber volume fraction and specimen width relates to the notch sensitivity factor. $G_c$ increases with a decrease in the notch sensitivity factor, which can be explained by a stress relaxation due to the increase of damage zone.

  • PDF

Mechanical Properties and Durability of Concrete in Relation to the Amount of Limestone Use (석회석 혼입량에 따른 콘크리트의 역학적 및 내구특성)

  • Oh, Sungwoo;Shin, Dongcheol
    • Journal of the Korea institute for structural maintenance and inspection
    • /
    • v.21 no.3
    • /
    • pp.138-144
    • /
    • 2017
  • In order to reduce carbon dioxide emission in construction industry, less amount of cement use can be one of the alternatives to manufacture concrete. One of the non-sintered construction materials are limestone, which is the raw material to manufacture ordinary Portland cement(OPC). A large amount of limestone have already been used as binders such as blended cement in Europe and US. Even European countries were already established the standard of blended cement, where the limestone can be used up to 35 percent. In this study, experimental researches were conducted to investigate the effects of limestone replacement on the mechanical properties and durability of concrete with 15%, 25% and 35% of limestone substitution to use limestone in blended cement. 15 percent use of limestone in blended cement developed equivalent or even higher compressive strengths compared to Plain mixture. Porosity of limestone cement with 15 percent substitution was much lower than Plain mixture. Most durability tests such as concrete carbonation, freeze-thaw cycle and drying shrinkage strains were conducted to evaluate long-term performance, and the test results indicated that 15 percent of limestone use did not significantly influence on the concrete durability compared with plain concrete.

Spectrum and Equivalent Transient Vibration Analysis of Small Composite Satellite Structure (소형 복합재위성의 스팩트럼 및 과도진동해석)

  • Cho, Hee-Keun;Seo, Jung-Ki;Myung, Noh-Hoon
    • Journal of the Korean Society for Aeronautical & Space Sciences
    • /
    • v.37 no.6
    • /
    • pp.586-594
    • /
    • 2009
  • This paper is the study on random, sinusoidal and shock vibration responses for the STSAT-3(science and technology satellite-3) proto-model which is the first small size all-composite satellite in Korea. The structure system of the STSAT-3 forms box type structure by joining several hybrid sandwich panels comprised of honeycomb core and carbon fiber reinforced laminated composite skins on both side. Mode shape, stress, displacement and acceleration responses are obtained on both the frequency domain and time domain by means of a commercial FEA software MSC/NASTRAN. From these analysis results, failure, safety factor and design validity are assessed. These results can be successfully applicable as reference data when a new satellite is developed as well as giving out an excellent criteria in satellite vibration treatment design.

Material Properties of 400MPa Grade Hot Rolled H-beam(SHN400) for Building Structure (400MPa급 건축구조용 열간압연 H형강(SHN400)의 소재 특성)

  • Kim, Hee-Dong;Choi, Byoung-Jeong;Kim, Sang-Sub;Kim, Chul-Hwan;Oh, Young-Suk
    • Journal of Korean Society of Steel Construction
    • /
    • v.23 no.4
    • /
    • pp.515-522
    • /
    • 2011
  • The purpose of this study was to evaluate the material characteristics of SHN400 steel, which is suitable as a steel material for building structures, using the experimental approach. For this purpose, the chemical composition test, tensile test, macro test, micro test, and charpy notch impact test were conducted with specimens taken from the highest, thickest, and commonly used H-beams for girder or beam members. Each test was conducted under the Korean Standard(KS) test conditions. All the test results satisfied the requirements of KS (KS D 3866) and the steel material for seismic design. The carbon equivalent value (Ceq), which is related to weldability, and the yield ratio, which is related to inelastic behavior, showed especially good results. Thus, SHN400 is definitely suitable as the steel material for building structures.

Solution Dynamics and Crystal Structure of $CpMoOs_{3}(CO)_{10}(\mu-H)_{2}[\mu_{3}-\eta^{2}-C(O)CH_{2}Tol]$

  • Joon T. Park;Jeong-Ju Cho;Kang-Moon Chun;Sock-Sung Yun;Kim SangSoo
    • Bulletin of the Korean Chemical Society
    • /
    • v.14 no.1
    • /
    • pp.137-143
    • /
    • 1993
  • The tetranuclear heterometallic complex CpMo$Os_3(CO)_{10}({\mu]-H)2[{\mu}3-{\eta}^2-C(O)CH_2Tol]\;(1,\;Cp={\eta}^5-C_5H_5,\;Tol=p-C_6H_4Me)$ has been examined by variable-temperature $^{13}$C-NMR spectroscopy and by a full three-dimensional X-ray structual analysis. Complex 1 crystallizes in the orthorhombic space group Pna2$_1$ with a = 12.960(1) ${\AA}$, b = 11.255(l) ${\AA}$, c = 38.569(10)${\AA}$, V = 5626(2) ${\AA}^3$ and ${\rho}$(calcd) = 2.71 gcm$^{-3}$ for Z = 8 and molecular weight 1146.9. Diffraction data were collectedon a CAD4 diffractometer, and the structure was refined to $R_F$ = 9.7% and $R_{W^F}$ = 9.9% for 2530 data (MoK${\alpha}$ radiation). There are two essentially equivalent molecules in the crystallographic asymmetric unit. The tetranuclear molecule contains a triangulated rhomboidal arrangement of metal atoms with Os(2) and Mo at the two bridgehead positions. The metal framework is planar; the dihedral angle between Os(l)-Os(2)-Mo and Os(3)-Os(2)-Mo planes is 180$^{\circ}$. A triply bridging (${\mu}_3,\;{\eta}^2$) acyl ligand lies above the Os(l)-Os(2)-Mo plane; the oxygen atom spans the two bridgehead positions, while the carbon atom spans one bridgehead position and an acute apical position. The molecular architecture is completed by an ${\eta}^5$-cyclopentadienyl ligand and a semi-triply bridging carbonyl ligand on the molybdenum atom, and nine terminal carbonyl ligands-four on Os(3), three on Os(l), and two on Os(2). The two hydride ligands are inferred to occupy the Os(l)-Os(2) and Mo-Os(3) edges from structural and NMR data.

Characterization of Partial Interfacial Fracture on Resistance Spot-Welded TRIP Steels for Automotive Applications (자동차 차체용 TRIP강판의 저항 점용접부 Partial Interfacial Fracture 특성에 관한 연구)

  • Choi, Chul Young;Kim, In-Bae;Kim, Yangdo;Park, Yeong-Do
    • Korean Journal of Metals and Materials
    • /
    • v.50 no.2
    • /
    • pp.136-145
    • /
    • 2012
  • Resistance spot welding of TRIP780 steels was investigated to enhance understanding of weld fracture mode after tensile shear testing (TST) and L-shape tensile testing (LTT). The main failure mode for spot welds of TRIP780 steels was partial interfacial fracture (PIF). Although PIF does not satisfy the minimum button diameter (4${\surd}$t) for acceptable welds, it shows enough load carrying capacity of resistance spot welds for advanced high strength steels. In the analysis of displacement controlled L-shape tensile test results, cracks initiated at the notch of the faying surface and propagated through the interface of weldments, and finally, cracks change path into the sheet thickness direction. Use of the ductility ratio and CE analysis suggested that the occurrence of PIF is closely related to high hardness and brittle welds, which are caused by fast cooling rates and high chemical compositions of TRIP steels. Analysis of the hold time and weld time in a welding schedule demonstrated that careful control of the cooling rate and the size of a weld nugget and the HAZ zone can reduce the occurrence of PIF, which leads to sound welds with button fractures (BFs).

Mechanical Properties of Early Strength Mortar with Ground Granulated Blast Furnace Slag and Expansive Additive (고로슬래그미분말 및 팽창재를 혼입한 조강형 모르타르의 역학적 특성)

  • Koo, Kyung-Mo;Choi, Jae-Won;You, Byeong-Know;Cha, Wan-Ho;Kang, Bong-Hee
    • Journal of the Korean Recycled Construction Resources Institute
    • /
    • v.9 no.2
    • /
    • pp.177-184
    • /
    • 2021
  • In this study, the effects of ground granulated blast furnace slag(GGBFS) and expansive additive(EA) on early strength mortar were examined for the purpose of reducing carbon and improving cement performance. As a result, ealry strength Portland cement(EPC) tended to decrease in flow compared to ordinary Portland cement(OPC), but binder with EPC and GGBFS was possible to obtain higher liquidity than OPC. EPC showed higher compressive strength and shrinkage than OPC. The compressive strength of specimen with EPC and GGBFS was reduced proportionally to the replacement ratio of GGBFS. The replacement ratio of GGBFS above the compressive strength equivalent to OPC was higher under low temperature conditions. The use of GGBFS resulted in high shrinkage compared to OPC, and this characteristic was even greater under low temperature conditions. The shrinkage of specimen with EA was decreased in early ages, but was higher than the OPC in long-term ages.